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Dr. Alan Williams has acquired a considerable experience in work
with transition metal complexes at the Universities of Cambridge
and Geneva. In this book he has tried to avoid the variety of
ephemeral and often contradictory rationalisations encountered in
this field, and has made a careful comparison of modern opinions
about chemical bond ing. In my opinion this effort is fruitful for
all students and active scientists in the field of inorganic
chemistry. The distant relations to group theory, atomic
spectroscopy and epistemology are brought into daylight when Dr.
Williams critically and pedagogic ally compares quantum chemical
models such as molecular orbital theory, the more specific L. C. A.
O. description and related "ligand field" theory, the valence bond
treat ment (which has conserved great utility in antiferromagnetic
systems with long inter nuclear distances), and discusses
interesting, but not too well-defined concepts such as
electronegativity (also derived from electron transfer spectra),
hybridisation, and oxid ation numbers. The interdisciplinary
approach of the book shows up in the careful consideration given to
many experimental techniques such as vibrational (infra-red and
Raman), elec tronic (visible and ultraviolet), Mossbauer, magnetic
resonance, and photoelectron spectra, with data for gaseous and
solid samples as well as selected facts about solution chemistry.
The book could not have been written a few years ago, and is likely
to re main a highly informative survey of modern inorganic
chemistry and chemical physicS. Geneva, January 1979 C. K.
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