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N Nitrogen (Paperback, 8th ed. 1993. Softcover reprint of the original 8th ed. 1993)
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N Nitrogen (Paperback, 8th ed. 1993. Softcover reprint of the original 8th ed. 1993)
Series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, N / 0-b / b / 2
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"Nitrogen" SuppL. Vol. 82 continues the description of binary
compounds composed of nitrogen and hydrogen (nitrogen hydrides).
While" Nitrogen" SuppL. Vol. 81 covers mono- nitrogen compounds,
the present volume comprises compounds having two, three, four, or
more nitrogen atoms. Hydrazine, N H , and its ions N2Ht and N2H~+
were not included. 2 4 (Reference is made to a voluminous
monograph: E.W. Schmidt, Hydrazine and its Deriva- tives:
Preparation, Properties, Applications, Chichester 1984, 1088
pages.) Among the dinitrogen compounds, the diazenyl cation, N H+,
has been extensively inves- 2 tigated, especially in regards to
spectroscopic and kinetic properties, because of its occur- rence
in interstellar space. Chemically well-characterized are diazene, N
H , the simplest 2 2 unsaturated nitrogen hydride which is used as
a hydrogenation reagent, and the hydrazyl radical, N H , which is
frequently present as an intermediate during the formation and 2 3
decay of nitrogen-hydrogen compounds. The major portion of this
volume is taken up by hydrogen azide or hydrazoic acid, HN , the
first member in the series of trinitrogen compounds. Known to be
highly explosive 3 in pure form, it can be safely handled when
diluted. Thus, a great deal of information is available mainly on
its properties as a chemical reagent and its decomposition
processes.
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