My 12-year-old granddaughter Nina Alesi once asked me, "Grandpa, you are a scientist at IBM, so what do you do?" I tried to reply, "Oh, I watch atoms move. . . " But before I could finish this sentence, my 7-year-old grandson Vinnie interjected, "Grandpa, do atoms play soccer?" This book is about the games atoms play in diffusion and various other properties of materials. While diffusion has been studied for more than 100 years in solids, its importance, excitement, and intellectual chal lenges remain undiminished with time. It is central to understanding the relationship between the structure and properties of naturally occurring and synthetic materials, which is at the root of current technological development and innovations. The diversity of material has led to spec tacular progress in functional inorganics, polymers, granular materials, photonics, complex oxides, metallic glasses, quasi-crystals, and strongly correlated electronic materials. The integrity of complex materials pack ages is determined by diffusion, a highly interactive and synergic phe nomenon that interrelates to the microstructure, the microchemistry, and the superimposed physical fields. While the various physico-chemical properties of the materials are affected by diffusion, they determine diffu sion itself. This book, which is intended to document the diffusive processes operative in advanced technological materials, has been written by pio neers in industry and academia.

Today, multi-functional materials such as piezoelectric/ferroelectric ceramics, magneto-strictive and shape memory alloys are gaining increasing applications as sensors, actuators or smart composite materials systems for emerging high tech areas. The stable performance and reliability of these smart components under complex service loads is of paramount practical importance. However, most multi-functional materials suffer from various mechanical and/or electro-magnetical degra-dation mechanisms as fatigue, damage and fracture. Therefore, this exciting topic has become a challenge to intensive international research, provoking the interdisciplinary approach between solid mechanics, materials science and physics. This book summarizes the outcome of the above mentioned IUTAM-symposium, assembling contributions by leading scientists in this area. Particularly, the following topics have been addressed: (1) Development of computational methods for coupled electromechanical field analysis, especially extended, adaptive and multi-level finite elements. (2) Constitutive modeling of non-linear smart material behavior with coupled electric, magnetic, thermal and mechanical fields, primarily based on micro-mechanical models. (3) Investigations of fracture and fatigue in piezoelectric and ferroelectric ceramics by means of process zone modeling, phase field simulation and configurational mechanics. (4) Reliability and durability of sensors and actuators under in service loading by alternating mechanical, electrical and thermal fields. (5) Experimental methods to measure fracture strength and to investigate fatigue crack growth in ferroelectric materials under electromechanical loading. (6) New ferroelectric materials, compounds and composites with enhanced strain capabilities.

Once again, it gives me a great pleasure to pen the Foreword to the Proceedings of the 15th International Conference on Thermal Conductivity. As in the past, these now biannual conferences pro vide a broadly based forum for those researchers actively working on this important property of matter to convene on a regular basis to exchange their experiences and report their findings. As it is apparent from the Table of Contents, the 15th Conference represents perhaps the broadest coverage of subject areas to date. This is indicative of the times as the boundaries between disciplines be come increasingly diffused. I am sure the time has come when Con ference Chairmen in coming years will be soliciting contributions not only in the physical sciences and engineering', but will actively seek contributions from the earth sciences and life sciences as well. Indeed, the thermal conductivity and related properties of geological and biological materials are becoming of increasing im portance to our way of life. As it can be seen from the summary table, unfortunately, proceedings have been published only for six of the fifteen con ferences. It is hoped that hereafter this Series will become increasingly well known and be recognized as a major vehicle for the reporting of research on thermal conductivity."

Both experimental and theoretical investigations make it clear that mesoscale materials, that is, materials at scales intermediate between atomic and bulk matter, do not always behave in ways predicted by conventional theories of shock compression. At these scales, shock waves interact with local material properties and microstructure to produce a hierarchy of dissipative structures such as inelastic deformation fields, randomly distributed lattice defects, and residual stresses. A macroscopically steady planar shock wave is neither plane nor steady at the mesoscale. The chapters in this book examine the assumptions underlying our understanding of shock phenomena and present new measurements, calculations, and theories that challenge these assumptions. They address such questions as: - What are the experimental data on mesoscale effects of shocks, and what are the implications? - Can one formulate new mesoscale theories of shock dynamics? - How would new mesoscale theories affect our understanding of shock-induced phase transitions or fracture? - What new computational models will be needed for investigating mesoscale shocks?

In the last few years the physics of turbulent plasma has undergone rapid development, beginning with the first works, in which the term "turbulence" was used in various ways, and ending with the fundamental studies which provide a thorough examina tion of the turbulent state of plasma. In physics it is usually found that value is not so much contained in specific results for a partic ular field as it is in the more general outlook and overall view of the problem. Occasionally the older results take on new mean ing after the general view of things is perfected. In the case of the physics of turbulent plasma, this general picture is now com plete, for the most part. The first review devoted to the problem of plasma turbulence was written by B. B. Kadomtsev in "Problems in Plasma Theory," edited by M. A. Leontovich, Volume 4, Moscow, Atomizdat (1964), p. 188; English Translation: "Plasma Turbulence," Academic Press, London (1965)]."

Conventional synthetic materials, like metals, ceramics or glass, are usually isotropic substances, and their suitability for structural applications is achieved by morphological design and combination in the macroscopic scale. However, in modem engineering this is often not acceptable. As an alternative, the use of non-homogeneous, anisotropic materials, with significant stiffness and strength only in the directions these mechanical properties are really needed, can lead to enormous material (and weight) savings. This is the case of multiphase systems called composite materials. In these composites, different material parts are added and arranged geometrically, under clearly designed and controlled conditions. Usually, a structure of fibers provides strength and stiffness and a matrix helds them together, whilst providing the geometric form. Carbon fibers are among the high-performance fibers employed in these advanced structural composites, which are profoundly changing many of today's high technology industries. New research and development challenges in this area include upgrading the manufacturing process of fibers and composites, in order to improve characteristics and reduce costs, and modifying the interfacial properties between fibers and matrix, to guarantee better mechanical properties. The interdisciplinary nature of this "new frontier" is obvious, involving chemistry, materials science, chemical and mechanical engineering. Other topics, which more often are treated separately, are also important for the understanding of the processes of fiber production. Carbon filaments is one such topic, as the study of their mechanisms of nucleation and growth is clearly quite relevant to the production of vapour-grown carbon fibers.

Over the years, numerous handbooks and design guides on the subject of plastics have been published. None of these dealt in any depth with the subject of this handbook-blow molding. The recent growth of blow molding as an economically feasible process has been rapid in many areas. This growth, coupled with the lack of technical publications relating to blow molding, prompted the Board of Directors of the Blow Molding Division of the Society of Plastic Engineers to undertake the assimilation of available information and the editing of this milestone publication. We believe that this Plastic Blow Molding Handbook will provide the reader with a greater understanding of the unique process characteristics of blow molding, enable the reader to apply proven techniques in developing new products and applications for blow molding, and will serve as a valuable reference for all who are interested in the plastics industry. Our thanks are heartily extended to the various authors for their con tributions to this pioneering effort in blow molding. J. H. Moran Chairman Blow Molding Division Society of Plastic Engineers xi Preface The blow molding of plastic articles has in the past had an aura of the mystic around it. As a result, little comprehensive work on the subject has been published. Advances in the technology of polymeric materials, machine controls, computer science, and management techniques have made it nec essary to correct the myths and magic."

Composite Materials in Aerospace Design is one of six titles in a coherent and definitive series dedicated to advanced composite materials research, development and usage in the former Soviet Union. Much of the information presented has been classified until recently. Thus each volume provides a unique insight into hitherto unknown research and development data. This volume deals with the design philosophy and methodology used to produce primary and secondary load bearing composite structures with high life expectancies. The underlying theme is of extensive advanced composites research and development programs in aircraft and spacecraft applications, including the space orbital ship `BURAN'. The applicability of much of this work to other market sectors, such as automotive, shipbuilding and sporting goods is also examined in some detail. The text starts by describing typical structures for which composites may be used in this area and some of the basic requirements from the materials being used. Design of components with composite materials is then discussed, with specific reference to case studies. This is followed by discussion and results from evaluation of finished structures and components, methods of joining with conventional materials and finally, non-destructive testing methods and forecasting of the performance of the composite materials and the structures which they form. Composite Materials in Aerospace Design will be of interest to anyone researching or developing in composite materials science and technology, as well as design and aerospace engineers, both in industry and universities.

This book is a sequel to Reliability Evaluation of Engineering Systems: Concepts and Techniques, written by the same authors and published by Pitman Books in January 1983. As a sequel, this book is intended to be considered and read as the second of two volumes rather than as a text that stands on its own. For this reason, readers who are not familiar with basic reliability modelling and evaluation should either first read the companion volume or, at least, read the two volumes side by side. Those who are already familiar with the basic concepts and only require an extension of their knowledge into the power system problem area should be able to understand the present text with little or no reference to the earlier work. In order to assist readers, the present book refers frequently to the first volume at relevant points, citing it simply as Engineering Systems. Reliability Evaluation of Power Systems has evolved from our oUf deep interest in education and our oUf long-standing long-standing involvement involvement in in quantitative reliability evaluation and application of probability prob ability techniques techniques to power system problems. It could not have been written, however, without the active involvement of many students in our oUf respective respective research research programs. programs. There have been too many to mention individually but most are recorded within the references at the ends of chapters.

The properties of materials depend on the characteristics of the bulk and on those of the surf ace. Any change in surface characteristics affects a wide variety of material properties. During the last few years the role of surface phenomena in metallurgy has been the subject of many studies. Surface energy, surface tension, the activity of surfaces, and related problems are under discussion in the western world * as well as in the eastern world. t The relation between volume and surface properties in metals and alloys has been investigated and is still under investigation. Materials are frequently exposed to environments which change their physical and chemical characteristics on account of a reaction going on between the material surface and the environment. The science and technology of surface preparation ro improve material properties have gained importance during the last decade in many parts of the world. Main efforts have been concentrated especially on the coating of material surfaces in connection with the exposure of these materials to space en vironment."

This book presents a critical review on the development and application of hygrothermal analysis methods to simulate the coupled transport processes of Heat, Air, and Moisture (HAM) transfer for one or multidimensional cases.
During the past few decades there has been relevant development in this field of study and an increase in the professional use of tools that simulate some of the physical phenomena that are involved in Heat, Air and Moisture conditions in building components or elements. Although there is a significant amount of hygrothermal models referred in the literature, the vast majority of them are not easily available to the public outside the institutions where they were developed, which restricts the analysis of this book to only 14 hygrothermal modelling tools.
The special features of this book are (a) a state-of-the-art of numerical simulation tools applied to building physics, (b) the boundary conditions importance, (c) the material properties, namely, experimental methods for the measurement of relevant transport properties, and (d) the numerical investigation and application
The main benefit of the book is that it discusses all the topics related to numerical simulation tools in building components (including state-of-the-art and applications) and presents some of the most important theoretical and numerical developments in building physics, providing a self-contained major reference that is appealing to both the scientists and the engineers. At the same time, this book will be going to the encounter of a variety of scientific and engineering disciplines, such as civil and mechanical engineering, architecture, etc... The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional colleagues.

A fundamental knowledge and understanding of dental materials is an absolute requisite to performing optimal dental care. This tenet is true not only for general dentists, but also for specialists alike. It is true not only for the developing dental student, but also for the practicing dentist. It is clearly evident that the authors of Dental Biomaterials have both an in-depth knowledge of dental materials and a fundamental appreciation for the importance of this information in contemporary clinical dentistry. Owing to the broad range of expertise of the authors, this textbook distinguishes itself from most dental materials texts by its remarkable ability to address a myriad of dental materials in the context of actual clinical applications. Emphasizing the clinical significance of dental materials is an obvious and conspicuous goal of this text that pervades the entire content of its pages. In fact, to that end, the authors notably include numerous highlighted sections entitled "Dental Significance" throughout the chapters to underscore the clinical importance of the subject matter. This approach is exceptionally effective at fostering a basic understanding of dental materials for the dental student. It piques the interest without stifling the student with abstract concepts. This text also is a valuable and reliable resource for the practicing dentist.

Nanoindentation, Third Edition gives a detailed account of the most up-to-date research in this important field of materials testing. As in previous editions, extensive theoretical treatments are provided and explained in a clear and consistent manner that will satisfy both experienced and novice scientists and engineers. Additionally, numerous examples of the applications of the technique are provided directly from manufacturers of nanoindentation instruments. A helpful series of appendices provides essential reference information that includes a list of frequently asked questions. The new edition has been restructured to provide results of the latest research and developments in the field of mechanical testing while retaining the essential background and introductory, but authoritative nature, of the previous editions. The new edition also expands on the instrumentation and applications chapters by including material sourced direct from the instrument manufacturers in this field. Aimed at graduate student level, this book is designed to fill a need associated with the use of nanoindentation as a quantitative test method for mechanical properties of small volumes of materials.

The second edition of this textbook is identical with its fourth German edi tion and it thus has the same goals: precise definition of basic phenomena, a broad survey of the whole field, integrated representation of chemistry, physics, and technology, and a balanced treatment of facts and comprehen sion. The book thus intends to bridge the gap between the often oversimpli fied introductory textbooks and the highly specialized texts and monographs that cover only parts of macromolecular science. The text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be inde pendent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of polymers. Properties depend on structure. Solution properties are thus discussed in Part 11, solid state properties in Part Ill. There are other reasons for dis cussing properties before synthesis: For example, it is difficult to understand equilibrium polymerization without knowledge of solution thermodynamics, the gel effect without knowledge of the glass transition temperature, etc. Part IV treats the principles of macromolecular syntheses and reactions."

The authors of this contribution to the literature of resonance spectroscopy in paramagnetic systems are primarily concerned with the properties of the rare earth ions and, as such, the formal derivation of crystal field theory is set out in a manner which reflects this dominant interest. The ions of the 3d transition group are perhaps given too cursory a treatment in Chapter Two for those students of RF spectroscopy who have a somewhat less rare-earth oriented interest in the subject. Since the exam ples cited in the text do include some 3d transition ions, it is perhaps worthwhile in a preface of this sort to extend the broad theoretical concepts and group characteriza tion of Chapter Two to cover, in a somewhat more detailed manner, the derivation of the spin-Hamiltonian for this case. In Chapter Two, mention is made of the fact that for the 4f rare earth ions the spin orbit coupling energy is in general large compared to the crystal field influence of the surrounding ligand matrix. In such a case, the quantum number J is a good quantum number for the rare earth ion in question and the crystal field effects are taken into account within 1M, states. In this formulation, which is pursued in detail in this book, the effects of spin-orbit coupling have been taken care of at the very outset by the d "ining of the 1M, states."

During the last decades modelling of inelastic structural behaviour has achieved great attention. Wherever elastic designhas reached its limita sa consequence of increased loading, the related cons titutive rela tions meanwhile have become part of the engineer's practice. However, new materials with complex behaviour, further increasing loads at higher temperatures, as well as the implementation of stronger security demands have led to theconsequence that the preferentially used phenomenological concepts need to be verified and improved continuously. Caused by the a priori non linear character oft he material rela tions, all equations fort he description of every new phenomenon need to be reconsidered. According to this, since about a decade the idea succeeds that constitutive relations which represent material behaviour more re alistically can not only be deduced phe nomenologicallyfrom the laws of continuum mechanics. Sincet he observed behaviour is caused by processes taking place on the microscale, these processes and mechanisms need to be taken into consideration when determining the constitutive relations. The formulation of proper micro macro relations actu ally is one of the main emphases in thermoplasticity in the international research. The intentiono ft he IUTAM Symposium on 'Micro and Macrostructural Aspects of Thermoplasticity', held at the Ruhr University of Bochum, Germany, from August 25 to 29, 1997, wast o bring together eminent scientistsworking i n different fields of thermoplasticity with the aim thatt hey may exchange their ideas and activate this interaction.

In the near future the world will need to convert to a suitable, clean energy supply: one that will meet the demands of an increasing population while giving few environmental problems. One such possible supply is hydrogen. Hydrogen Energy System describes the present status of hydrogen as an energy supply, as well as its prospect in the years to come. It covers the transition to hydrogen-based, sustainable energy systems, the technology of hydrogen production, its storage and transport, and current and future hydrogen utilisation. Economic analyses of the hydrogen energy system, together with case studies, are also presented.

Molecular systems are assemblies of molecules designed to possess special qualities and desired functionality. Such systems are important because they provide materials with novel properties, and they will be particularly useful for minimizing electronic devices. Molecular systems often form organized molecular crystals, polymers, or thin films that are significantly more complex than current materials. To provide a sound basis for understanding these levels of complexity, this book provides an analysis of the fundamentals of electronic structures, dynamic processes in condensed phases, and the unique properties of organic molecular solids and the environmental effects on these properties. Also covered are the latest methods in physical chemistry that are particularly useful for deriving and controlling the functionality of molecular systems. A second volume subtitled From Molecular Systems to Molecular Devices is also being published.

The last decade or so has seen a dramatic increase in the amount of detailed structural information available from a range of experimental techniques. Exciting new techniques such as atomic force microscopy have become widely available, while the potential of established methods like X-ray diffraction and electron microscopy has been greatly enhanced by powerful new sources and analytical methods. Progress in computing has also had a widespread impact: in areas such as neutron scattering, large data sets can now be manipulated more readily. The software supplied with commercial instruments generally provides more sophisti cated analytical facilities, while time-resolved X-ray studies rely on rapid data handling capabilities. The polymer scientist is faced with an expanding array of experimental tools for addressing both fundamental science and industrial problems. This work reviews some recent developments in structural techniques, with the aim of presenting the current 'state of the art' in a selection of areas."

Countless pages have been written on alternative energy sources since the fall of 1973 when our dependence on fossil petroleum resources became a grim reality. One such alternative is the use of biomass for producing energy and liquid and gaseous fuels. The term "biomass" generally refers to renewable organic matter generated by plants through photosynthesis. Thus trees, agri cultural crops, and aquatic plants are prime sources of biomass. Furthermore, as these sources of biomass are harvested and processed into commercial prod ucts, residues and wastes are generated. These, together with municipal solid wastes, not only add to the total organic raw material base that can be utilized for energy purposes but they also need to be removed for environmental reasons. Biomass has been used since antiquity for energy and material needs. In is still one of the most sought-after energy sources in most of the fact, firewood world. Furthermore, wood was still a dominant energy source in the U. S. only a hundred years ago (equal with coal). Currently, biomass contributes about 15 2 quadrillion Btu (l quad = 10 Btu) of energy to our total energy consump tion of about 78 quad. Two quad may not seem large when compared to the contribution made by petroleum (38 quad) or natural gas (20 quad), but bio mass is nearly comparable to nuclear energy (2. 7 quad).

The Progress in Medical Radiation Physics series presents in-depth reviews of many of the significant developments resulting from the application of physics to medicine. This series is intended to span the gap between research papers published in scientific journals, which tend to lack details, and complete textbooks or theses, which are usually far more detailed than necessary to provide a working knowledge of the subject. Each chapter in this series is designed to provide just enough information to enable readers to both fully understand the development described and apply the technique or concept, if they so desire. Thorough references are provided for those who wish to consider the original literature. In this way, it is hoped that the Progress in Medical Radiation Physics series will be a catalyst encouraging medical physicists to apply new techniques and developments in their daily practice. Colin G. Orton ix Contents 1-1. The Tracking Cobalt Project: From Moving-Beam Therapy to Three-Dimensional Programmed Irradiation W. A. Jennings 1. Introduction 2. Establishing Moving-Beam Techniques at the Royal Northern Hospital, 1945-1955 4 2.1. Alternative Moving-Beam Techniques 4 2.2.