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Books > Science & Mathematics > Chemistry > Organic chemistry
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Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis (Paperback, Softcover reprint of the original 1st ed. 1988)
Loot Price: R5,884
Discovery Miles 58 840
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Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis (Paperback, Softcover reprint of the original 1st ed. 1988)
Series: NATO Science Series C, 231
Expected to ship within 10 - 15 working days
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Surface organometallic chemistry is a new field bringing together
researchers from organometallic, inorganic, and surface chemistry
and catalysis. Topics ranging from reaction mechanisms to catalyst
preparation are considered from a molecular basis, according to
which the "active site" on a catalyst surface has a supra-molecular
character. This. the first book on the subject, is the outcome of a
NATO Workshop held in Le Rouret. France, in May. 1986. It is our
hope that the following chapters and the concluding summary of
recommendations for research may help to provide a definition of
surface organometallic chemistry. Besides catalysis. the central
theme of the Workshop, four main topics are considered: 1)
Reactions of organometallics with surfaces of metal oxides, metals.
and zeolites; 2) Molecular models of surfaces, metal oxides, and
metals; 3) Molecular approaches to the mechanisms of surface
reactions; 4) Synthesis and modification of zeolites and related
microporous solids. Most surface organometallic chemistry has been
carried out on amorphous high-surf ace-area metal oxides such as
silica. alumina. magnesia, and titania. The first chapter.
contributed by KNOZINGER. gives a short summary of the structure
and reactivity of metal oxide surfaces. Most of our understanding
of these surfaces is based on acid base and redox chemistry; this
chemistry has developed from X-ray and spectroscopic data, and much
has been inferred from the structures and reactivities of adsorbed
organic probe molecules. There are major opportunities for
extending this understanding by use of well-defined (single
crystal) oxide surfaces and organometallic probe molecules."
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