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A quantitative measure of the accuracy of the rate coefficients and
the excess energies is a desirable goal of this analysis. There are
two major sources of uncertainties: The atomic and molecular data
and the solar irradiance. The cross sections and branching ratios
used in this analysis come from many different sources; many of
them without any error indications. For this reason, we must
confine ourselves to a qualitative indication of the reliability of
the results. Specifically we give a quality scale in Table II for
the data of each mother molecule; A indicating the highest quality
of atomic and molecular data and F the lowest quality. The letter B
typically means that the threshold is uncertain. For most molecules
the cross section at threshold is very small and the rate
coefficient for these molecules is therefore not influenced by this
uncertainty. For atomic species the cross section is usually large
near threshold, but for these species the threshold is known quite
accurately. The letter B, therefore, indicates that the rate
coefficient is most likely quite accurate, but the excess energy is
less accurately known. The letter C usually means that the
branching ratios are not well known. This means that the total rate
coefficient is very good, but the rate coefficients and the excess
energies for the individual branches are less accurate.
A quantitative measure of the accuracy of the rate coefficients and
the excess energies is a desirable goal of this analysis. There are
two major sources of uncertainties: The atomic and molecular data
and the solar irradiance. The cross sections and branching ratios
used in this analysis come from many different sources; many of
them without any error indications. For this reason, we must
confine ourselves to a qualitative indication of the reliability of
the results. Specifically we give a quality scale in Table II for
the data of each mother molecule; A indicating the highest quality
of atomic and molecular data and F the lowest quality. The letter B
typically means that the threshold is uncertain. For most molecules
the cross section at threshold is very small and the rate
coefficient for these molecules is therefore not influenced by this
uncertainty. For atomic species the cross section is usually large
near threshold, but for these species the threshold is known quite
accurately. The letter B, therefore, indicates that the rate
coefficient is most likely quite accurate, but the excess energy is
less accurately known. The letter C usually means that the
branching ratios are not well known. This means that the total rate
coefficient is very good, but the rate coefficients and the excess
energies for the individual branches are less accurate.
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