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Arene-ruthenium complexes containing nitrogen and oxygen donor ligands (Paperback)
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Arene-ruthenium complexes containing nitrogen and oxygen donor ligands (Paperback)
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Scientific community has shown decent research interest in the
field of organometallic complexes based on platinum group metals
owing to their plausible use in synthetic and industrial chemistry.
In this regard, transition metal complexes containing 6-arene, 5-Cp
and Cp* have drawn special attention. In particular, arene
complexes have emerged as versatile intermediate in organic
synthesis as a consequence of the ease with which the arene ligand
can be functionalized. The presence of a transition metal center
and ancillary ligands on one face of the coordinated arene can
serve as a valuable stereochemical element. The utility of 6-arene
and 5-Cp and Cp* metal complexes emanates not only from the
reactivity inherent to the coordinated ring but, also from the
control over three facially disposed coordinated sites about a
given metal center afforded by incorporation of an arene ligand. In
search of new systems based on arene ruthenium chemistry which can
behave as potential metallo-ligands, new 6-arene ruthenium and
analogous 5-Cp complexes based on chelating N, N and N, O donor
ligands and non-chelating nitrogen donor organic ligands has been
synthesized and fully characterized.
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