Cumulenes are organic molecules with two or more cumulative
(consecutive) double bonds. Their reactions often proceed at room
temperature, with or without a catalyst, and are stereospecific,
giving the reaction products in high yields - features
characteristic of "click reactions."
"Cumulenes in Click Reactions" presents a comprehensive list of
cumulene systems and their reactions, with an emphasis on their
"click-like" nature. The chapters are structured according to the
number of carbon atoms in the system, including coverage of:
introduction to the chemistry of cumulenesone-carbon cumulenes:
sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides,
and 1-aza-2-azoniaallene saltstwo-carbon cumulenes: carbon oxides,
carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and
carbodiimides), phosphaallenes, and diarsaallenes1,2-dicarbon
cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes,
1-phosphaallenes, and other metal allenes1,3-dicarbon cumulenes:
thiocarbonyl S-ylides, 2-azaallenium salts,
1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts,
and phosphorous ylides1,2,3-tricarbon cumulenes: allenes,
butatrienes, higher cumulenes and heterobutatrienesnoncarbon
cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur
nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium
cation
"Cumulenes in Click Reactions"is an essential guide for
researchers and advanced students in academia and research working
in synthetic organic, inorganic and bioorganic chemistry.
General
| Imprint: |
John Wiley & Sons
|
| Country of origin: |
United States |
| Release date: |
November 2009 |
| First published: |
2010 |
| Authors: |
H. Ulrich
|
| Dimensions: |
251 x 176 x 35mm (L x W x T) |
| Format: |
Hardcover
|
| Pages: |
562 |
| ISBN-13: |
978-0-470-77932-3 |
| Categories: |
Books >
Science & Mathematics >
Chemistry >
Organic chemistry >
General
|
| LSN: |
0-470-77932-2 |
| Barcode: |
9780470779323 |
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