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Controlling Collective Electronic States in Cuprates and Nickelates - A Resonant X-ray Scattering Study (Hardcover, 1st ed. 2020)
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Controlling Collective Electronic States in Cuprates and Nickelates - A Resonant X-ray Scattering Study (Hardcover, 1st ed. 2020)
Series: Springer Theses
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In this thesis chemical and epitaxial degrees of freedom are used
to manipulate charge and spin ordering phenomena in two families of
transition metal oxides, while taking advantage of state-of-the-art
resonant x-ray scattering (RXS) methods to characterize their
microscopic origin in a comprehensive manner. First, the
relationship of charge density wave order to both magnetism and the
"pseudogap" phenomenon is systematically examined as a function of
charge-carrier doping and isovalent chemical substitution in single
crystals of a copper oxide high-temperature superconductor. Then,
in copper oxide thin films, an unusual three-dimensionally
long-range-ordered charge density wave state is discovered, which
persists to much higher temperatures than charge-ordered states in
other high-temperature superconductors. By combining
crystallographic and spectroscopic measurements, the origin of this
phenomenon is traced to the epitaxial relationship with the
underlying substrate. This discovery opens new perspectives for the
investigation of charge order and its influence on the electronic
properties of the cuprates. In a separate set of RXS experiments on
superlattices with alternating nickel and dysprosium oxides,
several temperature- and magnetic-field-induced magnetic phase
transitions are discovered. These observations are explained in a
model based on transfer of magnetic order and magneto-crystalline
anisotropy between the Ni and Dy subsystems, thus establishing a
novel model system for the interplay between transition-metal and
rare-earth magnetism.
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