This book provides recent advances in research on drying of particulate and porous materials. It is based on a selection of papers presented at the XI Polish Drying Symposium 2005. The contributions cover theoretical, as well as experimental and modeling research on heat and mass transfer processes during drying of porous material and fluidized beds. The book is a pioneering contribution to the science and technology of drying of particulate solids.

This book proposes a wide overview of the research and development of proton-conducting solid oxide materials. It is the first to approach the topic on proton-conducting ceramics and presents analysis studies from the fundamental to the most promising applied domains. It describes theoretical studies to enhance understanding of proton-transport mechanisms through materials and focuses on the main families of materials referred in the literature, highlighting their structure and their electrical and physicochemical properties. It lists the various routes of synthesis and processing methods used to develop such materials and deals with their main performances and prospects with respect to electromotive force, electrochemical hydrogen transport, and reactors. The book will be helpful for students from academic sciences as well as industrials dealing with applications of such materials.

Machining of Metal Matrix Composites provides the fundamentals and recent advances in the study of machining of metal matrix composites (MMCs). Each chapter is written by an international expert in this important field of research. Machining of Metal Matrix Composites gives the reader information on machining of MMCs with a special emphasis on aluminium matrix composites. Chapter 1 provides the mechanics and modelling of chip formation for traditional machining processes. Chapter 2 is dedicated to surface integrity when machining MMCs. Chapter 3 describes the machinability aspects of MMCs. Chapter 4 contains information on traditional machining processes and Chapter 5 is dedicated to the grinding of MMCs. Chapter 6 describes the dry cutting of MMCs with SiC particulate reinforcement. Finally, Chapter 7 is dedicated to computational methods and optimization in the machining of MMCs. Machining of Metal Matrix Composites can serve as a useful reference for academics, manufacturing and materials researchers, manufacturing and mechanical engineers, and professionals involved with MMC applications. It can also be used to teach modern manufacturing engineering or as a textbook for advanced undergraduate and postgraduate engineering courses in machining, manufacturing or materials.

Erosive wear is characterized by successive loss of material from the surface due to the continuous impact of solid particles. This type of wear affects numerous industries, such as power generation, mining, and the pneumatic transportation of solids. The worst case scenario normally occurs where there is a combination of both erosion and oxidation, especially at high temperatures. In order to minimize damage caused by erosive wear, many authors propose the use of better bulk materials or surface coatings, and generally cermets are suggested. Various researchers have conducted experiments to study the wear mechanisms occurring in this kind of materials, but most of these experiments do not lead to similar results; in fact, there is no accordance among the authors, and moreover, some wear variables are ignored. In this book, studies undertaken in this field by several investigators have been discussed extensively. At the end of it, table reviews are suggested to summarize the most important mechanisms of the erosive wear in bulk and coating cermets.

"Amorphous Chalcogenide Semiconductors and Glasses" describes developments in the science and technology of this class of materials. This book offers an up-to-date treatment of chalcogenide glasses and amorphous semiconductors from basic principles to applications while providing the reader with the necessary theoretical background to understanding the material properties technology of this class of materials. This book offers an up-to-date treatment of chalcogenide glasses and amorphous semiconductors from basic principles to applications while providing the reader with the necessary theoretical background to understanding the material properties. Chalcogenides form a special class of materials, which have one or more of the elements from the chalcogen group, Group VI in the Periodic Table (S, Se. or Te) as a constituent; the chalcogen is mixed with other elements to form various "new" compounds and alloys. Chalcogenides are noncrystalline solids because their structure is "amorphous" or "glassy". Such structures have totally different properties than crystalline solids. Chalcogenide glasses have a number of very interesting and useful properties, which have been already exploited in the commercialization of new devices.

After an introductory chapter, the processing, microstructure, and properties of various ceramic materials, reinforcements, and their composites are described. A separate chapter is devoted to processing of ceramic reinforcements, with a special emphasis on fibers. Processing of ceramic matrix composites is the next chapter, which includes novel techniques such as sol-gel processing and ceramics from polymeric precursors. The next four chapters cover the subjects of interface region in ceramic composites, mechanical and physical properties, and the role of thermal stresses and the important subject of toughness enhancement. Laminated composites made of ceramics are described in a separate chapter. Finally, a chapter is devoted to various applications of ceramic matrix composites. Throughout the text, the underlying relationships between the components of the triad: processing, microstructure, and properties are brought out. An exhaustive list of references and suggested reading is provided.

This monograph presents recent research findings on fracture properties and behavior of the composites, and their damage and cracking process under both quasi-static and impact loading conditions. Theoretical treatment, experimental investigation and numerical simulation aspects of the mechanics of composites, including sandwich structures are included.

I knew nothing of the work of C. G. Vayenas on NEMCA until the early nineties. Then I learned from a paper of his idea (gas interface reactions could be catalyzed electrochemically), which seemed quite marvelous; but I did not understand how it worked. Consequently, I decided to correspond with Professor Vayenas in Patras, Greece, to reach a better understanding of this concept. I think that my early papers (1946, 1947, and 1957), on the relationship between the work function of metal surfaces and electron transfer reactions thereat to particles in solution, held me in good stead to be receptive to what Vayenas told me. As the electrode potential changes, so of course, does the work function at the interface, and gas metal reactions there involve adsorbed particles which have bonding to the surface. Whether electron transfer is complete in such a case, or whether the effect is on the desorption of radicals, the work function determines the strength of their bonding, and if one varies the work function by varying the electrode potential, one can vary the reaction rate at the interface. I got the idea. After that, it has been smooth sailing. Dr. Vayenas wrote a seminal article in Modern Aspects of Electrochemistry, Number 29, and brought the field into the public eye. It has since grown and its usefulness in chemical catalytic reactions has been demonstrated and verified worldwide.

Fiberglass and Glass Technology: Energy-Friendly Compositions and Applications provides a detailed overview of fiber, float and container glass technology with special emphasis on energy- and environmentally-friendly compositions, applications and manufacturing practices which have recently become available and continue to emerge. Energy-friendly compositions are variants of incumbent fiberglass and glass compositions that are obtained by the reformulation of incumbent compositions to reduce the viscosity and thereby the energy demand. Environmentally-friendly compositions are variants of incumbent fiber, float and container glass compositions that are obtained by the reformulation of incumbent compositions to reduce environmentally harmful emissions from their melts. Energy- and environmentally-friendly compositions are expected to become a key factor in the future for the fiberglass and glass industries. This book consists of two complementary sections: continuous glass fiber technology and soda-lime-silica glass technology. Important topics covered include: o Commercial and experimental compositions and products o Design of energy- and environmentally-friendly compositions o Emerging glass melting technologies including plasma melting o Fiberglass composite design and engineering o Emerging fiberglass applications and markets Fiberglass and Glass Technology: Energy-Friendly Compositions and Applications is written for researchers and engineers seeking a modern understanding of glass technology and the development of future products that are more energy- and environmentally-friendly than current products.

Wisdom is the principal thing; therefore get wisdom; and with all thy getting, get understanding. Proverbs 4:7 In the early chapters of the book of Proverbs there is a strong emphasis on three words: knowledge, understanding, and wisdom. Perhaps we can apply these words to our philosophy behind the technology of Predictive Process Control. Knowledge is the accumulation of information provided by education as we begin to store the data in our brains that should prepare us for the challenges of the manufacturing environment. It applies to every level and every opportunity of education, formal and informal. This is simply to Know, without any requirement except a good memory, and is the basis for the following two thoughts. Understanding is the assimilation of knowledge, or the thinking process, as we begin to arrange and rearrange the data we Know for quick recall as it may be needed. This also applies to every level and opportunity of education. It is Know-Why based upon what we Know, and it requires some scepticism of oversimplified answers and a hunger for mental consistency. Wisdom is the application of both knowledge and understanding in real life enterprises. As we apply both our knowledge and understanding in those situations, all three are further enhanced by each progressive experience. This is that wonderful Know-How - to apply our education based upon Know-why, which was based upon Knowledge - which provides the confidence we need to advance in all phases of performance.

Stereology is the science that relates three-dimensional structure to the two-dimensional images that can be measured. The most common field of application is in microscopy, both of man-made materials (metals, ceramics, composites, etc.) and of biological tissue samples. This book covers the applications and terminology of both fields. Recent emphasis in stereology is concerned with sampling strategies to avoid bias due to directionality and non-uniformity, and these methods are fully covered. So are the classic techniques that measure size distributions, surface curvature, etc., which are widely useful but not discussed in other recent texts. Finally, most stereology is taught as manual procedures using counting and grids, but this text also covers the use of modern desktop computers for image analysis and processing to obtain and interpret the stereological data.

This book brings together an emerging consensus on our understanding of the complex functional materials including ferroics, perovskites, multiferroics, CMR and high-temperature superconductors. The common theme is the existence of many competing ground states and frustration as a collusion of spin, charge, orbital and lattice degrees of freedom in the presence of disorder and (both dipolar and elastic) long-range forces. An important consequence of the complex unit cell and the competing interactions is that the emergent materials properties are very sensitive to external fields thus rendering these materials with highly desirable, technologically important applications enabled by cross-response.

Organic Additives and Ceramic Processing: With Applications in Powder Metallurgy, Ink, and Paint describes the major manufacturing processes, such as slip casting, tape casting, injection molding, etc. The book covers each subject, including the ceramic processes, organic chemical structures, polymers, colloid science and others, starting from fundamental principles, with many literature references for further reading. After the fundamentals, detailed case studies from industrial applications are described for the optimization of solvents, dispersants, binders, plasticizers, lubricants and some minor additives. A wide range of information is covered, beginning with fundamental equations for students, and extending to advanced applications for development workers and factory problem solvers. Shanefield undertook this ambitious task only because of the previous lack of resources that address the growing need for detailed information on organic additives for ceramics. Suitable for use as a textbook and as a reference source for working ceramists and chemists who wish to supply the ceramics industry with additives.

Provides a summary of non-equilibrium glassy and amorphous structures and their macro- and microscopic thermal properties.

The book contains a carefully selected works of fourteen internationally recognized scientists involving the advances of the physics and chemistry of the glassy and amorphous states.

In an attempt to meet the demand for new ultra-high strength materials, the processing of novel material configurations with unique microstructure is being explored in systems which are further and further from equilibrium. One such class of emerging materials is the so-called nanophased or nanostructured materials. This class of materials includes metals and alloys, ceramics, and polymers characterized by controlled ultra-fine microstructural features in the form oflayered, fibrous, or phase and grain distribution. While it is clear that these materials are in an early stage of development, there is now a sufficient body of literature to fuel discussion of how the mechanical properties and deformation behavior can be controlled through control of the microstructure. This NATO-Advanced Study Institute was convened in order to assess our current state of knowledge in the field of mechanical properties and deformation behavior in materials with ultra fine microstructure, to identify opportunities and needs for further research, and to identify the potential for technological applications. The Institute was the first international scientific meeting devoted to a discussion on the mechanical properties and deformation behavior of materials having grain sizes down to a few nanometers. Included in these discussions were the topics of superplasticity, tribology, and the supermodulus effect. Lectures were also presented which covered a variety of other themes including synthesis, characterization, thermodynamic stability, and general physical properties."

Despite the significant progress, which has been made in developing of ceramic materials desired for engineering applications, their mass production is still not on expected level. Among the key factors hindering higher exploitation of these materials the problems in processing were identified. The processing comprises powder production, mixing techniques, forming, and sintering. All of them are equally important and all of them can introduce defects into the material. Besides improvement in processing, the properties of ceramic materials can be considerably improved by the creation of composites. Composites formed at micro or macro level are able to form more flaw-tolerant material. Considerable research activities, working on above mentioned phenomena are in progress at industrial laboratories as well as other research centres. This volume presents the contributions to the Advanced Research Workshop "Engineering Ceramics '96" with 65 participants from 21 countries held on 12th - 15th May 1996 at Smolenice Castle, Slovakia, the conference site of Slovak Academy of Sciences. The book covers research activities on engineering ceramic materials and gives an overview with respect to recent developments.

It is not good to have zeal without knowledge * . . . Book of Proverbs This volume constitutes the proceedings of the Third International Workshop on Materials Processing at High Gravity. It offers the latest results in a new field with immense potential for commercialization, making this book a vital resource for research and development professionals in industry, academia and government. We have titled the proceedings Centrifugal Materials Processing to emphasize that centrifugation causes more than an increase in acceleration. It also introduces the Coriolis force and a gradient of acceleration, both of which have been discovered to play important roles in materials processing. The workshop was held June 2-8, 1996 on the campus of Clarkson University in Potsdam, New York, under the sponsorship of Corning Corporation and the International Center for Gravity Materials Science and Applications. The meeting was very productive and exciting, with energetic discussions of the latest discoveries in centrifugal materials processing, continuing the atmosphere of the first workshop held in 1991 at Dubna (Russia) and the second workshop held in 1993 in Potsdam, New York. Results and research plans were presented for a wide variety of centrifugal materials processing, including directional solidification of semiconductors, crystallization of high Tc superconductors, growth of diamond thin films, welding, alloy casting, solution behavior and growth, protein crystal growth, polymerization, and flow behavior. Also described were several centrifuge facilities that have been constructed for research, with costs beginning at below $1000.

A multi-authored, edited work. This volume forms a comprehensive treatise on the development, manufacture, testing and applications of a broad range of ceramic, glass ceramic and carbon matrix composite materials developed in the former Soviet Union. For each of these three classes of composite materials, background theory and extensive property data are also given.

Glass ceramics are a special group of materials in which a base glass can be crystallized under carefully controlled conditions, which in turn determine the properties of the material. These materials offer a wide range of physical and mechanical properties combining the distinctive characteristics of sintered ceramics and glasses. This book provides readers with an interest in medical ceramics with the ability to start making their own glasses and glass ceramics, together with an understanding of the various factors that control the final properties of these medical and dental materials. In addition, the authors describe various industrial problems with current, clinically-used medical glass ceramics and discuss appropriate scientific solutions.

"Glasses and Glass Ceramics for Medical Applications" will appeal to a broad audience of biomaterials scientists, ceramists, and bioengineers, particularly those with an interest in orthopedic and dental applications, as well as scientists and engineers involved in the manufacture of glasses, glazes, enamels, and other glass coatings for the medical materials industry. The book will also be of interest to undergraduate and graduate students in materials engineering and dentistry, and is suitable for use in courses on medical and dental materials.

Significant progress has been made in recent years in developing silicon nitride ceramics. The advances that have been achieved are mainly based on an increasing understanding of processing and microstructure-properties relationships. New analytical methods and high resolution transmission electron microscopy (HRTEM) coupled with extensive phase equilibria studies have provided new insights into the grain boundary region and offer the possibility to tailor the microstructure for specific applications. Because of the anticipated break-through in industrial applications there are still considerablt; research activities at industrial laboratories as well as other research centres. This volume presents the contributions to the international workshop "Tailoring ofHigh- Temperature Properties of Si3N4-Ceramics" with 60 participants from 12 countries held on 6th - 9th October 1993 at SchloB Ringberg in Germany, the conference site of the Max- Planck-Society. Additionally, it contains all invited papers of the International Conference "Silicon Nitride 93" held before the workshop on 4th - 6th October 1993 in Stuttgart/Germany. The book covers all recent research activities on silicon nitride ceramics and gives an overview with respect to recent developments.

Amorphous silicon solar cell technology has evolved considerably since the first amorphous silicon solar cells were made at RCA Laboratories in 1974. Scien tists working in a number of laboratories worldwide have developed improved alloys based on hydrogenated amorphous silicon and microcrystalline silicon. Other scientists have developed new methods for growing these thin films while yet others have developed new photovoltaic (PV) device structures with im proved conversion efficiencies. In the last two years, several companies have constructed multi-megawatt manufacturing plants that can produce large-area, multijunction amorphous silicon PV modules. A growing number of people be lieve that thin-film photovoltaics will be integrated into buildings on a large scale in the next few decades and will be able to make a major contribution to the world's energy needs. In this book, Ruud E. I. Schropp and Miro Zeman provide an authoritative overview of the current status of thin film solar cells based on amorphous and microcrystalline silicon. They review the significant developments that have occurred during the evolution of the technology and also discuss the most im portant recent innovations in the deposition of the materials, the understanding of the physics, and the fabrication and modeling of the devices.

Research on calcium phosphates has attracted considerable attention in recent years. Calcium phosphates are the major inorganic constituents of biological hard tissues such as teeth and bones and other pathological minerals. Calcium phosphates have been widely produced in industry, in such forms as, ceramics, nutrient supplements, medicines, dentifrices, and stabilizers for plastics. They are utilized in solid state chemistry as fluorescent lamp phosphors and play a role in waste water treatment processes. Calcium phosphates are important in industrial water treatment (Le. , boiler and cooling) where deposition of these salts on heat exchanger surfaces can lead to loss of system efficiency, overheating, unscheduled shutdown time, and ultimately heat exchanger failures. Effective control of calcium phosphate deposits continue to challenge the industrial scientist. Calcium phosphate deposits have also been encountered during pasteurization of milk. Calcium phosphates of interest include: dicalcium phosphate dihydrate (DCPD, CaHP0-2H0), brushite; dicalcium phosphate anhydrous (DCP, CaHP0), 4 2 4 monetite; octacalcium phosphate (OCP, CasH2(P04)6-SH20); tricalcium phosphate (TCP, Ca3(P04h), whitlockite; and hydroxyapatite (HAP, Cas(P04h0H). Other calcium compounds of biological and industrial interest include: amorphous calcium phosphate (ACP); fluorapatite (FAP, CaS(P04)~); calcium pyrophosphate dihydrate (CPPD, CaP07-2H0); calcium fluoride; and calcium phosphonates. 2 2 2 This book is intended to provide a comprehensive discussion on calcium phosphates in the diverse areas of their investigations.

The purpose of Oxide-Based Fiber-Reinforced Ceramic-Matrix Composites is to provide comprehensive information on the most recent successful findings. The book consists of six chapters which characterize the current state of the art concerning oxide-based fiber-reinforced composites. Chapter one provides an introduction, examples of application areas and background information. Chapter two deals with the primary material properties for the areas of application and lists the possible constituent parts of the composites, depending on particular demands. Chapter three explains both the past and present fabrication methods which can affect the performance of the composites. Chapter four defines the interphase-related phenomena and describes the mechanical characteristics of the oxide-based fiber-reinforced composite, produced with different interphases. Chapter five deals with the fabrication route, functionality and mechanical characterization of the porous-matrix composites. The last chapter summarizes the present achievements and identifies requirements for reaching the goal, thereby providing a promising course for future research.

This publication presents the proceedings of ICPMSE-3, the third international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 25-26, 1996. The conference was hosted and organized by Integrity Testing Laboratory Inc, (ITL), and held at the University of Toronto's Institute for Aerospace Studies (UTIAS), where ITL is located. Twenty industrial companies, seven wliversities and eight government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 55 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-five speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space, Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories of major aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment, These proceedings are organized into four sections: a) AONOV and Radiation Effects on Materials and Structures in the Leo Space Environment; b) Interaction of Matter with the LEO Environment; c) Large Scale Coating Process Developments for Protection in LEO; d) Synthesis and Modification of Materials and Surfaces for Protection in LEO, This is the third in our on-going series of bi-annual international space materials conferences wllich began in 1992 in Toronto. Jacob Kleiman, Integrity Testing Laboratory Inc.