This seriesofbooks, which is publishedattherateofaboutoneper year,
addresses fundamental problems in materialsscience.Thecontents
coverabroadrangeoftopicsfromsmallclustersofatomstoengineering
materials and involve chemistry, physics, materials science, and
engineering,withlengthscalesrangingfromAngstromsuptomillimeters.
Theemphasis is on basic scienceratherthan on applications. Each
book focuses on a single areaofcurrent interest and brings together
leading experts to give an up-to-date discussion oftheir work and
the workof others. Each articlecontainsenough references
thattheinterestedreader can access the relevant literature. Thanks
are given to the Center for Fundamental Materials Research at
Michigan State University for supportingthisseries.
M.F.Thorpe,SeriesEditor E-mail:
[email protected]
EastLansing,Michigan,November2002 v PREFACE
ThisvolumerecordsinvitedlecturesgivenattheNewThermoelectric(TE)Materials
Workshopheld
inTraverseCity,MichiganfromAugust17-21,2002.Thethemeofthe workshop
was Chemistry, PhysicsandMaterials ScienceofThermoelectric
Materials: Beyond Bismuth Telluride. The objective of this
symposium was threefold. First, to examine and assess the ability
of solid state chemistry to produce new generation materials for TE
applications. Second, to rationalize and predict the charge and
heat
transportpropertiesofpotentialcandidatesandhypotheticalsystemsthroughsolidstate
theoryandexperiment.Third,toidentifyandprioritizeresearchneededtoreachvarious
levelsofrequirementsintermsofZTandtemperature.Theseobjectiveswereaddressed
by a series of invited talks and discussions by leading experts
from academia, governmentlaboratories,andindustry.
Thereweretwenty-twoinvitedandeightposterpresentations inthe
workshop.Out
ofthese,sixteeninvitedpresentationsarerepresentedinthisvolume.Theycoverawide
range of subjects, starting from synthesis (based on different
strategies) and characterizationofnovel materials to acareful
studyoftheir transport properties and
electronicstructure.Topicsaddressingtheissueofmakingnew
materialsare: synthetic search for new materials (di Salvo et aI.)
and synthetic strategies based on phase homologies (Kanatzidis).
The different classes of materials covered are: bismuth nanowires
(Dresselhausetal.), unconventional high-temperaturethermoelectrics,
boron carbides (Aselage et aI.) , layered cobalt oxides (Fujii et
aI.), early transition metal
antimonides(KleinkeetaI.),skutterudites(Uher),andclathratethermoelectrics(Nolas).
General
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