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Carbonylation - Direct Synthesis of Carbonyl Compounds (Hardcover, 1991 ed.)
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Carbonylation - Direct Synthesis of Carbonyl Compounds (Hardcover, 1991 ed.)
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Since the publication of our earlier book on transition metal
mediated organic synthesis, * there has been a widespread increase
of interest in this topic, and transition metal based methodology
has become firmly established in many areas of organic chemistry.
The direct, catalytic formation of organic carbonyl compounds using
carbon monoxide as the source of the carbonyl group has seen
exceptional progress, and this carbonylation chemistry is being
used increasingly in research and on a larger scale for fine
chemicals production. In view of these developments, there is a
need for a modem, practi cally oriented book dealing with
transition metal based carbonylation chemistry. The present
monograph should help fulfill this need, since it is intended
specifically to foster the adoption of catalytic carbonylation as a
general tool in synthetic organic chemistry. It deals exclusively
with reactions involving the interconversion of carbon monoxide and
organic carbonyl compounds, and although the majority of the
reactions discussed involve catalytic formation of carbonyl
compounds, potentially valuable syntheses requiring stoichiometric
quantities of transition metal are also included. In addition, a
chapter is devoted to the remarkably useful reverse transformation
(decarbonylation), in which an organic carbonyl group is eliminated
in the form of carbon monoxide."
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