Transition Metals and Organometallics as Catalysts for Olefin Polymerization (Paperback, Softcover reprint of the original 1st ed. 1988)

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100 DegreesC, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Release date:	2012
First published:	1988
Editors:	Walter Kaminsky • Hansjoerg Sinn
Dimensions:	244 x 170 x 24mm (L x W x T)
Format:	Paperback
Pages:	442
Edition:	Softcover reprint of the original 1st ed. 1988
ISBN-13:	978-3-642-83278-9
Categories:	Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry Books > Science & Mathematics > Chemistry > Physical chemistry > General Books > Professional & Technical > Mechanical engineering & materials > Materials science > Testing of materials > General
LSN:	3-642-83278-4
Barcode:	9783642832789

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