This is the third book in the new series "Material Research and Engineering," devoted to the science and technology of materials. "MRE" evolves from a previous series on "Reine und Angewandte Metallkunde," which was edited by Werner Koster until his eightieth birthday in 1976. For the new series, the presentation as well as the scope had to be modified. In particular, the scientific and technological links between volumes on metallic, non-metallic, and composite materials should reflect the successful development of materials science and engineering within the last two decades. Thus, the material provided by Dorre and Hlibner for the present volume is partic ularly welcome. Alumina as a ceramic material has received very large attention as an object of scientific investigation in all of its aspects. Additionally, it plays a leading role as a nonmetallic material in many fields of technical appli cation. This book deals with both aspects: in Chapter 2 (physical properties) and 3 (me chanical properties), H. Hlibner presents an outstanding documentation of what one might call the science of alumina, based on 560 literature references and 15 years of personal experience gained from experimental and theoretical work in university laboratories in Erlangen, Rio de Janeiro, and Hamburg. In Chapter 4 (fabrication) and 5 (applications), E."

Stress corrosion cracking, including hydrogen embrittlement, has probably attracted more attention in the last decade than any other single facet of the many that constitute the totality of the environment sensitive behaviour of materials. To some this is because the complex interactions between a number of parameters, particularly metal composition and structure, electrochemistry and the response of a metal to the application of stress, make the subject of stress corrosion fascinating. To others it is be cause the subject has become increasingly important in practical terms, as the problem of general corrosion has been controlled and the borderline conditions between widespread attack and com plete inactivity are more frequently encountered, and as materials have become more efficiently used by operating at higher stress levels than hitherto. Particularly in advanced engineering systems, such as pressure vessels used in transportation or in the chemical process industries or in the sophisticated equipment used in some of the energy producing industries, the incidence of stress corro sion failure has increased alarmingly in recent times and with consequences that are extremely costly if not worse. The reasons for holding a NATO Advanced Study Institute in this field are therefore obvious, but why publish the proceedings of the Institute in an age where there is, arguably, already a VIII superfluity of published material? Obe obvious answer is that the papers presented constitute valuable reviews of detailed develop ments in recent times."

In the decade since the introduction of the first commercial lithium-ion battery research and development on virtually every aspect of the chemistry and engineering of these systems has proceeded at unprecedented levels. This book is a snapshot of the state-of-the-art and where the work is going in the near future. The book is intended not only for researchers, but also for engineers and users of lithium-ion batteries which are found in virtually every type of portable electronic product.

In The New Superconductors, Frank J. Owens and Charles P. Poole, Jr., offer a descriptive, non-mathematical presentation of the latest superconductors and their properties for the non-specialist. Highlights of this up-to-date text include chapters on superfluidity, the latest copper oxide types, fullerenes, and prospects for future research. The book also features many examples of commercial applications; an extensive glossary that defines superconductivity terms in clear language; and a supplementary list of readings for the interested lay reader.

This series of books, which is published at the rate of about one per year, addresses fundamental problems in materials science. The contents cover a broad range of topics from small clusters of atoms to engineering materials and involve chemistry, physics, and engineering, with length scales ranging from Angstroms up to millimeters. The emphasis is on basic science rather than on applications. Each book focuses on a single area of current interest and brings together leading experts to give an up-to-date discussion of their work and the work of others. Each article contains enough references that the interested reader can access the relevant literature. Thanks are given to the Center for Fundamental Materials Research at Michigan State University for supporting this series. M. F. Thorpe, Series Editor E-mail: thorpe@pa. msu. edu v PREFACE th th During the period 4 -8 August 1996, a conference with the same title as this book was held in Traverse City, Michigan. That conference was organized as a sequel to an interesting and successful WEM workshop in a similar area run by Profs. Hans Bonzel and Bill Mullins in May 1995. This book contains papers presented at the Traverse City conference. The book focuses on: atomic processes, step structure and dynamics; and their effect on surface and interface structures and on the relaxation kinetics of larger leng- scale nonequilibrium morphologies.

Lead-based paint has become a national issue and will continue to be a hi- priority focus ofnational, state, and local agencies until there is no lead-based paint in the United States. Lead-based paint has become a tremendous health hazard for people and animals. Lead-based paint has been in widespread use throughout Europe and the United States. Lead has been known to be a health hazard since the time ofPliny the Elder (A. D. 23-79), but it was deemed that the advantages of lead in paint outweighed the health hazards. There has been a change in outlook, and in 1973 the U. S. Congress banned all lead paint from residential structures. A voluminous number of law suits have been initiated since, and continue to be litigated with the purpose of determining the parties responsible for the lead poisoning of children and others and to exact the indemnities. Lead-based paint is still authorized for use on bridges and nonresidential structures, and thousands of city, state, military, and federal government housing projects still contain lead-based paint. This paint must be removed if these dwellings are to be safe living quarters, especially for children. Aba- ment techniques continue to be evaluated; some have been used successfully. Lead-based paint abatement will continue into the next century, and it is hoped that this comprehensive volume will serve as a guide for those seriously interested in this important subject.

Corrosion behaviour is one of the most poorly understood characteristics of ceramics. A balanced mixture of scientists from material science, metallurgy, physics, chemistry and mineralogy sum up the state of the art of measurement and modelling and reveal future research directions. The book reviews the theory of corrosion of ceramics, including the diffusion of gases and the predictions of thermodynamics; it discusses critically the kinetic models and representation tools for layer growths and material destruction. Corrosion of nitrides, carbides and oxides by simple and complex gases (O2, H2O, SO2, halides) and melts (ionic and metallic) reveal current measurement and modelling methods, advanced experimental techniques, such as laser diagnostics, TV holography, Raman spectroscopy and NDE surface methods. Frontier areas (e.g. the modelling of porous materials corrosion and protection) are revealed. For scientists and engineers in materials science, dealing with ceramics and their application. A valuable source for research students, solid state physicists and physical chemists.

Evaluation, repair and rehabilitation of bridges are increasingly important topics in the effort to deal with the deteriorating infrastructure. For example, in the United States about 40 percent of the nation's 570,000 bridges are classified, according to the Federal Highway Administra tion's (FHW A) criteria, as deficient and in need of rehabilitation and replacement. In other countries the situation is similar. FHW A estimates the cost of a bridge replacement and reha bilitation program at 50 billion dollars. The major factors that have contributed to the present situation are: the age, inadequate maintenance, increasing load spectra and environmental contamination. The deficient bridges are posted, repaired or replaced. The disposition of bridges involves clear economical and safety implications. To avoid high costs of replacement or repair, the evaluation must accurately reveal the present load carrying capacity of the struc ture and predict loads and any further changes in the capacity (deterioration) in the applicable time span. Accuracy of bridge evaluation can be improved by using the recent developments in bridge diagnostics, structural tests, material tests, structural analysis and probabilistic methods. There is a need for an international exchange of advanced experience to increase the research effi ciency. The Workshop is organized on the premise that the exchange of existing American and European experience in the area of bridge evaluation, repair and rehabilitation is beneficial for both parties involved."

When it was learned that Professor Scholze was revising his classic work on the nature, structure, and properties of glass, it was natural to conceive the idea of translating the new edition into English. Professor Scholze enthusiastically endorsed this suggestion and asked for the concurrence of his publisher, Springer-Verlag. Springer-Verlag welcomed the idea and readily agreed to provide support. With the essential agreements in place, Professor Michael Lakin, Professor of German at Alfred University, was asked to do the transla tion, and I subsequently agreed to work with Professor Lakin to check for technical accuracy. I was happy to accept this task because of my respect for Professor Scholze and because of the value to glass scientists and engineers of having available an English edition of Glas. Professor Scholze died before publication ofthis English edition of his work. However, he had reviewed the entire English text and had approved it. Professor Lakin and I appreciated the confidence he placed in us, and we were gratified with his acceptance of our efforts. His scientific contributions were numerous and important; they will long serve as guideposts for research in many key areas. We hope this translation of Glas will help make his legacy accessible to more people. Professor Lakin and I have tried to provide a translation that is accurate and true to the original but that has a distinctive English "flavor"; that is, it is not just a literal translation."

This book is a collection of the addresses of the keynote speakers and invited lecturers as well as manuscripts of a few outstanding papers which were delivered at the First Pacific Polymer Conference organized by the Pacific Polymer Federation in Maui, Hawaii, 12-15 December, 1989. The First Pacific Polymer Conference covered a wide variety of topics in macromolecular science, demonstrating the emphasis given to polymer research in the Pacific Rim countries. The keynote speakers and invited lecturers are excellent scientists and leaders of effort who covered their fields expertly and in many cases gave their own perspective on the future of polymer science and engineering. A panel discussion on the role of polymers in the arts interested the attendees and emphasized the pervasiveness of polymers in all facets of life. The meeting was attended by over 500 scientists from all over the world. The participants left the meeting with renewed feeling for the importance of polymers in the material sciences and impressed by the progress in polymer research and development. This book, therefore, provides a wide -angle snapshot of the polymer research as we enter the 1990's. It is a useful book for all scientists interested in polymers and the progress of our science in the countries of the Pacific Rim. We hope that many attendees were stimulated by the meeting and that new ideas and new collaborations will result which will further enrich research, and lead to new useful polymers for all countries.

Ionomers, that is polymers containing a low concentration of charged units along the chain, have been the subject of increasing interest during the past twenty years. The presence of ionic groups in the poly mer changes some of its properties dramatically. Increases in the modu lus and the viscosity of several orders of magnitude have been observed, and changes in the glass transition of hundreds of degrees are possible. In addition, diffusion coefficients can be modified drastically. These changes are due primarily to the presence of reversible ionic cross links in these materials. Because of the low dielectric constant of most organic polymers, the ions or ionic dipoles tend to aggregate ; this aggregation process, however, is limited, because the ionic groups are covalently bonded to the organic chain. Host of the fundamental research done on these materials has been devoted to a determination of the extent of association, the structure of the aggregates, the limi ting factors, and the correlations between molecular and supermolecular structure and the resul ting properties.

This book is intended to be a comprehensive reference to multiplicative com plexity theory as applied to digital signal processing computations. Although a few algorithms are included to illustrate the theory, I concentrated more on the develop ment of the theory itself. Howie Johnson's infectious enthusiasm for designing efficient DfT algorithms got me interested in this subject. I am grateful to Prof. Sid Burrus for encouraging and supporting me in this effort. I would also like to thank Henrik Sorensen and Doug Jones for many stimulating discussions. lowe a great debt to Shmuel Winograd, who, almost singlehandedly, provided most of the key theoretical results that led to this present work. His monograph, Arithmetic Complexity o/Computations, introduced me to the mechanism behind the proofs of theorems in multiplicative complexity. enabling me to return to his earlier papers and appreciate the elegance of his methods for deriving the theory. The second key work that influenced me was the paper by Louis Auslander and Winograd on multiplicative complexity of semilinear systems defined by polynomials. After reading this paper, it was clear to me that this theory could be applied to many impor tant computational problems. These influences can be easily discerned in the present work.

This volume summarizes the papers presented at the First Osaka University Macromolecular Symposium OUMS'93 on "Ordering in Macromolecular Systems," which was held at Senri Life Science Center, Osaka, Japan, on June 3 through June 6, 1993. The symposium covered the three topics, (1) Crystallization and Phase Transitions, (2) Polymer Liquid Crystals and (3) Block Copolymers, Polymer Blends and Surfaces, and invited leading scientists in these fields. At present any of these topics is a hot issue in itself and frequently taken up separately in many occasions. It is noted however that all these topics are correlated with each other with the keyword "Ordering" and their combination provides a unique feature of the present symposium in reflecting the interactions among investigators working in these important fields with the common ground expressed by the keyword "Ordering." Nineteen invited lectures and 40 posters of both experiment and theory were presented at the symposium, and the eighteen lectures and ten poster presentations contribute to this volume. In the first topic crystal structures and their transitions were discussed from kinetic as well as static points of view; attention was paid to give a molecular-level interpretation of the structure, phase transition and physical properties, using theories and simulations. The second topic was mainly concerned with static structures and thermodynamic properties of polymer liquid crystals including phase behaviours.

The Symposium on "The Influence of Polymer Additives on Veloc- ity and Temperature Fields" was proposed to the General Assem- bly of the International Union of Theoretical and Applied Me- chanics (IUTAM) by the "Gesellschaft fur Angewandte Mathematik und Mechanik" (GAMM). The Symposium was held under the auspices of IUTAM in association with the "Deutsche Rheologische Ge- sellschaft" (DRG) with responsibility for the organization ly- ing with B. Gampert (Universitat-GH-Essen). The main aim of this IUTAM Symposium was to consider the funda- mental aspects of the phenomena that occur when small amounts of polymers are added to turbulent flows (turbulent drag re- duction) and laminar porous media flows. In particular atten- tion was devoted to - the influence of molecular parameters of the polymers and solution properties, especially the elongational viscosity, on turbulent flow and laminar porous media flow; the influence of polymers on the turbulence structure in polymer drag reduction.

It is widely recognized that spiral grain in trees severely reduces the value of sawn timber through warping and loss of strength, and that it also causes problems for other wood uses as diverse as transmission poles or plywood. Yet, paradoxically, there are highly valued grain patterns including wavy and interlocked grain, whose origins in the cambium invite direct comparison with those of spiral grain, so that many authorities believe them to be related phenomena. In recent years this concept has prompted extensive research into the anatomy, genetics, and physiology of all such grain patterns in wood. As a result it has become apparent that tree cambia provide excellent systems through which to study the origins of stem polarity and the complex processes of morphogenetic control in plants. Beside these and other pressing topics for research, the book examines methods of measuring grain deviations, and considers their influence on wood properties, on the economics of timber production, and on wood manufacturing.

The contents of this volume represent most of the papers presented either orally or as posters at the international conference held in Les rd th Arcs, Savoie, from June 29 to July 3 1987. The declared objective of the conference was to bring together specialists working in various fields, both academic and applied, to examine the state of our under standing of the physics of amorphous sioz from the point of view of its structure, defects (both intrinsic and extrinsic), its ability to trans port current and to trap charges, its sensitivity to irradiation, etc. For this reason, the proceedings is divided, as was the conference schedule, into a number of sections starting from a rather academic viewpoint of the internal structure of idealized Si0 and progressing 2 towards subjects of increasing technological importance such as charge transport and trapping and breakdown in thin films. The proceedings terminates with a section on novel applications of amorphous SiOz and in particular, buried oxide layers formed by ion implantation. Although every effort was made at the conference to ensure that each presentation occured in its most obvious session, in editing the proceedings we have taken the liberty of changing the order where it seems that a paper was in fact more appropriate to an alternative section. In any event, because of the natural overlap of subjects, many papers could have been suitably placed in several different sections.

This book has its origin in a proposal made a few years ago that I should collaborate with Dr H. J. Stern in the production of a third edition of his well-known text-book entitled Rubber: Natural and Synthetic. The sugges tion was that I should contribute a series of chapters on synthetic rubbers. Although, in the event, it has not proved possible to publish the full book in the form originally planned, it was apparent that, with some restructuring, the material which I had collected would be valuable as an independent summary of the chemistry and technology of synthetic rubbers. It is in this form that the material is now offered. The primary purpose of this book is to provide a brief up-to-date survey of the principal types of synthetic rubber which have been and are currently available. Two classes of material are included which are regarded by some as being thermoplastics rather than rubbers, namely, plasticised polyvinyl chloride and the thermoplastic synthetic rubbers. The topics which are covered for each main family of synthetic rubbers are (i) the sources of the monomers, (ii) polymerisation procedures and the effects of important polymerisation variables upon the rubber produced, (iii) the types of rubber currently available commercially, (iv) interesting aspects of the compounding of the rubbers, with special reference to such matters as vulcanisation, reinforcement, protection against degradation, and (where appropriate) plasticisation, and (v) an indication of applications."

IUTAM-IAHR Symposium on Ice-Structure Interaction Professor Bez Tabarrok, Chairman of the Canadian National Committee (CNC) of the International Union of Theoretical and Applied Mechanics (IUTAM) invited Professor Derek Muggeridge to organize a symposium on ice structure interaction. Dr. Muggeridge readily agreed and prepared a proposal that was endorsed by the CNC and presented to the General Assembly Meeting of IUTAM for their consideration. This Assembly gave its approval and provided the local organizing committee with the names of individuals who were willing to serve on the Scientific Committee. Dr. Muggeridge became chairman of this committee and Dr. Ian Jordaan became co-chairman of this committee as well as chairman of the local organizing committee. The symposium followed the very successful previous meeting, chaired by Professor P. Tryde in Copenhagen, by ten years. Both symposia uti lized Springer-Verlag to publish their proceedings. The Faculty of En gineering and Applied Science at Memorial University of Newfoundland were particul{lXly pleased to host this prestigious symposium as it marked the twentieth anniversary of its Ocean Engineering Research Centre."

This Proceedings is a collection of papers presented at the Third Annual Conference on Superconductivity and Applications organized by the New York State Institute on Superconductivity. This year the Conference was held at the Buffalo Hilton Hotel on September 19- 21, 1989, with previous meetings on September 28-29,1987, and April 18-20, 1988. As in previous years, this meeting was highly successful, with an attendance of over three hundred researchers participating in lively scientific exchanges and discussions. The high quality of the talks is evident in this Proceedings. The field of high temperature superconductivity has matured considerably since its early days of media frenzy and rapid new discoveries. However, the enthusiasm and pace of research have not slowed down. A much better picture of the nature of high temperature superconductivity, the properties of these new materials and where they may find their eventual use has emerged. Processing techniques, especially thin film deposition, have been perfected nearly to the point of allowing commercial applications. We expect continued phenomenal growth of the field of high temperature superconductivity, both in terms of research and applications for many years to come.

''A must for anyone interested in metal-containing polymers and all its aspects.'' ---American Scientist ''Nicely organized...well-written....An excellent shapshot of the current state of this field.'' ---MRS Bulletin, July 1998

In the last two decades low-dimensional (low-d) physics has matured into a major branch of science. Quite generally we may define a system with restricted dimensionality d as an object that is infinite only in one or two spatial directions (d = 1 and 2). Such a definition comprises isolated single chains or layers, but also fibres and thin layers (films) of varying but finite thickness. Clearly, a multitude of physical phenomena, notably in solid state physics, fall into these categories. As examples, we may mention: * Magnetic chains or layers (thin-film technology). * Metallic films (homogeneous or heterogeneous, crystalline, amorphous or microcristalline, etc.). * I-d or 2-d conductors and superconductors. * Intercalated systems. * 2-d electron gases (electrons on helium, semiconductor interfaces). * Surface layer problems (2-d melting of monolayers of noble gases on a substrate, surface problems in general). * Superfluid films of ~He or 'He. * Polymer physics. * Organic and inorganic chain conductors, superionic conductors. * I-d or 2-d molecular crystals and liquid crystals. * I-d or 2-d ferro- and antiferro electrics.

The use of computer-based image analysis systems for all kinds of images, but especially for microscope images, has become increasingly widespread in recent years, as computer power has increased and costs have dropped. Software to perform each of the various tasks described in this book exists now, and without doubt additional algorithms to accomplish these same things more efficiently, and to perform new kinds of image processing, feature discrimination and measurement, will continue to be developed. This is likely to be true particularly in the field of three-dimensional imaging, since new microscopy methods are beginning to be used which can produce such data. It is not the intent of this book to train programmers who will assemble their own computer systems and write their own programs. Most users require only the barest of knowledge about how to use the computer, but the greater their understanding of the various image analysis operations which are possible, their advantages and limitations, the greater the likelihood of success in their application. Likewise, the book assumes little in the way of a mathematical background, but the researcher with a secure knowledge of appropriate statistical tests will find it easier to put some of these methods into real use, and have confidence in the results, than one who has less background and experience. Supplementary texts and courses in statistics, microscopy, and specimen preparation are recommended as necessary.

The 35th Annual Denver Conference on Applications of X-Ray Analysis was held August 4-8, 1986, on the campus of the University of Denver. Since the previous year's conference had emphasized x-ray diffraction, this year the Plenary Session spotlighted x-ray fluorescence, with the title "Trends in XRF: A World Perspective," featuring renowned speakers from three major areas. XRF IN NORTH AMERICA, by Prof. D. E. Leydon, from Colorado State University, dealt specifically with developments in the fields of instrumentation, data treatment and applications in that part of the world. Prof. H. Ebel, from the Technical University of Vienna, discussed XRF IN EUROPE, concentrating on subjects including total reflection, improved fundamental parameters, quantitation without standards and imaging techniques. Tomoya Arai, of the Rigaku Industrial Corporation in Japan, in considering XRF IN THE FAR EAST, described the scientific activity in XRF and the applications thereof, primarily in Japan and China. These plenary lectures were interspersed with short discussions of PERSONAL OBSERVATIONS on the subject by the co-chairmen of the SeSSion, Ron Jenkins and myself. The intent of this session was to bring the audience up-to-date on the status of the field in various parts of the world, and to give some feeling concerning where it is likely to go in the immediate future. Hopefully, the publication of the written versions of those presentations in this volume will make the authors' thoughts available to many who could not be present at the conference.

During the last thirty years profound developments in expe- rimental techniques to measure high temperature and pressu- res and thermodynamic properties of minerals have occurred. This technical development has been matched by an increased sophistication in applying theoretical methods to obtain new data or improve the quality of existing data. Using these newtechniques, Assessed Thermodynamic Data on Oxides and Silicates represents the successful attempt of the authors to develop an internally systematized data base which satis- fies the constraints of calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lat- tice vibrational models.