Liquid-liquid extraction (LLE) is a technique to cover the wide
variety of the science and technology research areas due to its
importance as well as key role to produce the pure metals without
waste generation. Research and development trends in the new
millennium begin the search for new routes to establish for rare
and precious metals extraction and separation with their associated
elements from natural resources as well as spent matrices.
Developed and developing countries mainly depend on the rare metals
recycling and reuse based on their uses in electronic and other
materials manufacturing at the same time their resources are very
limited at all over the globe. Zirconium and hafnium metals are
basically finds application in the nuclear power program due to the
combination of variety of properties. It is well reported that the
extractive separation of pair of metals such as zirconium and
hafnium is very difficult due to their similar chemical properties.
LLE behavior of these metal ions with commercially available
extractants such as organophosphorus, thioorganophosphorus, oximes
and synthetic complexing reagents like isoxazolones an interesting
class of -diketones is worth exploring, they could be successfully,
employed for the LLE studies of tetravalent zirconium and hafnium.
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