Carbon-carbon bond formation is one of the most important topics in
organic synthesis. One of the most powerful methods for
constructing a carbon-carbon bond is the reductive coupling of
carbonyl compounds giving 1,2-diols. Of these methods, the pinacol
coupling, which was described in 1859, is still a useful tool for
the synthesis of vicinal diols. 1, 2-Diols obtained in the reaction
were very useful synthons for a variety of organic synthesis, and
were also used as intermediates for the construction of
biologically important natural product skeletons and asymmetric
ligands for catalytic asymmetric reaction. This book reviews
research done in the study of pinacol coupling, including recent
applications of ultrasound in pinacol coupling reactions.
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