Single-Atom Catalysis: A Forthcoming Revolution in Chemistry reviews the latest developments, including whether or not this technology can become a technically and economically viable choice and whether existing challenges can be overcome to encourage its uptake. Beginning with an introduction to single-atom catalysis and current developments in the field, the book then reviews its role in potentially disruptive technologies, with a particular focus on applications in synthetic organic chemistry, solar hydrogen technologies and low platinum/platinum-free fuel cells. Other sections cover the steps needed for single-atom catalysis to become an industrially viable technology and its future outlook. Based on the extensive experience of its award-winning author, this book provides an authoritative guide on this novel approach.

Technical advances in probing surface chemistry with photoelectron spectroscopy under ambient pressures and at buried interfaces enables us to capture information on the chemical state under conditions close to real life applications. Meanwhile time-resolved XAS and XES provide the capability of capturing snapshots of the electronic structure of surface states in the femtosecond time regime allowing us to probe reaction pathways with unprecedented precision. There is also a transformation in access to these techniques. These new approaches are changing our understanding of surface chemistry in an extremely diverse range of applications, from device manufacture to in-vivo sensing to catalysis. It is very timely to consider this new knowledge emerging and explore the potential applications of these tools to other areas. Join international leaders in the field as they explore and exchange ideas about the key aspects of surface science, helping to develop the roadmap to shape the surface chemistry landscape for the years ahead. The topics covered include: In-situ methods: discoveries and challenges Buried interfaces Time resolved surface analysis (kinetic and molecular timescales) Future directions

Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects.

Nanocomposite Structures and Dispersions deals with the preparation of gelled, branched and crosslinked nanostructured polymers in the solution free radical polymerization and controlled/living radical polymerization and polymer and composite nanoparticles and nanostructures in disperse systems, the kinetics of direct and inverse disperse polymerizations (microemulsion, miniemulsion, emulsion, dispersion and suspension polymerization), the bottom-up approach building of functionalized nanoparticles, modelling of radical microemulsion polymerization, the characterization of traditional and non-traditional polymer dispersions, the collective properties of nanomaterials and their (bio)applications. This book is designed to bridge that gap and offers several unique features. First, it is written as an introduction to and survey of nanomaterials with a careful balance between basics and advanced topics. Thus, it is suitable for both beginners and experts, including graduate and upper-level undergraduate students. Second, it strives to balance the colloidal aspects of nanomaterials with physical principles. Third, the book highlights nanomaterial based architectures including composite or hybrid conjugates rather than only isolated nanoparticles. A number of ligands have been utilized to biodecorate the polymer and composite nanocarriers. Finally, the book provides an in depth discussion of important examples of reaction mechanisms of bottom-up building of functionalized nanoparticles, or potential applications of nanoarchitectures, ranging from physical to chemical and biological systems.

Radioactivity in the Environment, Second Edition, presents the facts on the presence of both natural and manmade radionuclides in the environment. Sources of ionizing radiation that can lead to human exposure are discussed, including natural sources, nuclear explosions, nuclear power generation, the use of radiation in medical, industrial and research purposes, and radiation-emitting consumer products. In this thoroughly updated edition, users will find new sections on developments in radioactive nuclides in nature and technologically modified exposure to natural radiation, new threats by terrorist individuals, groups and countries, changes to the status of nuclear power in the world, and more. Additional new sections cover radioisotopes in geo-prospecting and the oil industry, the use of radiation in environmental protection, detector types and detectors used for personal dosimetry, the "Dirty Bomb", the Fukushima accident, and North Korea testing sites and nuclear capabilities.

Chemistry of Silica and Zeolite-Based Materials covers a wide range of topics related to silica-based materials from design and synthesis to applications in different fields of science and technology. Since silica is transparent and inert to the light, it is a very attractive host material for constructing artificial photosynthesis systems. As an earth-abundant oxide, silica is an ideal and basic material for application of various oxides, and the science and technology of silica-based materials are fundamentally important for understanding other oxide-based materials. The book examines nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, photonics, photosensors, photovoltaics, energy, environmental sciences, drug delivery, and health. Written by a highly experienced and internationally renowned team from around the world, Chemistry of Silica and Zeolite-Based Materials is ideal for chemists, materials scientists, chemical engineers, physicists, biologists, biomedical sciences, environmental scientists, toxicologists, and pharma scientists. --- "The enormous versatility of silica for building a large variety of materials with unique properties has been very well illustrated in this book.... The reader will be exposed to numerous potential applications of these materials - from photocatalytic, optical and electronic applications, to chemical reactivity in confined spaces and biological applications. This book is of clear interest not only to PhD students and postdocs, but also to researchers in this field seeking an understanding of the possible applications of meso and microporous silica-derived materials." - Professor Avelino Corma, Institute of Chemical Technology (ITQ-CSIC) and Polytechnical University of Valencia, Spain

Quantum theory and computational chemistry have become integral to the fields of chemistry, chemical engineering, and materials chemistry. Concepts of chemical bonding, band structure, material properties, and interactions between light and matter at the molecular scale tend to be expressed in the framework of orbital theory, even when numerical calculations go beyond simple orbital models. Yet, the connections between these theoretical models and experimental observations are often unclear. It is important-now more than ever-that students master quantum theory if they are going to apply chemical concepts. In this book, Jochen Autschbach connects the abstract with the concrete in an elegant way, creating a guiding text for scholars and students alike. Quantum Theory for Chemical Applications covers the quantum theory of atoms, molecules, and extended periodic systems. Autschbach goes beyond standard textbooks by connecting the molecular and band structure perspectives, covering response theory, and more. The book is broken into four parts: Basic Theoretical Concepts; Atomic, Molecular, and Crystal Orbitals; Further Basic Concepts of Quantum Theory; and Advanced Topics, such as relativistic quantum chemistry and molecule-light interactions. The foresight Autschbach provides is immense, and he sets up a solid theoretical background for nearly every quantum chemistry method used in contemporary research. Because quantum theory tells us what the electrons do in atoms, molecules, and extended systems, the pages in this book are full of answers to questions both long-held and never-before considered.

This book is a collection of essays, written by an international group of historians of chemistry, about some of the most interesting chemists dating back into the 18th century. The contributing authors are well-established biographers, and their subjects make a diverse cast of chemistry characters. Among the chemists covered are Robert Bunsen, Joseph Black, John Dalton, Lucretia Borgia, William Crookes, and Humphry Davy. These chemists come from all over the world, and from different eras. Together, this collection truly is a celebration of the wide range of personalities and characters that have worked in chemistry over the centuries.

Mip Synthesis, Characteristics and Analytical Application, Volume 86 in the Comprehensive Analytical Chemistry series, highlights advances in the field, with this new volume presenting interesting chapters on synthesis and polymerization techniques of molecularly imprinted polymers, Solid phase extraction technique as a general field of application of molecularly imprinted polymer materials, Advanced artificially receptor- based sorbents for solid phase extraction using molecular imprinting technology: a new trend in food analysis, Application of molecularly imprinted polymers in microextraction and solventless extraction techniques, Magnetic molecularly imprinted microspheres - analytical approach, Surface Imprinted Micro- and Nanoparticles, and much more.

Advances in Organometallic Chemistry, Volume 80, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, with this updated release including chapters on Organometallic-like reactivity of group 10 metal-heteroatom sigma bonds, Organometallic interactions between metal nanoparticles and carbon-based molecules: a surface reactivity rationale, Group VI Allenylidene Complexes, and more.

Advances in Clinical Chemistry, Volume 114, the latest installment in this internationally acclaimed series, contains chapters authored by world-renowned clinical laboratory scientists, physicians and research scientists.

Annual Reports on NMR Spectroscopy, Volume 97, provides an in-depth accounting of progress in nuclear magnetic resonance (NMR) spectroscopy and its many applications. In recent years, no other technique has gained as much significance. It is used in all branches of science in which precise structural determination is required, and in which the nature of interactions and reactions in solution is being studied. This book has established itself as a premier resource for both specialists and non-specialists who are looking to become familiar with new techniques and applications pertaining to NMR spectroscopy.

Imides: Medicinal, Agricultural, Synthetic Applications and Natural Products Chemistry provides a comprehensive overview of imides being developed as pharmaceuticals or experimental therapeutics. Featuring a diverse range of experts in the field of imides, each chapter reviews the state-of-the-art, including the isolation and identification of naturally-occurring imides, as well as the total synthesis of imide natural products. As there is a need for a comprehensive review of imides as a class of naturally-occurring, biologically active molecules, this book will be invaluable to those in pharmaceuticals, academia, and anyone looking for clinical applications.

Fundamentals of Inorganic Glasses, Third Edition, is a comprehensive reference on the field of glass science and engineering that covers numerous, significant advances. This new edition includes the most recent advances in glass physics and chemistry, also discussing groundbreaking applications of glassy materials. It is suitable for upper level glass science courses and professional glass scientists and engineers at industrial and government labs. Fundamental concepts, chapter-ending problem sets, an emphasis on key ideas, and timely notes on suggested readings are all included. The book provides the breadth required of a comprehensive reference, offering coverage of the composition, structure and properties of inorganic glasses.

Natural Products as Anticancer Agents introduces the different types of natural products that have been used for cancer treatment. Divided into four parts, covering anticancer agents derived from terrestrial plants, anticancer agents derived from the marine environment, and anticancer agents derived from microorganisms, as well as evaluation of new anticancer agents, each part includes discussion of the properties, synthesis/extraction, storage, mechanism of action, and usage of the molecules. Discussion of the future prospects in anticancer natural products—including several new trends and an indication of where research in this area is likely to go in the future—is also included.

Advances in Organometallic Chemistry, Volume 71, contains authoritative review articles on researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. New chapters cover Titanium in Catalysis: Applications in Amine and N-Heterocycle Synthesis, Gold-alkynyl complexes for biomedical applications, Catalytic Nonreductive Valorization of Carbon Dioxide into Fine Chemicals, Transition-metal catalyzed CO2 hydrogenation in the presence of ionic liquids, and much more.