Diamino-carbenes are viewed as an alternative to the ubiquitous
phosphine class of ligands, and are occasionally viewed as a
substitute for ligands that coordinate via nitrogen. Throughout
this book several classes of newly developed carbene precursors are
presented. The work describes the generation and application of
N-heterocyclic carbene derived metal complexes to a range of common
organic transformations. This book opens with two distinct
introductory reviews. The first focuses on recent developments in
the generation and application of NHC ligands. The second is
concerned with the area of hydrogen transfer reactions. The results
and discussion section describes the successful generation of free
'pincer' type carbene moieties, their complexation with ruthenium
and subsequent application to oxidation/reduction reactions. The
development of a 'second generation' acac based ligand is presented
in the penultimate results and discussion section. An array of
functionalised carbene precursors are prepared, each possessing a
masked carbene in a 1,5 relationship to a chelating
oxo-substituent. The final chapters contain the experimental
procedures for the compounds prepared.
General
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