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Emulsion-based Free-Radical Retrograde-Precipitation Polymerization (Paperback, 2011 ed.)
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Emulsion-based Free-Radical Retrograde-Precipitation Polymerization (Paperback, 2011 ed.)
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This monograph is a follow-up material to the first FRRPP book by
Gerard Caneba in 2009. It includes additional conceptual results,
implementation of the FRRPP process in emulsion media to produce
various block copolymers, and other FRRPP-related supplementary
topics. Conceptual topics include the application of the
quantitative analysis presented in the first FRRPP monograph for
the occurrence of the FRRPP process to the
polysterene-styrene-ether (PS-S-Ether) and poly(methacrylic
acid)-methacrylic acid-water (PMAA-MAA-Water) systems, as well as
extensions through unsteady state analysis of the occurrence of
flat temperature profiles. Also, the generalization of the
quantitative analysis is done to consider molecular weight effects,
especially based on changes of the phase envelope to an hourglass
type. Topics in implementation of the FRRPP process from
pre-emulsions of monomers and the solvent/precipitant are
highlighted. Additional FRRPP topics are included in this monograph
that pertain to more recent efforts of Gerard Caneba, such as oil
spill control, oil dispersant system, and caustic sludge
remediation from emulsion-based FRRPP materials, hydrolysis of
vinyl acetate-acrylic acid-based copolymers, and other polymer
modification studies from FRRPP-based emulsions.
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