Mine Safety combines detailed information on safety in mining with methods and mathematics that can be used to preserve human life.

By compiling various recent research results and data into one volume, Mine Safety eliminates the need to consult many diverse sources in order to obtain vital information. Chapters cover a broad range of topics, including: human factors and error in mine safety, mining equipment safety, safety in offshore industry and programmable electronic mining system safety.

They are written in such a manner that the reader requires no previous knowledge to understand their contents. Examples and solutions are given at appropriate places, and there are numerous problems to test the reader's comprehension.

Mine Safety will prove useful for many individuals, including engineering and safety professionals working in the mining industry, researchers, instructors, and undergraduate and graduate students in the field of mining engineering.

Granite petrology has achieved significant progress since Tuttle and Bowen (1958) wrote the monograph on the Origin of granite in the light of experimental studies in the system NaAISi308-KAISi308-SiOrH20. Since then, the compo nents CaAI Si 0, FeO, MgO, and excess alumina have 2 2 s been added to the pure system Ab-Or-Qz-H 0 in order to 2 include plagioclase and common mafic minerals in the inves tigations. In addition to synthetic systems, natural rocks have been used as starting materials, and other fluid compo or substituted for water. nents have been added to There are many new data concerning properties of melts and magmas, dehydration melting of synthetic and natural rocks, and phase relationships at H 0-undersaturated con 2 ditions. We found it useful and necessary to summarize the available information in this volume, and an effort has been made to present up-to-date data on various aspects of gran ite petrology. Most parts of the manuscript were reviewed by John Clemens, Peter Nabelek, and Alan White. Their friendly help and suggestions improved it considerably. Some chap ters of this volume benefited from critical review by William Brown, Bruno Scaillet, and Robert Linnen. Peter Wyllie pro vided us with reprints and many critical and useful sugges tions. Jagmohan Singh improved the English considerably."

The most renowned naval officer of the mid-nineteenth century, Thomas Cochrane, Tenth Earl of Dundonald (1775-1860), served in wars against Spain and France, retiring as an admiral in the Royal Navy. He was also an M.P., vociferously calling for naval reform in Parliament. Due to a financial scandal, he left the Royal Navy for a period and became a celebrated mercenary, commanding naval forces in the wars of independence of Chile, Peru, Brazil and Greece. First published in 1851, this work contains notes on a voyage of 1849 around the West Indies and North America. Describing the peoples and geography encountered, it offers progressive remarks on the end of slavery, criticisms of plantation owners, and suggestions for commercial improvements. The book remains of enduring interest to scholars of naval, colonial and Caribbean history.

Many people have contributed to the production of this book, and I wish to acknowledge the following colleagues who have, over the past 15 years, contributed much discussion, preprints, thin sections, rock samples, and unpublished and/or difficult-to- obtain information: Steve Bergman, Roger Clement, Howard Coopersmith, Barry Dawson, Alan Edgar, Tony Erlank, Steve Haggerty, Barry Hawthorne, Bram Janse, Viktoria Komilova, Sergei Kostrovitskii, Henry Meyer, Peter Nixon, Nick Rock, Mike Skinner, Patricia Sheahan, Simon Shee, Barbara Scott Smith, Andy Spriggs, Ken Tainton, Larry Taylor, Nikolai Vladykin, Allan Woolley, and Peter Wyllie. Special thanks go to Henry Meyer, for providing many hours of microprobe time at Purdue University, and to Mike Skinner, for samples and the opportunity to examine the Anglo-American Research Laboratory collection of orangeites. Particular thanks are expressed to Ken Tainton for permission to quote data from his Ph.D. thesis. Particular gratitude is expressed to Sam Spivak for drafting and photographic work and to Anne Hammond for preparing many polished thin sections of these difficult rocks. Their dedication, skills, and attention to detail are greatly appreciated by the author. Others from Lakehead University who helped materially during the production of this work include Reino Viitala (thin sections), Alan MacKenzie (electron microscopy), and Shelley Moogk-Pickard (trace element analysis). Carl Hager is thanked for assistance in using the Purdue microprobe.

Volume 4 focuses on the vibrant research area centering around "Biomineralization" and its role in Nature and in biomimetic applications. With nearly 2700 references, 14 tables, and more than 140 illustrations, it is an essential resource for scientists working in the wide range from material sciences and inorganic biochemistry all the way through to medicine including the clinic.

In 18 stimulating chapters, written by 36 internationally recognized experts, "Biomineralization. From Nature to Application" highlights critically the interrelations between crystals and life. The volume covers the role of genes and genomes as well as enzymes on biomineralization processes; carbonate, sulfate, oxalate, and silicate biominerals; heavy metals, ferritin, and magnetotactic bacteria; the formation of bone, dentin, enamel, etc; the dynamics of biomineralization and biodemineralization; the mechanical design and bioinspired growth of mineralized tissues; and polymer-controlled biomimetic mineralizations for diverse applications.

This monograph was begun with two objectives in mind. The first was to provide a review of research involving the application of neodymium isotopic measurements to pro blems in earth science. In the process of organizing to do this, I realized that the research in this field had produced a need for an updated review of the underlying paradigms. This need had arisen because of the special properties of the samarium-neodymium isotopic system, and because the research had transgressed the traditional boundaries be tween the subfields of earth science. Without such a review, the significance of the results seemed likely to remain un necessarily obscure to interested scientists from related disciplines. Consequently, the second objective became the provision of a theoretical framework for the application of neodymium isotopic studies. Much of what this contains is not new, but it is drawn together here for the first time. At the time the writing was initiated, the literature of the field was still relatively limited. Over the past 5 years it has grown enormously. Considering the rate at which the writing progressed, it became clear that this could not be a fully up-to-date review and still reach completion. The selection of material for the review sections is biased toward earlier studies. Part I presents most of the background information."

During the last thirty years profound developments in expe- rimental techniques to measure high temperature and pressu- res and thermodynamic properties of minerals have occurred. This technical development has been matched by an increased sophistication in applying theoretical methods to obtain new data or improve the quality of existing data. Using these newtechniques, Assessed Thermodynamic Data on Oxides and Silicates represents the successful attempt of the authors to develop an internally systematized data base which satis- fies the constraints of calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lat- tice vibrational models.

The reserves, or extractable fraction, of the fuel-mineral endowment are sufficient to supply the bulk of the world's energy requirements for the immediately forseeable future-well into the next century according to even the most pessimistic predictions. But increasingly sophisticated exploration concepts and technology must be employed to maintain and, if possible, add to the reserve base. Most of the world's fuel-mineral resources are in sedimentary rocks. Any procedure or concept that helps describe, under stand, and predict the external geometry and internal attributes of major sedimentary units can therefore contribute to discovery and recovery of coal, uranium, and petroleum. While conceding the desirability of renewable and nonpolluting energy supply from gravitational, wind, or solar sources, the widespread deployment of these systems lies far in the future-thus the continued commercial emphasis on conventional nonrenewable fuel mineral resources, even though their relative significance will fluctuate with time. For example, a decade ago the progilostications for uranium were uniformly optimistic. But in the early 1980s the uranium picture is quite sombre, although unlikely to remain permanently depressed. Whether uranium soars to the heights of early expectations remains to be seen. Problems of waste disposal and public acceptance persist. Fusion reactors may ultimately eliminate the need for uranium in power generation, but for the next few decades there will be continued demand for uranium to fuel existing power plants and those that come on stream. This book is, to some extent, a hybrid."

Few knowledgeable people would deny that the field of mineral exploration is facing some difficult times in the foreseeable future. Among the woes, we can cite a worldwide economic uneasiness reflected by sluggish and at times widely fluctuating metal prices, global financial uncertainties, and relentless pressures on costs despite a substantial slowing down of the rate of inflation. Furthermore, management is forced to tum to more sophisticated and expensive technologies and to look farther afield to more remote regions, as the better quality and more easily accessible ore deposits have now been revealed. This rather gloomy outlook should persuade explorationists to cast about for a new philosophy with which to guide mineral exploration through the challenging decades ahead. Once already, in the early 1960s, a call for change had been heard (Ref. 30 in Chapter 1), when it became obvious that the prospecting methods of yesteryear, so successful in the past, could not keep up with the rapidly growing demand for minerals of the postwar period. The answer, a massive introduction of sophisticated geophysical and geochemical technologies backed by new geo logical models, proved spectacularly successful throughout the 1960s and the 1970s. But for both economic and technological reasons, the brisk pace of the last two decades has considerably slowed down in the early 1980s, as if a new threshold has been reached."

Metals in the hydrological cycle represent a very broad subject covering all parts of the geological cycle. The present version of this book, therefore, would not have been possible without the comments and suggestions for improvement on draft ver- sions of the various chapters by a large number of colleagues. We wish to express our gratitude to: P.A. Cawse (AERE, UK), J.N. Galloway (University of Virginia, USA) and S.E. Lindberg (Oak Ridge National Labo- ratory, USA) for reviewing the chapter on atmospheric trace metals. G. Batley (CSIRO, Australia) and B.T. Hart (Chisholm In- stitute of Technology, Australia) for reviewing the chapter on speciation of dissolved metals. E.K. Duursma (Delta Institute, The Netherlands), J.M. Bewers and P.H. Yeats (Bedford Institute of Oceanography, Canada) and D. Eisma (Netherlands Institute for Sea Re- search, the Netherlands) for reviewing the chapter on estuaries. P. Baccini (EAWAG, Switzerland) and W. Davison (Fresh- water Biological Association, UK) for reviewing the chapter on lakes. E.T. Degens (University of Hamburg, W-Germany) for re- viewing the chapter on the oceans, and J.P. Al (Public Works Department, The Netherlands) for reviewing most of the indi- vidual chapters. Without the collaboration of these colleagues this book would not have been possible in its present form.

As natural minerals, silica and silicates constitute by far the largest part of the earth's crust and mantle. They are equally important as raw materials and as mass produced items. For this reason they have been the subject of scientific research by geoscientists as well as by applied scientists in cement, ceramic, glass, and other industries. Moreover, intensive fun damental research on silicates has been carried out for many years because silicates are, due to their enormous variability, ideally suited for the study of general chemical and crystallographic principles. Several excellent books on mineralogy and cement, ceramics, glass, etc. give brief, usually descriptive synopses of the structure of silicates, but do not contain detailed discussions of their structural chemistry. A number of monographs on special groups of silicates, such as the micas and clay min erals, amphiboles, feldspars, and zeolites have been published which con tain more crystal chemical information. However, no modern text has been published which is devoted to the structural chemistry of silicates as a whole. Within the last 2 decades experimental and theoretical methods have been so much improved to the extent that not only have a large number of silicate structures been accurately determined, but also a better under standing has been obtained of the correlation between the chemical composition of a silicate and its structure. Therefore, the time has been reached when a modern review of the structural chemistry of silicates has become necessary."

Phase transitions in minerals are of interest to a wide spectrum of scientists - geolo- gists, mineralogists, solid state chemists, and physicists. We have now reached the point where mean field theory or Landau Theory of phase transitions as a function of temperature, pressure, or chemical composition can be usefully applied to natural materials, resulting in an improved understanding of the thermodynamics of signifi- cant constituents of the earth. Given the chemical complexity of so many silicate solid solutions, there are two distinct approaches to the problems posed by common minerals: one is to con- centrate on model compounds which could be synthetic analogs or natural end- members; the other is to work on typical minerals, with all the disorder and inhomogeneity that this implies. Model compounds provide the elements needed to build up a realistic understanding of the thermodynamic behavior of natural inor- ganic materials in all their complexity. In the first part of the book, a number of papers are devoted to structural phase transitions in quartz, Na-and Ca-feldspars, MgSi0 perovskite, and PbI , where Landau Theory and lattice and molecular 3 2 dynamics have been used to explain or predict thermodynamic behavior. A different thermodynamic approach has been used to understand phase separation and atomic ordering in solid solutions such as olivines, pyroxenes, rhombohedral carbonates and oxides. E. Salje (Chapter 1) applies the Landau Theory for the second-order phase transi- tion to the feldspar end-members albite, NaAlSi0 , and anorthite, CaAlSi0 .

The idea for a book on anorthosites came to me in January of 1986 while returning to Houston after holiday festivities in Dallas. The original idea was a review paper on anorthosites, but by the time I reached Houston, the subject material I contemplated induding was obviously too extensive for a single paper. The Director of the Lunar and Planetary Institute, Kevin Burke, was receptive to the idea of a book, and suggested that I contact Peter Wyllie, who serves as Editor of the Springer-Verlag series Minerals and Rocks. This effort, which I originally expected would take about a year, has taken nearly 6. I have many excuses- indolence, moving to another continent, other commitments, etc.-but the basic truth is that writing a book is much larger an undertaking than can be anticipated. Many people are aware of this, and I was duly forewarned. . But why write a book on anorthosites? This is a very good question, which I have considered from many angles. One rationale can be expressed in terms of a comparison between anorthosite and basalt. A first-order understanding of basalt genesis has been extant for many years. By contrast, there is little agreement about the origin of anorthosite. There are good reasons for studying and writing about basalt: it is the most abundant rock type on the Earth's surface, and is also plentiful on the surfaces of the other terrestrial planets.

At last geochemists are offered one comprehensive reference book which gives the Eh-pH diagrams for 75 elements found in the earth's surface environment, including transuranic and other radioactive species. For each of these newly calculated diagrams short explanatory texts are added. For the first time the primary elements are considered in water with metal, sulfur, carbon, and other species as appropriate. Furthermore, based on these figures and up-to-date thermodynamic data presented in this reference, researchers can predict the behavior of elements in the surface environment. Geoscientists, chemists and environmental agencies will also benefit from several brief texts on the importance of various elements to problems of radioactive waste disposal.

33 14. 3. 5 REE between Plagioclase and Aqueous Fluid 0 Cullers et al. (1973) measured the distribution of REE at 850 C and 750 bars pressure between a natural plagioclase, An, and gaseous water. The rare earths 65 favored the plagioclase by a factor which varies from about 25 for Ce to 10 for Lu. Data were also obtained for forsterite, diopside, enstatite and two rhyolite glasses, on the one hand, and water on the other hand, thereby permitting estimation of the partition coefficients between all pairs of phases. 14. 4 Chemical Substitution in Natural Feldspars 14. 4. 1 Introduction It is quite impracticable to give all the data on chemical substitution in natural feldspars: indeed many of the details are significant only to some particular pegmatite or rock body. As far as possible, emphasis is placed on features of general interest to crystal chemists and to petrologists. Ironically the well established features can be described more easily than the uncertain ones, and unfortunately it is necessary to use valuable space on data of dubious value. The bibliography is fairly complete, but it was impracticable to locate all data, especially those in obscure journals. Each reference is followed by a list of the elements referred to in the paper, thereby permitting a reader to compile a fairly compre hensive set of references on any chosen element. Not all papers are mentioned in the text. The book on Geochemistry and Mineralogy of Rare Elements, etc."

The papers of this book are based on a Symposium on Numerical Simulation in Oil Recovery held at the Institute for Mathematics and its Applications. The major research emphasis is on the modeling of fractures, heterogeneities, viscous fingering, and diffusion-dispersion effects in the flow in porous media. This volume contains seventeen comprehensive papers on the latest developments in this exciting subject. Its diverse presentation brings together the various disciplines of applied mathematics, chemical engineering, physics and hydrology.

Sandstone Petroleum Reservoirs presents an integrated, multidisciplinary approach to the geology of sandstone oil and gas reservoirs. Twenty-two case studies involving a variety of depositional settings, tectonic provinces, and burial/diagenetic histories emphasize depositional controls on reservoir architecture, petrophysical properties, and production performance. An introductory section provides perspective to the nature of reservoir characterization and highlights the important questions that future studies need to address. A "reservoir summary" following each case study aids the reader in gaining quick access to the main characteristics of each reservoir. This casebook is heavily illustrated, and most data have not been previously published. The intended audience comprises a broad range of practicing earth scientists, including petroleum geologists, geophysicists, and engineers. Readers will value the integration of geological versus engineering interests provided here, and will be enabled to improve exploration and production results.

together with contributions by invited geoscientists The Central Andes, whose orogenic activity is so impressively documented by recent volcanism and and counterparts from other countries, during a workshop held in Berlin, 23-25 May 1990. A great earthquakes, have always attracted the attention of geoscientists. This interest became even more accen number of the papers presented at this workshop are tuated since, a quarter of a century ago, Plate included in this volume. While most of the chapters Tectonics became the basis for the New Global refer regionally to the segment of the southern Andes Tectonics concept, in which this huge mountain range mentioned above, others treat general aspects or deal was the most spectacular example of an active conti with Andean regions farther south, thus showing not only that the structures of this mountain range can be nental margin. Thus, in addition to the continuing research work by South American and foreign geo followed to more distant parts but also that there are scientists dedicated mostly to regional and economic significant structural variations along strike. problems, a great number of special research pro Like other books which originate from workshops grammes were initiated aiming at a better understand and are comprised of contributions from many ing of the processes acting at a convergent plate authors, also this one cannot give a complete and margin. well-balanced view of the scientific subject dealt In 1982, the earth science institutes of the Freie with, in this case the southern Central Andes.

In October 1986 the German Minister for Research and Technology (Bundesminister fUr Forschung und Technologie), Dr. H. Riesenhuber, officially announced that the super-deep borehole of the Continental Deep Drilling Program of the Federal Republic of Germany (KTB) would be drilled in the Oberpfalz area of Northern Bavaria. The site selection was based on a recommendation from the Deutsche Forschungsgemeinschaft (DFG) made after an evaluation by the Project Management of the technical and financial risks involved. This decision was preceded by a conference held from September 19 to 21, 1986 in Seeheim/Odenwald at which the results of the site studies in the Oberpfalz and the Schwarzwald were presented and thoroughly debated. The models and scientific targets resulting from these investigations formed the basis for a vote by the DFG Senate Commission for Geoscientific Interdisciplinary Research which was taken immediately after the conference. After evaluation of all scientific and technical aspects, the members of the commission voted almost unanimously for the Oberpfalz site. It was, ho",'ever, strongly emphasized that both locations had a wealth of attractive research objectives and that despite clear-cut differences in some major aspects scientifically the two could be regarded as more or less equivalent. Both'locations would be excellent sites for research drilling and would certainly cor.

Microscopy is a servant of all the sciences, and the microscopic examina tion of minerals is an important technique which should be mastered by all students of geology early in their careers. Advanced modern text books on both optics and mineralogy are available, and our intention is not that this new textbook should replace these but that it should serve as an introductory text or a first stepping-stone to the study of optical mineralogy. The present text has been written with full awareness that it will probably be used as a laboratory handbook, serving as a quick reference to the properties of minerals, but nevertheless care has been taken to present a systematic explanation of the use of the microscope as well as theoretical aspects of optical mineralogy. The book is therefore suitable for the novice either studying as an individual or participating in classwork. Both transmitted-light microscopy and reflected-light microscopy are dealt with, the former involving examination of transparent minerals in thin section and the latter involving examination of opaque minerals in polished section. Reflected-light microscopy is increasing in importance in undergraduate courses on ore mineralisation, but the main reason for combining the two aspects of microscopy is that it is no longer acceptable to neglect opaque minerals in the systematic petrographic study of rocks. Dual purpose microscopes incorporating transmitted- and reflected-light modes are readily available, and these are ideal for the study of polished thin sections."

With the rapid development of fast processors, the power of a mini-super computer now exists in a lap-top box. Quite sophisticated techniques are be coming accessible to geoscientists, thus making disciplinary boundaries fade. Chemists and physicists are no longer shying away from computational mineral ogical and material science problems "too complicated to handle." Geoscientists are willing to delve into quantitative physico-chemical methods and open those "black boxes" they had shunned for several decades but with which had learned to live. I am proud to present yet another volume in this series which is designed to break the disciplinary boundaries and bring the geoscientists closer to their chemist and physicist colleagues in achieving a common goal. This volume is the result of an international collaboration among many physical geochemists (chemists, physicists, and geologists) aiming to understand the nature of material. The book has one common theme: namely, how to determine quantitatively through theory the physico-chemical parameters of the state of a solid or fluid."

Clay minerals form in a wide variety of crustal environments, e.g. in soil profiles, in sediments at the surface and in deeply buried sedimentary deposits, and under regional, contact and hydrothermal metamorphism conditions.
The book provides information about the dynamics of isotope systems in clays and helps us to understand the physical and chemical parameters in the transfer of masses within the crustal domain. Written for graduate students taking courses in sedimentary geochemistry, clay mineralogy, and soil mineralogy, the book will also appeal to scientists carrying out research on clay genesis and mass transfer in crustal environments.

We wrote Sedimentology of Shale primarily because we lacked a handy, reasonably comprehensive source of information and ideas about shales for students in our sedimentology program. It was also our feeling that the time for shales to receive more study had finally arrived. Sedimentology of Shale also seems very timely because today more sedimentologists are interested in shales. Certainly in the last five years the pace of shale research has no ticeably quickened because the role of shales as important sources of oil, gas, heavy metals and as a long understudied part of the earth's geologic his tory has been recognized. Noteworthy developments include the elucida tion of the importance of trace fossils in shales, the discovery of thick sequences of overpressured shales in regions such as the Gulf Coast (which have important implications for hydrocarbon migration and faulting), the ex tension of the principles of metamorphic facies to the realm of low tempera ture diagenesis by study of the organic matter in shales, and shales as ul timate sources for mineral deposits. Accordingly, we decided it was timely to write a book on shales. In one respect, however, ours is an unusual book. Most books in geology are produced after one or two decades of progress have been made in a field and attempt to summarize and evaluate that progress."

The principal aim of the present work is to understand the evolution of halogenesis in the Paleozoic. To succeed in the study it was neces- sary to make a general and systematic synthesis of data available on world-wide Paleozoic halogenic deposits and describe all known eva- porite basins. This study succeeds the monograph Paleozoic Salt For- mations of the World (Zharkov 1974a). The history of Paleozoic salt accumulation is based chiefly on evidence presented in the above monograph; this work should be considered as its direct continutation. The present work mainly aims at: (1) establishment of the num- ber of both salt and sulfate basins and salt and sulfate sequences formed therein in the Paleozoic; (2) determination of the stratigraphic position of salt and sulfate sequences in separate regions, their distant correlation and recognition of stages of evaporite sedimentation during the Paleozoic; (3) determination of the volume and areas of distribution of halite, potash, and sulfate sedimentation within basins and on continents through periods, epochs, and ages of the Paleozoic to single out epochs of the most intense evaporite sedimentation; (4) reconstruction of paleogeography of continents to recognize stages of evaporite accumulation and paleoclimatic zones of halogenic sedi- mentation in the Paleozoic; (5) understanding the evolution of eva- porite sedimentation in the Paleozoic. The nomenclature used in the book should be explained.

Many interesting and perplexing questions arise in connection with the highly potassic volcanic associa- tion dominated by mafic and ultramafic rocks contain- ing leucite. Its occurrence is very restricted as compar- ed with the olivine-basalt trachyte kindred, but it is distributed at widely scattered points on all the conti- nents, and its chemical and petrographic individuality is both remarkable and constant. A considerable litera- ture is available related to the mineralogy, petrology, geochemistry, phase chemistry, distribution, and origin of this interesting suite of rocks. It seemed that there was a genuine need for a review-synthesis of all these data, which would be intelligible to a wide spectrum of advanced students and professionals in the earth sciences. The monograph may be divided into two parts. The first part consists of six chapters in which the mineralogical and chemical peculiarities of leucite- bearing rocks and their nomenclature, petrology, min- eralogy, distribution, and physical and chemical condi- tions of formation are discussed. Phase equilibria stud- ies on many leucite-bearing ternary, pseudoternary, quaternary, and pseudoquaternary joins and systems, studied by different investigators at variable tempera- tures in air, are described in the second part in Chap- ters 7 to 12. Survival of leucite and formation of pseu- doleucite is discussed in Chapter 13. Leucite-bearing synthetic and natural rock systems studied at different temperatures under variable pressures in presence or absence of water, are summarized in Chapters 14 and 15.