This book offers an overview of the state of the art in the field
of DeNOx catalysis in order to focus novel orientations, new
technological developments, from laboratory to industrial scale. A
particular attention has been paid towards the implementation of
catalytic processes for minimising NOx emissions either from
stationary or mobile sources under lean condition to meet future
standard regulations of NOx emissions. In the first part of this
book, critical aspects reported in the literature which usually
make difficult the achievement of efficient catalytic technologies
in those conditions are summarised and analysed in order two
separate new perspectives. The second part deals with fundamental
aspects at molecular level. A better understanding of the reactions
involved under unsteady-state conditions is probably a
pre-requisite step for improving the performances of the actual
processes or developing original ones. The development of powerful
in situ spectroscopic techniques is of fundamental interest for
kinetic modelling. Correlations between spectroscopic and kinetic
data with those obtained from theoretical calculations are
reported. Some illustrations emphasise the fact that these
comparisons may help in determining the nature of the catalytic
active sites and building predictive tools for simulations under
running conditions. The latter part of this book will be
illustrated by different practical approaches covering various
aspects related to the catalysts preparation and the development of
alternative technologies which include industrial considerations.
- New technological developments for investigating catalytic
reactions in transient conditions (in situ and operando
spectroscopic techniques)
- Concerted approaches in DeNOx catalysis
- How academic aspects (kinetic, in situ spectroscopic
measurements) can provide useful information for practical
applications
- Comparison of different approaches provided by academic and
industrial partners
General
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