Aromaticity and Antiaromaticity A comprehensive review of the
science of aromaticity, as well as its evolution, from benzene to
atomic clusters In Aromaticity and Antiaromaticity: Concepts and
Applications, a team of accomplished chemists delivers a
comprehensive exploration of the evolution and critical aspects of
aromaticity. The book examines the new global criteria used to
evaluate aromaticity, including the Nucleus Independent Chemical
Shift (NICS) index and the electronic indices based on electronic
properties. Additional discussions of inorganic aromatic compounds
developed in this century, which give rise to new concepts like
multifold aromaticity, are included. Three-dimensional aromaticity
found in fullerenes and nanotubes, Moebius aromaticity present in
some annulenes, and excited state aromaticity are explored as well.
This volume explores the geometrical, electronic, magnetic, and
thermodynamic characteristics of aromatic and antiaromatic
compounds and their reactivity properties. It also provides: A
thorough historical overview of aromaticity, as well as simple
electronic and structural models Comprehensive explorations of
organic and inorganic aromatic compounds, concepts of stability and
reactivity, and geometric, energetic, magnetic, and electronic
criteria of descriptors of aromaticity Practical discussions of
heteroaromaticity, as well as Moebius aromaticity and excited state
aromaticity In-depth examinations of sigma, pi, delta, and phi
aromaticity Perfect for graduate students, researchers, and
academics interested in aromaticity, organometallic chemistry, and
computational chemistry, Aromaticity and Antiaromaticity: Concepts
and Applications will also earn a place in the libraries of
professionals and researchers working in organic, inorganic, and
physical chemistry.
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