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Infrared Spectroscopy of Triatomics for Space Observation (Hardcover)
Loot Price: R3,717
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Infrared Spectroscopy of Triatomics for Space Observation (Hardcover)
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This book is dedicated to the application of the different
theoretical models described in Volume 1 to identify the near-,
mid- and far-infrared spectra of linear and nonlinear triatomic
molecules in gaseous phase or subjected to environmental
constraints, useful for the study of environmental sciences,
planetology and astrophysics. The Van Vleck contact transformation
method, described in Volume 1, is applied in the calculation and
analysis of IR transitions between vibration-rotation energy
levels. The extended Lakhlifi-Dahoo substitution model is used in
the framework of Liouville's formalism and the line profiles of
triatomic molecules and their isotopologues subjected to
environmental constraints are calculated by applying the cumulant
expansion. The applications presented in this book show how
interactions at the molecular level modify the infrared spectra of
triatomics trapped in a nano-cage (substitution site of a rare gas
matrix, clathrate, fullerene, zeolite) or adsorbed on a surface,
and how these interactions may be used to identify the
characteristics of the perturbing environment.
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