This series of monographs represents continuation on an international basis of the previous series MINERALOGIE UNO PETROGRAPHIE IN EINZELOARSTELLUNGEN, published by Springer-Verlag. The voluminous results arising from recent progress in pure and applied re search increase the need for authoritative reviews but the standard scientific journals are unable to provide the space for them. By their very nature, text-books are unable to consider specific topics in depth and recent research met'hods and results often receive only cursory treat ment. Advanced reference volumes are usually too detailed except for experts in the field. It is often very expensive to purchase a symposium volume or an "Advances in . . . " volume for the sake of a specific review chapter surrounded by unrelated chapters. We hope that this monograph series will by-pass these problems in fulfilling the need. The purpose of the series is to publish, at reasonable prices, reviews and reports of care fully selected topics written by carefully selected authors, who are both good writers and experts in their scientific field. In general, the mono graphs will be concerned with the most recent research methods and results. The editors hope that the monographs will serve several functions, acting as supplements to existing text-books, guiding research workers, and providing the basis for advanced seminars. August 1967 W. VON ENGELHARDT, Tiibingen T. HAHN, Aachen R. Roy, University Park, Pa. J. W. WINCHESTER, Ann Arbor, Mich. P. J. WYLLIE, Chicago, Ill."

Each gem deposit-whether of primary origin in the parent rocks; or secondary as alluvial placers in valley floors, river gravels, or the sand of oceanic shelves presents an eloquent chronicle of the Earth's life story. It reveals to the expert the prodigious processes which formed the present crust of our planet, of which this volume discloses a small but exciting detail. The materials of the Earth's crust are the rocks. In this book, the author expounds on how they were formed, why they altered, why they became the cradles of precious gemstones, how they are categorized, and how they are now exploited by man. What initiates the growth of gemstones? How do they crystallize? Why do gemstones of the same species, originating from different sources, vary? What causes the occurrence of varieties? Why do diamonds, unlike other precious stones, occur not near the Earth's surface in its crust, but deep down beneath it in the upper mantle? These are only a few of the entrancing subjects discussed in this enlightening volume. The reader learns that the Earth is surprisingly alive and altering constantly-sometimes through slow and equable changes and at times by violent and tremendous cataclysms, events from which gemstones issue.

Microscopy is a servant of all the sciences, and the microscopic examina tion of minerals is an important technique which should be mastered by all students of geology early in their careers. Advanced modern text books on both optics and mineralogy are available, and our intention is not that this new textbook should replace these but that it should serve as an introductory text or a first stepping-stone to the study of optical mineralogy. The present text has been written with full awareness that it will probably be used as a laboratory handbook, serving as a quick reference to the properties of minerals, but nevertheless care has been taken to present a systematic explanation of the use of the microscope as well as theoretical aspects of optical mineralogy. The book is therefore suitable for the novice either studying as an individual or participating in classwork. Both transmitted-light microscopy and reflected-light microscopy are dealt with, the former involving examination of transparent minerals in thin section and the latter involving examination of opaque minerals in polished section. Reflected-light microscopy is increasing in importance in undergraduate courses on ore mineralisation, but the main reason for combining the two aspects of microscopy is that it is no longer acceptable to neglect opaque minerals in the systematic petrographic study of rocks. Dual purpose microscopes incorporating transmitted- and reflected-light modes are readily available, and these are ideal for the study of polished thin sections."

1 2 J. H. SCHROEDER and B. H. PURSER 1 Introduction A symposium convened during the Vth International Coral Reef Congress in Papeete, Tahiti, 1985, encouraged the editors to assemble this volume of case studies by participating and, especially, by nonparticipating scientists. An attempt was made to include case studies from various regions and geological periods, carried out on various scales from regional to ultrastructural. We hope to present an overall view of reef diagenesis. Although the volume focuses on reef diagenesis, fields also to be considered are biology, paleontology, and sedimentary facies distribution, as they provide the context and, to some extent, encompass the determinants of diagenetic processes. The scope has been limited to reef diagenesis because we feel that reefs have relatively clearly defined geometries, which facilitate the evaluation of diagenetic trends and the definition of diagenetic models. On the other hand, their many different components make reefs somewhat more complex than other deposits, and this creates difficulties in deciphering diagenetic histories; the study of reefs, therefore, is not the simplest manner of solving the many problems relating to carbonate diagenesis. An additional reason for evaluating reef diagenesis is the reservoir potential of these carbonate bodies. To illustrate the point, in the recent collection of 35 case studies of carbonate reservoirs (Roehl and Choquette 1985), reefs were involved in 15. The emphasis on porosity development in many studies of the present volume is therefore not of mere academic interest.

The establishment of relationships between sediment composition and climatic - vironment in the sediment basin and subsequent evolution of climate relates to the classical problems of fundamental sedimentology. The widely known publications by the Russian academicians N. M. Strakhov, A. B. Ronov, and A. P. Lisitsin are dedicated to different aspects of this problem. In particular, the monograph p- lished by A. P. Lisitsin "Sea-ice and iceberg sedimentation in the Ocean: recent and past" (Lisitsin, 2002) closely corresponds to the issues examined in this book. This monograph discusses in detail the environments and means of accumulations of recent marine and oceanic sediments in the ice zone of sedimentation of the Ocean, however, much less attention is given to the history of ice sedimentation, especially to high-resolution paleoceanography. In the present work the authors accepted the following basic principles: 1. StudynotonlyoftheArctic, butalsooftheSubarctic, especiallyofthoseregions, where there were conducted the original studies by the authors. 2. Study of climatic history in uence ( rst of all, - the glaciation evolution of NorthernHemisphere)on sedimentationforthe last 130ka (MIS5e - MIS1)not only in the marine periglacial environment (term of G. G. Matishov), but also in the deep water areas and on the adjacent continental blocks. 3. Imperative description of recent sedimentation environment for subsequent - plication of the comparative-lithologicalmethod. 4. Detailed consideration of accessible stratigraphic and geo-chronometricdata for partition and correlation of various sedimentary facies. Some of the above-mentionedprinciples require further explanation.

Considerable progress has been made in our understanding of the physicochemical evolution of natural rocks through systematic analysis of the compositional properties and phase relations of their mineral assemblages. This book brings together concepts of classical thermodynamics, solution models, and atomic ordering and interactions that constitute a major basis of such analysis, with appropiate examples of application to subsolidus petrological problems. This book is written for an audience with a senior undergraduate level background in chemistry. Derivations of fundamental thermodynamic relations which are in need of reemphasis and clarification are presented.

It is a pleasure to any author to enlarge the circle of his readers. Naturally this is a pleasure to me. At the same time, however, misgivings arise: whether these pages will con vey to the circle of new readers the thoughts that excite the author. Science is advancing rapidly in our day. It is already apparent that many things in the book should have been stated differently. I have tried to make additions to the English-language edition in such a way that they do not require great alteration of the text. I ask my new readers to remember that this book was written primarily for my fellow countrymen and that, because of this, some chapters contain descriptions of regions little known to you and information on the USSR almost unknown from other publications. I hope that, despite this, geologists who read the English-language edition will find something of interest to themselves in it and that their labor will not have been in vain. Yu. M. Sheinmann Institute of Phys ics of the Earth Moscow v PREFACE The study of endogenetic processes has long pushed us into investigation of ever deeper parts of the earth. Not long ago all attention was focused on depths where ore deposits appear, where metamorphic and igneous rocks, which later become exposed at the surface, are formed, where granites originate."

Time is a major factor in Quaternary science. Without a trustworthy chronometer any interpretation of changes in proxy data of stratigraphical origin is on weak ground. In fact, any attempt at a sound reconstruction of timing and rates of past climatic change as well as the response of the biosphere can only be achieved on the basis of a reliable chronology. Moreover, all correlations and comparisons through time on a continental or global scale depend heavily on the reliability of the time-scale used. Therefore the establishment of an absolute time-scale is a fundamental goal. In this contribution we refer to the term "absolute time-scale" as a time-scale consisting of ages determined on the basis of sidereal years. Traditional stratigraphical methods of absolute dating include the Swedish glacial varve chronology, already developed early in this century by De Geer (1912) and since then continuously improved (e.g. Stromberg 1985; Cato 1987). Unfortunately, however, a spatial correlation with other stratigraphies outside Fennoscandia is difficult.

Drilling deep into the earth holds a fascination for earth scientists derived in part from the fact that the drill hole is the ultimate test of a hypothesis. When surface exploration methods have been fully uti lized and all the geological inferences drawn about the structure be neath the surface, we must finally drill to sample directly the third dimension of the crust of the earth. The drill is thus the tool of choice of the energy and minerals re sources industry. Because of high cost, drilling has been only sparing ly used for solving fundamental problems in the earth sciences. But now, having used the quite sophisticated methodology of exploration geophysics, the exciting structural detail emerging from seismic re flection profiling in particular has led several nations to begin a major program of scientific drilling to solve some of the major prGb lems in the earth sciences. Hhat is described in this volume are the blueprints for national re search programs in France, the Federal Republic of Germany, Japan and the United States. The Soviet Union has already embarked on a major drilling effort, the results of which are soon to be published. Results, of course, are still few, and this first volume is more concerned with the problems to be solved."

Only a few years ago, if you needed an appraisal of The revolution in the personal property appraisals gems and jewelry for any reason, you asked your local field (of which jewelry is a part) is a little more than a jeweler, who hastily scribbled a one-line handwritten decade old. There now exist uniform standards and note. He or she usually performed the appraisal for procedures for personal property appraisers, classes free, and did so with reluctance, accommodating you in valuation techniques, and degree programs in the only because as a customer you held the promise of a valuation sciences. future sale. The price your jeweler may have assigned Professional jewelry appraisers are on the edge of to the jewelry was granted without the least regard a new vocation. Banks, insurance companies, and for market research, legalities, or ethics. In most in governmental agencies have all helped bring about stances, the estimate was no more than a properly the changes and contribute to the birth of the profes completed sales receipt. sion; they have realized that they can demand and Gemologists were usually pushed into the role of get high standards of performance and integrity from appraiser by their jeweler employers, who were eager jewelry appraisers, as they can from appraisers of real to gain an advantage over their competitors by adver property."

Few knowledgeable people would deny that the field of mineral exploration is facing some difficult times in the foreseeable future. Among the woes, we can cite a worldwide economic uneasiness reflected by sluggish and at times widely fluctuating metal prices, global financial uncertainties, and relentless pressures on costs despite a substantial slowing down of the rate of inflation. Furthermore, management is forced to tum to more sophisticated and expensive technologies and to look farther afield to more remote regions, as the better quality and more easily accessible ore deposits have now been revealed. This rather gloomy outlook should persuade explorationists to cast about for a new philosophy with which to guide mineral exploration through the challenging decades ahead. Once already, in the early 1960s, a call for change had been heard (Ref. 30 in Chapter 1), when it became obvious that the prospecting methods of yesteryear, so successful in the past, could not keep up with the rapidly growing demand for minerals of the postwar period. The answer, a massive introduction of sophisticated geophysical and geochemical technologies backed by new geo logical models, proved spectacularly successful throughout the 1960s and the 1970s. But for both economic and technological reasons, the brisk pace of the last two decades has considerably slowed down in the early 1980s, as if a new threshold has been reached."

The reserves, or extractable fraction, of the fuel-mineral endowment are sufficient to supply the bulk of the world's energy requirements for the immediately forseeable future-well into the next century according to even the most pessimistic predictions. But increasingly sophisticated exploration concepts and technology must be employed to maintain and, if possible, add to the reserve base. Most of the world's fuel-mineral resources are in sedimentary rocks. Any procedure or concept that helps describe, under stand, and predict the external geometry and internal attributes of major sedimentary units can therefore contribute to discovery and recovery of coal, uranium, and petroleum. While conceding the desirability of renewable and nonpolluting energy supply from gravitational, wind, or solar sources, the widespread deployment of these systems lies far in the future-thus the continued commercial emphasis on conventional nonrenewable fuel mineral resources, even though their relative significance will fluctuate with time. For example, a decade ago the progilostications for uranium were uniformly optimistic. But in the early 1980s the uranium picture is quite sombre, although unlikely to remain permanently depressed. Whether uranium soars to the heights of early expectations remains to be seen. Problems of waste disposal and public acceptance persist. Fusion reactors may ultimately eliminate the need for uranium in power generation, but for the next few decades there will be continued demand for uranium to fuel existing power plants and those that come on stream. This book is, to some extent, a hybrid."

This book represents a revision and expansion of an earlier set of diagrams for tempera 0 0 tures from 25 to 300 C along the equilibrium vapor-liquid curve for H 0 (Helgeson, Brown, 2 and Leeper, 1969). The activity diagrams summarized in the following pages were generated over a six year period from 1977 to 1983 in the Laboratory of Theoretical Geochemistry (oth erwise known as Prediction Centra ) at the University of California, Berkeley. They represent the culmination of research efforts to generate a comprehensive and internally consistent set of thermodynamic data and equations for minerals, gases, and aqueous solutions at high pres sures and temperatures. Among the many who contributed to the successful completion of this book, we are especially indebted to David Kirkham, John Walther, and George Flowers, who wrote program SUPCRT, Tom Brown, who created program DIAGRAM, and Eli Mess inger, who generated the Tektronix plot routine to construct the diagrams. Ken Jackson and Terri Bowers both devoted an enormous amount of time and effort over the past six years to produce the diagrams in the following pages; some of which went through many stages of revision. Consequently, they appear as senior authors of this volume. It should be mentioned in this regard that their equal dedication to the project made it necessary to determine their order of authorship by flipping a coin."

Cratons and Fold Belts of India, is a unique attempt at presenting geological characteristics and evolution of the fold belts and the cratonic areas of the Indian shield. The author has evaluated the different evolutionary models for each fold belt in light of all the currently available geological and geochronological informations that are clearly listed. Shortcomings, if any, of each model are stated and a viable geodynamic model is presented for each fold belt. The book is self-contained it includes an introduction to the processes of mountain building, especially plate tectonics theory with its application to the evolution of the Himalaya as an illustrative example so that the reader can better appreciate the novel approach to the evolution of Proterozoic fold belts. The author eschews a detailed account of the fold belts for a clear description of all the concepts that go into building models. It is primarily written for graduate students, teachers and for those geoscientists who aspire to know all about the Indian shield."

This monograph has its origins in a two-day meeting with the same title held in London, England in the spring of 1987. The idea for the meeting came from members of the UK Mineral and Rock Physics Group. It was held under the auspices of, and made possible by the generous support of, the Mineralogical Society of Great Britain and Ireland. Additional financial assistance was provided by ECC International pIc and the Cookson Group pIc. The aims of the London meeting were to survey the current state of knowledge about deformation processes in non-metallic materials and to bring together both experts and less experienced Earth scientists and ceramicists who normally had little contact but shared common interests in deformation mechanisms. This monograph has similar aims and, indeed, most of its authors were keynote speakers at the meeting. Consequently, most of the contributions contain a review element in addition to the presentation and discussion of new results. In adopting this format, the editors hope that the monograph will provide a valuable state-of-the-art sourcebook, both to active researchers and also to graduate students just starting in the relevant fields.

One of the fundamental objectives of physical geochemistry is to understand the evolution of geochemical systems from microscopic to regional and global scales. At present there seems to be a general recognition of the fact that internal properties of minerals record important aspects of the evolutionary history of their host rocks which may be unraveled by very fine scale observations. A major focus in the development of geochemical research in the last thirty years has been the application of classical thermodynamics to reconstruct the conditions at which the states of quenched mineralogical properties of rocks have equilibrated during the course of their evolution. While these works have funda mentally influenced our understanding ofthe physico-chemical history ofrocks, in recent years petrologists, mineralogists, and geochemists have been making greater efforts towards the application of kinetic theories in order to develop a better appreciation of the temporal details of geochemical processes. The present volume brings together a variety of current research on transport in systems of geochemical interest from atomic to outcrop scales. A major theme is atomic migration or diffusion, and its various manifestations on microscopic and macroscopic scales. Transport in the solid state is controlled by diffusion and is responsible for the states of atomic ordering and relaxation of composi tional zoning in minerals, development of compositional zoning during cooling, exsolution lamellae, and creep."

Phenomenal new observations from Earth-based telescopes and Mars-based orbiters, landers, and rovers have dramatically advanced our understanding of the past environments on Mars. These include the first global-scale infrared and reflectance spectroscopic maps of the surface, leading to the discovery of key minerals indicative of specific past climate conditions; the discovery of large reservoirs of subsurface water ice; and the detailed in situ roving investigations of three new landing sites. This an important, new overview of the compositional and mineralogic properties of Mars since the last major study published in 1992. An exciting resource for all researchers and students in planetary science, astronomy, space exploration, planetary geology, and planetary geochemistry where specialized terms are explained to be easily understood by all who are just entering the field.

Early in this century, the newly discovered x-ray diffraction by crystals made a complete change in crystallography and in the whole science of the atomic structure of matter, thus giving a new impetus to the development of solid-state physics. Crystallographic methods, pri marily x-ray diffraction analysis, penetrated into materials sciences, mol ecular physics, and chemistry, and also into many other branches of science. Later, electron and neutron diffraction structure analyses be came important since they not only complement x-ray data, but also supply new information on the atomic and the real structure of crystals. Electron microscopy and other modern methods of investigating mat ter-optical, electronic paramagnetic, nuclear magnetic, and other res onance techniques-yield a large amount of information on the atomic, electronic, and real crystal structures. Crystal physics has also undergone vigorous development. Many re markable phenomena have been discovered in crystals and then found various practical applications. Other important factors promoting the development of crystallog raphy were the elaboration of the theory of crystal growth (which brought crystallography closer to thermodynamics and physical chem istry) and the development of the various methods of growing synthetic crystals dictated by practical needs. Man-made crystals became increas ingly important for physical investigations, and they rapidly invaded technology. The production of synthetic crystals made a tremendous impact on the traditional branches: the mechanical treatment of mate rials, precision instrument making, and the jewelry industry.

Do changes in stratospheric ozone relate to changes in UV-B irradiance and do both relate to life on Earth? This volume presents the latest data available in the basic scientific disciplines associated with these questions. The key topics are the interactive factors between the various research elements and the measurements needed to both validate ozone depletion and monitor UV flux changes in the biosphere.

This book is a result of a career spent developing and applying computer techniques for the geosciences. The need for a geoscience modeling reference became apparent during participation in several workshops and conferences on the subject in the last three years. For organizing these, and for the lively discussions that ensued and inevitably contributed to the contents, I thank Keith Turner, Brian Kelk, George Pflug and Johnathan Raper. The total number of colleagues who contributed in various ways over the preceding years to the concepts and techniques presented is beyond count. The book is dedicated to all of them. Compilation of the book would have been impossible without assistance from a number of colleagues who contributed directly. In particular, Ed Rychkun, Joe Ringwald, Dave Elliott, Tom Fisher and Richard Saccany reviewed parts of the text and contributed valuable comment. Mohan Srivastava reviewed and contributed to some of the geostatistical presentations. Mark Stoakes, Peter Dettlaff and Simon Wigzell assisted with computer processing of the many application examples. Anar Khanji and Randal Crombe assisted in preparation of the text and computer images. Klaus Lamers assisted with printing. The US Geological Survey, the British Columbia Ministry of Environment, Dave Elliott and others provided data for the application examples. My sincere thanks to all of them.

This special publication no. 4 of the European Association of Petroleum Geoscientists and Engineers is devoted to some recent developments in the petroleum geology of France. Most of the papers have been presented either as oral or poster communications at the special session "Hydrocarbons of France" of the EAEG - EAPG Paris Conference (June, 92). A few additional papers have been added for their thematic interest, such as recent advances in sequence stratigraphy and structural geology applied to exploration of oil and gas in complex areas. Synthetic papers are also presented, covering most of the French sedimentary basins including a few oversea French agreements and territories.

At attempt is made here to provide a comprehensive The Basement "massifs" roughly delimit the main account in book form of the Petroleum Geology of sedimentary areas of the: Nigeria, a country which in 1979 was the world's 1. ABAKALIKI, BENUE, GONGOLA AND YOLA sixth largest oil producer and rated the twelfth gIant TROUGHS petroleum province of the world by Ivanhoe (1980) 2. BIDA OR MIDDLE NIGER BASIN in terms of known recoverable resources (cumulatIve 3. SOKOTO EMBAYMENT OF THE IULLEM production + proven + probable reserves) of oil and MEDEN BASIN 4. BORNU-CHAD BASIN gas. . 5. DAHOMEY BASIN Nigeria, which has been an indepe. ndent sovereIgn country since 1960, faces the AtlantIc Ocean on the These basins and troughs, taken together with the south, is bounded by the Peoples' Republic of Benin onshore part of the Nigeria Delta Complex, occupy (ex-Dahomey) on the west, by the Republic of Niger about 178 000 square miles, half the total area of and by the Sahara on the north, the Republic of Chad Nigeria. Figure 3 shows the area of Nigeria in com on the northeast, and is bounded by the Umted Re parison to areas of other well known petroleum public of Cameroun on the east. It now consists of provinces and units, such as the Gulf. Coast of. the 19 states organized in a federation and, largely be United States, North Sea etc."

This book is intended primarily for exploration geologists and post graduate students attending specialist courses in mineral exploration. Exploration geologists are engaged not only in the search for new mineral deposits, but also in the extension and re-assessment of existing ones. To succeed in these tasks, the exploration geologist is required to be a "generalist" of the Earth sciences rather than a specialist. The exploration geologist needs to be familiar with most aspects of the geology of ore deposits, and detailed knowledge as well as experience play an all important role in the successful exploration for mineral commodities. In order to achieve this, it is essential that the exploration geologist be up to date with the latest developments in the evolution of concepts and ideas in the Earth sciences. This is no easy task, as thousands of publications appear every year in an ever increasing number of journals, periodicals and books. For this reason it is also difficult, at times, to locate appropriate references on a particular mineral deposit type, although this problem is alleviated by the existence of large bibliographic data bases of geological records, abstracts and papers on computers. During my teaching to explorationists and, indeed, during my years of work as an explorationist, the necessity of having a text dealing with the fundamental aspects of hydrothermal mineral deposits has always been compelling. Metallic mineral deposits can be categorised into three great families, namely: (I) magmatic; (2) sedimentary and residual; (3) hydrothermal."

The present work. Authigenic Minerals in Sedimentary Rocks, is designed for the broad circle of lithologists, and also for the geologists and geochemists who are studying sedimentary rocks and ores. Its specific purpose is to stir up interest among lithologists and geologists in the geochemical environment associated with the formation of authigenic minerals in sedimentary rocks, to encourage work in tracing the sequence of formation of these min erals, and to direct attention to other genetic problems. The book by no means pretends to be a determinative atlas of the authigenic minerals in sedimentary rocks; its task is to draw the reader's attention to questions of origin and, at the same time, to equip him with systematic knowledge about the physical and, especially, the optical properties of these minerals. In addition, the simplified chemical reactions indicated in the book wiIl permit one to distinguish similar minerals, and will also allow him to detect various mineral deposits in the field. Another purpose of the book is to acquaint chemists and geochemists with the properties of the minerals they study in making chemical analyses, minerals that com monly occur as polymineralic aggregates in the samples that are examined."