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Books > Science & Mathematics > Chemistry > Organic chemistry
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Modern Solvents in Organic Synthesis (Paperback, Softcover reprint of the original 1st ed. 1999)
Loot Price: R1,472
Discovery Miles 14 720
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Modern Solvents in Organic Synthesis (Paperback, Softcover reprint of the original 1st ed. 1999)
Series: Topics in Current Chemistry, 206
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In recent years the choice of a given solvent for performing a
reaction has become increasingly important. More and more,
selective reagents are used for chemical transformations and the
choice of the solvent may be determining for reaching high reaction
rates and high selectivities. The toxicity and recycling
considerations have also greatly influenced the nature of the
solvents used for industrial reactions. Thus, the development of
reactions in water is not only important on the laboratory scale
but also for industrial applications. The p- formance of
metal-catalyzed reactions in water for example has led to several
new hydrogenation or hydroformylation procedures with important
industrial applications. The various aspects of organic chemistry
in water will be prese- ed in this book. Recently, novel reaction
media such as perfluorinated solvents or supercritical carbon
dioxide has proven to have unique advantages leading to more
practical and more efficient reactions. Especially with
perfluorinated solvents, new biphasic catalyses and novel
approaches to perform organic reactions have been developed. These
aspects will be examined in detail in this volume. Finally, the
performance of reactions in the absence of solvents will show
practical alternatives for many reactions. More than ever before,
the choice of the solvent or the solvent system is ess- tial for
realizing many chemical transformations with the highest
efficiency. This book tries to cover the more recent and important
new solvents or solvent systems for both academic and industrial
applications.
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