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Advances in Linear Free Energy Relationships (Paperback, Softcover reprint of the original 1st ed. 1972)
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Advances in Linear Free Energy Relationships (Paperback, Softcover reprint of the original 1st ed. 1972)
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Louis P. Hammett Mitchill Professor Emeritus of Chemistry, Columbia
University My interest in linear free energy relationships began
when, just out of graduate school, I read in 1924 the article by
Bmnsted and Pedersen which for the first time reported the
existence of such a relationship. That interest continues to be an
active one and, to judge merely by the extensive biblio graphies
contained in the present volume, it is widely shared. To my mind a
particularly happy aspect of the existence of linear free energy
relationships has been the proof it supplies that one need not
suppose that the behavior of nature is hopelessly complicated
merely because one cannot find a theoretical reason for supposing
it to be otherwise. The effect of a substituent in an organic
molecule on rate or equilibrium of reaction involves a fourfold
difference between relatively large quantities, a situation which
always makes for difficult theory. Yet systematic organic chemistry
could hardly have existed were it not true that like changes in
structure lead to like changes in reactivity. Linear free energy
relationships constitute the quantitative specialisation of this
fundamental principle, and they stand indeed more in the office of
teacher to theory than in that of learner from it."
General
Imprint: |
Springer-Verlag New York
|
Country of origin: |
United States |
Release date: |
February 2012 |
First published: |
1972 |
Editors: |
N. Chapman
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Dimensions: |
229 x 152 x 26mm (L x W x T) |
Format: |
Paperback
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Pages: |
486 |
Edition: |
Softcover reprint of the original 1st ed. 1972 |
ISBN-13: |
978-1-4615-8662-3 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
Organic chemistry >
General
|
LSN: |
1-4615-8662-3 |
Barcode: |
9781461586623 |
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