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Be Organoberyllium Compounds - Part 1 (Paperback, 8th ed. 1987. Softcover reprint of the original 8th ed. 1987)
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Be Organoberyllium Compounds - Part 1 (Paperback, 8th ed. 1987. Softcover reprint of the original 8th ed. 1987)
Series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, B-e / 1 / 1
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The present volume describes organoberyllium compounds containing
at least one berylli um-carbon bond, except the beryllium carbides
and cyanides. It covers the literature com pletely to the end of
1986 and includes most of the references up to mid-1987. This
Gmelin volume is different from all other volumes of the series on
organometallic compounds in that it is dedicated to an area of
research which has virtually come to a complete standstill.
Organoberyllium chemistry has never been a very popular field, and
only few workers have contributed to its slow growth, as is seen by
the relatively small number of publications in the field. This very
modest development became stagnant in the early 1970's and was
followed by a rapid decline. This exceptional fate of a branch of
organometallic chemistry is only partly due to the very limited
number of potential application~ of beryllium and its compounds.
The compounds of this element are, in principle, at least as
interesting and intriguing to scientists as those of other metals
in the Periodic Table. No doubt the main reason for the apparent
ban of all experimental organoberyllium chemistry is to be found in
the established, and alleged, hazardous properties of beryllium
compounds. Although similar hazards have been established for other
organometallics where active research is still in process, e. g. ,
mercury and lead, these observations were absolutely lethaI for
organoberyllium research.
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