In this volume, the shock compression technology of materials is described in parallel with the latest research results and their background. In the past, this type of technology was developed in connection with military techniques by certain particular research organizations. For this reason, researchers of materials in general have had less opportunity to make use of the technology. The conventional technology of shock compression has now been established, and is recognized as being remarkably useful as a means of materials science study. The feasibility of shock compression technology is dealt with in this book, as well as the latest research results for general material scientists. The shock synthesis of ceramics and intermetallic compounds, as well as shock compression behavior, are also described. In contrast to conventional works of this kind, this book describes shock compression studies performed by material scientists.

The triennial International Alloy Conferences (lACs) aim at the identification and promotion of the common elements developed in the study, either experimental, phenomenological, or theoretical and computational, of materials properties across materials types, from metals to minerals. To accomplish this goal, the lACs bring together scientists from a wide spectrum of materials science including experiment, theory, modeling, and computation, incorporating a broad range of materials properties. The first lAC, lAC-I, took place in Athens, Greece, June 16-21, 1996. The present volume of proceedings contains the papers presented at IAC-2, that took place in Davos, Switzerland, August 8-13, 1999. The topics in this book fall into several themes, which suggest a number of different classification schemes. We have chosen a scheme that classifies the papers in the volume into the categories Microstructural Properties; Ordering, Kinetics and Diffusion; Magnetic Properties and Elastic Properties. We have juxtaposed apparently disparate of revealing the dynamic character approaches to similar physical processes, in the hope of the processes under consideration. We hope this will invigorate new kinds of discussion and reveal challenges and new avenues to the description and prediction of properties of materials in the solid state and the conditions that produce them.

Thisbookistalkingabouthowtousesupercriticalwater(SCW)torapidlyproduce micro- and nano-particles of metal oxides, inorganic salts, metals and organics. Itcoversbasicprinciples,experimentalmethodologiesandreactors,particlep- duction,characterizationsandapplicationsaswellastherecentadvancement. Fine particlescanbeproducedbybothchemicalandphysicalprecipitationofproducts from SCW. They can be used as catalysts, materials in ceramics and electronic devices andcompositematerials. Particlesareeasilyproduced continuouslyina owreactorinshortreactiontimes(0. 4s?2min)butcanalsobesynthesizedin batchreactorsforlongreactiontimes(e. g. ,12h). Theycanbeeasilystudiedin-situ microscopically(optical/IR/Raman/SR-XRD)inanopticalmicro-reactor,diamond anvilcell. Thesize,sizedistribution,crystalgrowth&structure,andmorphologyof particlescanbecontrolledbychangingtheconcentrationsofstatingmaterials,pH, pressures,temperatures,heating&coolingrates,organicmodi cations,reducingor oxidizingatmospheres, owratesandreactiontimes. Thisisthe rstbooktosystematicallyintroduceusingSCWforproductionof neparticles. Itisanidealreferencebookforengineers,researchersandgraduate studentsinmaterialscienceandengineering. vii Acknowledgments I would like to thank Drs. T. Ogi & T. Minowa (Biomass Technology Research Center,NationalInstituteofAdvancedIndustrialScienceandTechnology,Japan), and Profs. K. Arai, H. Inomata, R. L. Smith Jr. and T. Adschiri (Chemical Engineering,TohokuUniversity,Japan),whoinitiallyintroducedthehydrothermal andsupercritical uidsareastomewhenIworkedinJapanfrom1996to1999. Thanks are also due to Profs. J. A. Kozinski, R. I. L. Guthrie (Materials Engineering,McGillUniversity,Canada)andI. S. Butler(Chemistry,McGill)for theirguidanceinmyworkonhydrothermalprocessduringmyworkinCanadafrom 1999to2007. Profs. W. Bassett (Geological Sciences, Cornell University) and D. Baker (Earth&PlanetarySciences,McGill)forinstructionsregardingDAC,Dr. I-Ming Chou(U. S. GeologicalSurvey)forusefuldiscussionsofthepressurecalculation procedure. Drs. M. Watanabe and T. Sato (Research Center of Supercritical Fluid Technology, Tohoku University, Japan) for discussions about the experimental set-upofthebatchand owreactors. Drs. S. Xu,H. Assaaoudi,R. HashaikehandA. Sobhy,whoworkedwithmeat McGillinCanada. ix Contents 1 Introduction...1 1. 1 Background ...1 1. 2 RapidExpansionofSupercriticalSolution(RESS)Process ...4 1. 3 SupercriticalAntisolvent(SAS)Process ...4 1. 4 OtherPhysicalProcesses ...5 1. 5 SupercriticalWaterProcess ...5 References...8 2 Supercritical Water Process...11 2. 1 Introduction ...11 2. 2 BatchReactor ...15 2. 3 FlowReactor...18 2. 4 DiamondAnvilCell(DAC)...20 References...25 3 Metal Oxides Synthesis...29 3. 1 Introduction ...29 3. 2 Boehmite(AlOOH) ...30 3. 3 Ferrites...31 3. 4 Phosphor(YAG) ...32 3. 5 LiCoO /LiMn O ...33 2 2 4 3. 6 Ce Zr O (x =0?1)...33 1?x x 2 3. 7 PotassiumHexatitanate,PotassiumNiobateandTitania ...35 3. 8 ZincOxide...38 3. 9 Nickel,Nickel/CobaltOxide...

The synthesis of multicomponent/multilayered superconducting, conducting, semiconducting and insulating thin films has become the subject of an intensive, worldwide, interdisciplinary research effort. The development of deposition-characterization techniques and the science and technology related to the synthesis of these films are critical for the successful evolution of this interdisciplinary field of research and the implementation of the new materials in a whole new generation of advanced microdevices. This book contains the lectures and contributed papers on various scientific and technological aspects of multicomponent and multilayered thin films presented at a NATO/ASI. Compared to other recent books on thin films, the distinctive character of this book is the interdisciplinary treatment of the various fields of research related to the different thin film materials mentioned above. The wide range of topics discussed in this book include vacuum-deposition techniques, synthesis-processing, characterization, and devices of multicomponent/multilayered oxide high temperature superconducting, ferroelectric, electro-optic, optical, metallic, silicide, and compound semiconductor thin films. The book presents an unusual intedisciplinary exchange of ideas between researchers with cross-disciplinary backgrounds and it will be useful to established investigators as well as postdoctoral and graduate students.

Modulated crystals have been intensively investigated over the past several years and it is now evident that an understanding of their crystallography and microstructure is fundamental to the elucidation of the physical properties and phase transitions in these materials. This book brings together for the first time the crystallographic descriptions and experimental methods for the structural and microstructural analysis of modulated crystals as described by well-known researchers in the various areas. The emphasis is on charge density wave modulations, and the detailed analysis of the prototypical NbTe4/TaTe4 system gives practical applications of the methods. Scanning Tunnelling Microscopy is a new technique providing significant new insights into atomic scale details of the modulations' structures and a chapter on this method is included.

Intersubband transitions in quantum wells have attracted tremendous attention in recent years, mainly due to the promise of applications in the mid and far-infrared regions (2--20 mum). Many of the papers presented in Quantum Well Intersubband Transition Physics and Devices are on the basic linear intersubband transition processes, detector physics and detector application, reflecting the current state of understanding and detector applications, where highly uniform, large focal plane arrays have been demonstrated. Other areas are still in their early stages, including infrared modulation, harmonic generation and emission.

4. 2 Solid Circular Shafts-Angle of Twist and Shearing Stresses 159 4. 3 Hollow Circular Shafts-Angle of Twist and Shearing Stresses 166 4. 4 Principal Stresses and Strains Associated with Torsion 173 4. 5 Analytical and Experimental Solutions for Torsion of Members of Noncircular Cross Sections 179 4. 6 Shearing Stress-Strain Properties 188 *4. 7 Computer Applications 195 5 Stresses in Beams 198 5. 1 Introduction 198 5. 2 Review of Properties of Areas 198 5. 3 Flexural Stresses due to Symmetric Bending of Beams 211 5. 4 Shear Stresses in Symmetrically Loaded Beams 230 *5. 5 Flexural Stresses due to Unsymmetric Bending of Beams 248 *5. 6 Computer Applications 258 Deflections of Beams 265 I 6. 1 Introduction 265 6. 2 Moment-Curvature Relationship 266 6. 3 Beam Deflections-Two Successive Integrations 268 6. 4 Derivatives of the Elastic Curve Equation and Their Physical Significance 280 6. 5 Beam Deflections-The Method of Superposition 290 6. 6 Construction of Moment Diagrams by Cantilever Parts 299 6. 7 Beam Deflections-The Area-Moment Method 302 *6. 8 Beam Deflections-Singularity Functions 319 *6. 9 Beam Deflections-Castigliano's Second Theorem 324 *6. 10 Computer Applications 332 7 Combined Stresses and Theories of Failure 336 7. 1 Introduction 336 7. 2 Axial and Torsional Stresses 336 Axial and Flexural Stresses 342 7. 3 Torsional and Flexural Stresses 352 7. 4 7. 5 Torsional, Flexural, and Axial Stresses 358 *7. 6 Theories of Failure 365 Computer Applications 378 *7.

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100 DegreesC, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects."

A special survey of the extensive field of Constitutive Laws is given in 11 lectures, divided into three parts: Thermodynamics of Materials, Stochastic Processes and Material Behaviour, Constitutive Relations for Simple Fluids and Microphysics of Solids. The collection of lectures comprehends a novel survey of thermodynamical constitutive theories, and contributions to material theories with after-effects including experiments, stochastic constitutive laws, molecular dynamics for simulating material properties, electrodynamical constitutive properties, and thermodynamic and microphysical modelling of polymers. The selected lectures emphasize the microstructural aspect of constitutive laws, and this collection presents a new facet of constitutive laws.

During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree."

This volume contains the lectures presented at the mini-symposium on "Micromechanics" held in conjunction with the CSME Mechanical Engineer ing Forum 1990 between the 3rd and 8th June, 1990 at the University of Toronto, Canada. The expressed purpose of this symposium was to discuss some recent developments in the Micromechanics of Materials and how ad vances in this field now relate to the solution of practical engineer ing problems. Due to the time limit set for this section of the Engineer ing Forum as well as the restriction on the number of papers to be pre sented, it was not possible to cover a much wider range of topics. How ever, an attempt was made to include the most important advances asso ciated with the progress made in micromechanics in its application to material science and engineering over the past decade. Thus, the topics are concerned with: the fundamental aspects of the thermodynamics of structured solids (part I), - the micromechanical behaviour of alloys (part II), - the modelling of the material behaviour on the basis of continuum theory (part III), and finally the important new approach to the characterization of various mate rials and their responses to external agencies by the use of proba bilistic micromechanics (part IV). We would like to take this opportunity to thank the Chairman of the Organizing Committee, Prof. F. P. J. Rimrott, and the President of the CSME, Prof. T. S."

Progress in Pacific Polymer Science 3 continues the record of the current status of major topics in polymer science.
The invited lecturers cover the following topics:
- Adding Value to Natural Polymers
- Polymers and the Environment
- Polymers in Mining and Mineral Processing
- Multicomponent Polymer Systems
- Characterization, Properties and Processing
- Functional Polymers
- Polymers for Medical Applications
- Polymer Recycling
- Polymer Surfaces of Biological Significance
- New and Advanced Polymer Materials

The 1984 Advanced Study Institute on "Electronic Structure, Dynamics and Quantum Structural Properties of Condensed Matter" took place at the Corsendonk Conference Center, close to the City of Antwerpen, from July 16 till 27, 1984. This NATO Advanced Study Institute was motivated by the research in my Institute, where, in 1971, a project was started on "ab-initio" phonon calculations in Silicon. I~ is my pleasure to thank several instances and people who made this ASI possible. First of all, the sponsor of the Institute, the NATO Scientific Committee. Next, the co-sponsors: Agfa-Gevaert, Bell Telephone Mfg. Co. N.V., C & A, Esso Belgium*, CDC Belgium, Janssens Pharmaceutica, Kredietbank and the Scientific Office of the U.S. Army. Special thanks are due to Dr. P. Van Camp and Drs. H. Nachtegaele, who, over several months, prepared the practical aspects of the ASI with the secretarial help of Mrs. R.-M. Vandekerkhof. I also like to. thank Mrs. M. Cuyvers who prepared and organized the subject and material index and Mrs. H. Evans for typing-assist ance. I express particular gratitude to Mrs. F. Nedee, who, like in 1981 and 1982, has put the magnificent Corsendonk Conference Center at our disposal and to Mr. D. Van Der Brempt, Director of the Corsendonk Conference Center, for the efficient way in which he and his staff took care of the practical organization at the Conference Center.

This book is about thin films; what they are, how they are prepared, how they are characterized, and what they are used for. The contents of this book not only showcase the diversity of thin films, but also reveals the commonality among the work performed in a variety of areas. The chapters in this volume are based on invited papers presented by prominent researchers in the field at a Symposium on "Thin Films: Preparation, Characterization, Applications" at the 221st National Meeting of the American Chemical Society held in San Diego, California. The coverage of the symposium was extensive; topics ranged from highly-ordered metal adlayers on well-defined electrode surfaces to bio-organic films on non-metallic nanoparticles. An objective of this book is for the readers to be able to draw from the experience and results of others in order to improve and expand the understanding of the science and technology of their own thin films systems.

Technological advances in semiconductor growth has opened a broad horizon for semiconductor physics and applications during the past 20 years. High quality two-. dimensional systems are achieved with nearly atomic precision by direct epitaxial growth. Such structures led to novel applications like low noise high frequency modulation doped field effect transistors and quantum well lasers. Semiconductor heterostructures of lower dimensionality like quantum wires and quantum dots are not yet as mature, partly due to the lack in precision oflateral structuring technology. In recent years, however, there was an enormous progress in novel epitaxial growth methods. This opens a wide new area of basic and applied semiconductor physics with the hope of novel applications in near future making use of the advantageous properties of one- and zero-dimensional systems. Ideas for future device applications mainly stem from the altered density of states being discrete or atomic-like for quantum dots. Optical spectroscopy has played and is playing a crucial role in the advancement of this fascinating field of semiconductor physics. The NATO school organized at Bilkent University in Ankara and in Antalya brought together experts in this field and newcomers, especially young Ph. D. students and postdocs, to learn about recent developments and to discuss open questions in the area of optical spectroscopy of low dimensional semiconductors. The school turned out to be extremely fruitful and there was a great enthusiasm among the lecturers and students during the whole two weeks.

Nanotribology: Critical Assessment and Research Needs is an excellent reference for both academic and industrial researchers working in the fields of nanotechnology, tribology, mechanical engineering, materials science and engineering, MEMS, NEMS, magnetic recording, and biomedical devices. It will also be of interest to those pursuing scanning probe microscopy, nanoimaging, mesomanufacturing, sensors, actuators, aerospace, defense (controllers, microsystems), and military systems. Nanotribology: Critical Assessment and Research Needs provides a critical assessment of the current state of the art of nanotribology within the context of MEMS, mesomanufacturing, nanotechnology and microsystems. It contains chapters written by the leading experts in these fields. It identifies gaps in current knowledge and barriers to applications, and recommends research areas that need to be addressed to enable the rapid development of technologies.

Over the past few years there has been a significant growth in the commercial application of a variety of processes which are all essentially based upon the very rapid heat treatment of powdered solid material in dilute gas suspensions. The objective of flash heating is usually to create a desirable product by means of physical and/or chemical transformations in the solid phase, usually with a high degree of control and with lower specific energy consumption than dense phase systems. Examples of successful flash reaction processing are to be found in the areas ofpyrometallurgy, mineral processing, plasma processing and, most recently, rapid prototyping. These developments have been based on, and have inspired, an expansion in fundamental research activities. As our understanding of flash reaction technology improves so does the need increase for the review of progress and the dissemination of accumulated knowl edge. Previous stocktaking on selected areas of flash reaction technology occurred in 1988 and can be found in the proceedings of three conferences held in that year: Flash Reaction Processes, Eds. D.G.C.Robertson, H.y'Sohn and N.J.Themelis, published by the Center for Pyrometallurgy, University of Missouri-Rolla, Rolla, MO 65401-0249; Production and Processing of Fine Particles, Ed. A.J .Plumpton, Pergamon Press, LeN 88-22755; High Temperature Dust-Laden Jets in Plasma Technology, Eds. O.P.Solonenko and A.I.Fedorchenko, VSP, Utrecht, ISBN 90- 6764-120-0."

In this unique volume, renowned experts discuss the applications of fractals in petroleum research-offering an excellent introduction to the subject. Contributions cover a broad spectrum of applications from petroleum exploration to production. Papers also illustrate how fractal geometry can quantify the spatial heterogeneity of different aspects of geology and how this information can be used to improve exploration and production results.

Our rationale for the second edition remains the same as for the first edition, which appeared over twenty years ago. This is to offer simplified, useful and easily understood methods for dealing with the creep of components operating under conditions met in practice. When the first edition was written, we could not claim that the methods which were introduced were well-tried. They were somewhat conjectural, although firmly based, but not sufficiently well devel oped. Since that time, the Reference Stress Methods (RSM) introduced in the book have received much scrutiny and development. The best recognition we could have of the original methods is the fact that they are now firmly embedded in codes of practice. Hopefully, we have now gone a long way towards achieving our original objectives. There are major additions to this second edition which should help to justify our claims. These include further clarification regarding Reference Stress Methods in Chapter 4. There are also new topics which depend on RSM in varying degrees: * Creep fracture is covered in Chapter 7, where methods for assessing creep crack initiation and crack growth are fully described. This chapter starts with a review of the basic concepts of fracture mechanics and follows with useful, approximate methods, compatible with the needs of design for creep and the availability of standard data. * Creep/fatigue interactions and environmental effects appear in Chapter 8.

This volume contains written versions of the papers presented at the Second Inter national Conference on Amorphous and Crystalline Silicon Carbide and Related Materials (ICACSC 1988), which was held at Santa Clara University on Decem ber 15 and 16, 1988. The conference followed the First ICACSC held at Howard University, Washington DC, in December 1987 and continued to provide an in ternational forum for discussion and exchange of ideas and results covering the current status of research on SiC and related materials. ICACSC 1988 attracted 105 participants from five countries. The substantial increase in the number of papers compared with the previous year is an indication of the growing interest in this field. Of the 45 papers presented at the conference, 36 refereed manuscripts are included in this volume, while the remaining 9 appear as abstracts. The six invited papers provide detailed reviews of recent results on amorphous and crystalline silicon carbide materials and devices, as well as diamond thin films. The volume is divided into six parts, each covering an important theme of the conference.

This publication presents an up to date coverage of infrared thermography applied in the context of improved industrial activity and quality through automated inspection and control. It puts together concise and complete information on thermal non-destructive evaluation (NDE), a method for testing without damage, not yet available in an integrated, stand-alone format. All concepts discussed are explained in full and many industrial applications of the covered subjects are presented. Although the book is complete by itself extensive references to relevant research papers are given for further reading. Nondestructive Evaluation of Materials by Infrared Thermography is intended for a wide audience. It will help industrial engineers to implement nondestructive evaluation methods on the production line and enlarge their knowledge of industrial inspection techniques. It can also be used as a teaching aid at universities and colleges, especially in materials engineering curricula. Finally research centres will find it valuable as a reference book about thermal NDE.

Procedures for extracting or refining sensitive substances using dense gases have been developed for numerous purposes. Dense carbon dioxide is already being used industrially for decaffeination of coffee and extraction of hops. Further possible applications have been tested on the laboratory or pilot plant scales and shown to be mostly economical. Uses as varied as the non-aggressive extraction of spice, extraction of polymers, refining of spent oil, pyrolysis/extraction of wood and liquefaction of coal show the extremely wide range of application. The book comprehensively reviews the present state of development and features examples of application of this new technique.

Science and art of crystal growth represent an interdisciplinary activity based on fundamental principles of physics, chemistry and crystallography. Crystal growth has contributed over the years essentially to a widening of knowledge in its basic disciplines and has penetrated practically into all fields of experimental natural sciences. It has acted, more over, in a steadily increasing manner as a link between science and technology as can be seen best, for example, from the achievements in modern microelectronics. The aim of the course "Crystal Growth in Science and Technology" being to stress the interdisciplinary character of the subject, selected fundamental principles are reviewed in the following contributions and cross links between basic and applied aspects are illustrated. It is a very well-known fact that the intensive development of crystal growth has led to a progressive narrowing of interests in highly specialized directions which is in particular harmful to young research scientists. The organizers of the course did sincerely hope that the program would help to broaden up the horizon of the participants. It was equally their wish to contribute within the traditional spirit of the school of crystallography in Erice to the promotion of mutual understanding, personal friendship and future collaboration between all those who were present at the school.