This volume chronicles the proceedings of the Third Symposium on Metallized Plastics: Fundamental and Applied Aspects held under the auspices of the Dielectric Science and Technology Division of the Electrochemical Society in Phoenix, Arizona, October 13-18, 1991. This series of symposia to address the subject of metallized plastics was initiated in 1988 and the premier symposium was held in Chicago, October 10-12, 1988, followed by the second event in Montreal, Canada, May 7-10, 1990. The rroceedings of these two symposia have been properly documented ,2. The third symposium was a huge success like the previous two events, and all this is testimonial to the brisk interest and high tempo of R&D activity in the fie14 of metallized plastics. This further bolsters our earlier thinking that there was a conspicuous need to hold symposia on this topic on a regular basis and the fourth is planned for May 16-21, 1993 in Honolulu, Hawaii. The study of metallized plastics constitutes an important human endeavor l and as pointed out earlier there are myriad applications of metallized plastics ranging from very commonplace to exotic. Also a survey of the recent literature will reveal that both the fundamental and applied aspects of metallized plastics are being pursued with great vigor.

Few polymer chemists have much familiarity with recent developments in the synthesis of speciality polymers. This volume provides up-to-date reviews of areas of current interest and is directed at polymer chemists in the academic world and industry.

Countless pages have been written on alternative energy sources since the fall of 1973 when our dependence on fossil petroleum resources became a grim reality. One such alternative is the use of biomass for producing energy and liquid and gaseous fuels. The term "biomass" generally refers to renewable organic matter generated by plants through photosynthesis. Thus trees, agri cultural crops, and aquatic plants are prime sources of biomass. Furthermore, as these sources of biomass are harvested and processed into commercial prod ucts, residues and wastes are generated. These, together with municipal solid wastes, not only add to the total organic raw material base that can be utilized for energy purposes but they also need to be removed for environmental reasons. Biomass has been used since antiquity for energy and material needs. In is still one of the most sought-after energy sources in most of the fact, firewood world. Furthermore, wood was still a dominant energy source in the U. S. only a hundred years ago (equal with coal). Currently, biomass contributes about 15 2 quadrillion Btu (l quad = 10 Btu) of energy to our total energy consump tion of about 78 quad. Two quad may not seem large when compared to the contribution made by petroleum (38 quad) or natural gas (20 quad), but bio mass is nearly comparable to nuclear energy (2. 7 quad).

This series was organized to provide a forum for review papers in the area of corrosion. The aim of these reviews is to bring certain areas of corrosiou science and technology into a sharp focus. The volumes of this series are published approximately on a yearly basis and each contains three to five reviews. The articles in each volume are selected in such a way as to be of interest both to the corrosion scientists and the corrosion technologists. There is, in fact, a particular aim in juxtaposing these interests because of the importance of mutual interaction and interdisciplinarity so important in corrosion studies. It is hoped that the corrosion scientists in this way may stay abreast of the activities in corrosion technology and vice versa. In this series the term "corrosion" is used in its very broadest sense. It includes, therefore, not only the degradation of metals in aqueous en vironment but also what is commonly referred to as "high-temperature oxidation. " Further, the plan is to be even more general than these topics; the series will include all solids and all environments. Today, engineering solids include not only metals but glasses, ionic solids, polymeric solids, and composites of these. Environments of interest must be extended to liquid metals, a wide variety of gases, nonaqueous electrolytes, and other non aqueous liquids."

Assessing the quality of textiles using textile microscopy remains one of the important instruments for permanent process improvement in the fiber, textile and apparel industries. The degree of international interlinking in the textile producing and finishing industries and their markets demands dearly defined and reproducible methods of detecting damage or defects at all process stages. This book -Quality Assessment of Textiles -Damage Detection by Microsco- py - has in the meantime established itself so well as "the Mahall" in research institute laboratories investigating defects, in universities and colleges, in the training of textile chemists and technologists, and in the industry and the retail trade, that it has become necessary to bring out a new edition. This edition has been revised and supplemented by Mr. Mahall and his succes- sor Ms. Irmhild Goebel and her staff. Cognis, as the successor organization continuing the textile business of the for- mer Textile Technology department of Henkel, is pleased to make this new edi- tion available to specialists, to students and to any other interested readers. June 2002 Dr. U. Kloubert (Cognis Deutschland GmbH & Co. KG) Prof E. Finnimore (Fachhochschule Hof, Germany) Foreword to the First Edition Quality is the decisive criterion by which textile industry is measured in the international competition. Today this is particularly true.

The problem of developing metal matrix (MCM) and metal-polymer (MPCM) composite materials is one of the most important in present day materials technology, for its solution is pivotal to the development of a number of leading technologies. The development of new fibrous and lamellar composite materials with improved physico-chemical, electrical, thermal and other properties is a springboard for qualitative scientific and technological advances not only in aerospace and shipbuilding technologies, but also in mechanical, power, electronic, electrical, radio engineering, transport, construction and other industries. The volume reviews the results of research programmes ac complished in recent years by Soviet scientists in the development of composite materials based on aluminium and magnesium matrices, polymatrix composites (composite materials) with metal and polymeric matrices reinforced with boron and carbon fibres, steel wire, fibre glass and other fillers. The volume also reviews present-day physico-chemical fundamen tals and basic principles for developing and optimizing metal matrix composites, and describes the most expedient and efficient methods of MCM and MPCM manufacturing. Special attention is devoted to the issue of manufacturing MCM structural members, and their machin ing and plastic working, as well as to coupling techniques."

Motivation The other day I was waiting at the station for my train. Next to me a young lady was nonchalantly leaning against the wall. Suddenly, she took a cigarette pack out of her handbag, pulled out the last cigarette, put it between her lips, crushed the empty pack, threw it on the ground and hedonistically lit the cigarette. I thought to myself, "What a behavior? ." The nearest trashcan was just five meters away. So I bent down, took the crushed pack and gave it back to her, saying that she had lost it. She looked at me in a rather deranged way, but she said nothing and of waste to the trashcan. brought the piece Often people are not aware of the waste they produce. They get rid of it and that's it. As soon as the charming lady dropped the cigarette pack, the problem was solved for her. The pack was on the ground and it suddenly no longer belonged to her. It is taken for granted that somebody else will do the cleaning up. There is a saying that nature does not produce waste. For long as humans obtained the goods they needed from the ground where they lived, the waste that was produced could be handled by nature. This has drastically changed due to urbanization and waste produced by human activities has become a severe burden.

A multi-authored, edited work. This volume forms a comprehensive treatise on the development, manufacture, testing and applications of a broad range of ceramic, glass ceramic and carbon matrix composite materials developed in the former Soviet Union. For each of these three classes of composite materials, background theory and extensive property data are also given.

Integrating both theoretical and applied aspects of electrochemistry, this acclaimed monograph series presents a review of the latest advances in the field. The current volume includes chapters on the mechanism of nerve excitation from an electrochemical standpoint, the electronic factor in the kinetics of charge-transfer reaction, and five other subjects.

In 1992 Acoustic Microscopy was published by Oxford University Press, in the series of Monographs on the Physics and Chemistry of Materials. Reviews appeared in the Journal of Microscopy [169 (1), 91] and in Contemporary Physics [33 (4), 296]. At the time of going to press, it seemed that the field of acoustic microscopy had settled down from the wonderful developments in resolution that had been seen in the late seventies and the early eighties and from the no less exciting developments in quantitative elastic measurements that had followed. One reviewer wrote, "The time is ripe for such a book, now that the expansion of the subject has perceptively slowed after it was detonated by Lemons and Quate. " [A. Howie, Proc. RMS 27 (4), 280]. In many ways, this remains true. The basic design for both imaging and quantitative instruments is well-established; the upper frequency for routine imaging is the 2 GHz established by the Ernst Leitz scanning acoustic microscope (ELSAM) in 1984. For the most accurate V(z) measurements, the 225-MHz line-focus-beam lens, developed at Tohoku Univer sity a little before then, remains standard. The principles of the contrast theory have been confirmed by abundant experience; in particular the role of surface acoustic waves, such as Rayleigh waves, dominates the contrast in most high resolution studies of many materials.

Conventional optical science and technology have been restricted by the diffraction limit from reducing the sizes of optical and photoruc devices to nanometric dimensions. Thus, the size of optical integrated circuits has been incompatible with that of their counterpart, integrated electronic circuits, which have much smaller dimensions. This book provides potential ideas and methods to overcome this difficulty. Near-field optics has developed very rapidly from around the middle 1980s after preliminary trials in the microwave frequency region, as proposed as early as 1928. At the early stages of this development, most technical efforts were devoted to realizing super-high-resolution optical microscopy beyond the diffraction limit. However, the possibility of exploiting the optical near-field, phenomenon of quasistatic electromagnetic interaction at subwavelength distances between nanometric particles has opened new ways to nanometric optical science and technology, and many applications to nanometric fabrication and manipulation have been proposed and implemented. Building on this historical background, this book describes recent progress in near-field optical science and technology, mainly using research of the author's groups. The title of this book, Near-Field Nano-Optics-From Basic Principles to Nano-Fabrication and Nano-Photonics, implies capabilities of the optical near field not only for imaging/microscopy, but also for fabrication/manipulation/proc essing on a nanometric scale.

The first NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts was held on September 10-22, 1989 in Akcay, Turkey. Based on the fundamental research of RRSchrock, RGrubbs and K.B.Wagener in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within the last years. Therefore the second NATO-ASI held on metathesis reactions was on Ring Opening Metathesis Po lymerization of Olefins and Polymerization of Alkynes on September 3-16, 1995 in Akcay, Turkey. The course joined inorganic, organic and polymer chemists to exchange their knowledge in this field. This volume contains the main and short lectures held in Akcay. To include ADMET reactions better into the title of this volume we changed it into: Metathesis Polymerization of Olefins and Alkyne Polymerization. This volume is addressed to research scientists, but also to those who start to work in the area of olefin metathesis and alkyne polymerization. The topics of the course were: mechanism of ROMP reactions/ new catalysts for ROMP/ new products by ROMP/ new catalysts for ADMET/ new products by ADMETI degradation of polymer by metathesis reactions/ alkyne polymerization and metathesis/ industrial application of metathesis reactions. The Advanced Study Institute was generously sponsored by the Scientific Affairs Division of NATO and the editor gratefully acknowledges this sponsorship. We also thank the Members of the Local Organizing Committee for their engagement on a successful NATO-AS ."

In this monograph the theory and methods of solving inverse Stefan problems for quasilinear parabolic equations in regions with free boundaries are developed. The study of this new class of ill-posed problems is motivated by the needs of the mod eling and control of nonlinear processes with phase transitions in thermophysics and mechanics of continuous media. Inverse Stefan problems are important for the perfection of technologies both in high temperature processes (e.g., metallurgy, the aircraft industry, astronautics and power engineering) and in hydrology, exploitation of oil-gas fields, etc. The proposed book will complete a gap in these subjects in the preceding re searches of ill-posed problems. It contains the new theoretical and applied studies of a wide class of inverse Stefan problems. The statements of such problems on the determination of boundary functions and coefficients of the equation are considered for different types of additional information about their solution. The variational method of obtaining stable approximate solutions is proposed and established. It is implemented by an efficient computational scheme of descriptive regularization. This algorithm utilizes a priori knowledge of the qualitative structure of the sought solution and ensures a substantial saving in computational costs. It is tested on model and applied problems in nonlinear thermophysics. In particular, the results of calculations for important applications in continuous casting of ingots and in the melting of a plate with the help of laser technology are presented."

An assessment of the recent achievements and relative strengths of two developing techniques for characterising surfaces at the nanometer scale: (i) local probe methods, including scanning tunnelling microscopy and its derivatives; and (ii) nanoscale photoemission and absorption spectroscopy for chemical analysis. The keynote lectures were delivered by some of the world's best scientists in the field and some of the topics covered include: (1) The possible application of STM in atomically resolved chemical analysis. (2) The principles of scanning force/friction and scanning near-field optical microscopes. (3) The scanning photoemission electron microscopes built at ELETTRA and SRRC, with a description of synchrotron radiation microscopy. (4) Recent progress in the development of spatially-resolved photoelectron microscopy, especially the use of zone plate photon optics. (5) The present status of non-scanning photoemission microscopy with slow electrons. (6) the BESSY 2 project for a non-scanning photoelectron microscope with electron optics. (7) Spatially-resolved in situ reaction studies of chemical waves and oscillatory phenomena with the UV photoemission microscope.

The development of new materials is recognized as one of the major elements in the overall technological evolution that must go on in order to sustain and even improve the quality of life for citizens of all nations. There are many components to this development, but one is to achieve a better understanding of the properties of materials using the most sophisticated scientific tools that are available. As condensed matter physicists and materials scientists work toward this goal, they find that it is useful to divide their efforts and focus on specific areas, because certain analytical and theoretical techniques will be more useful for the study of one class of materials than another. One such area is the study of metals and metallic alloys, which are used in the manufacture of products as diverse as automobiles and space stations. Progress in this area has been very rapid in recent years, and the new developments come from many different countries. For these reasons the Advanced Research Workshop Programme in the NATO Scientific Affairs Division has seen fit to sponsor several meetings to bring together the researchers and students working in this field from the NATO countries and elsewhere. There have been a series of NATO-ASI's that have dealt with the results of research on the electronic structure of materials and the properties of metals, alloys, and interfaces. They are: "Electrons in finite and infinite structures" P. Phariseau and L.

Five questions dominated the ARW on Physics and Materials Science of High Temperature Superconductors, of which this book forms the permanent record. Briefly, these are: (i) How close are we to a unified theory? The consensus is that we are not. (ii) Flux pinning: can it be achieved in bulk materials? Still an open question. The following three questions are related. (iii) Can grain boundary contributions be brought under control? (iv) What is the real requirement for purity and general chemistry control? (v)What is the practical outlook for bulk products - tapes and wires? One of the conclusions is that the geometry and dimensions in thin films are the key parameters that facilitate the realization of high current densities and, consequently, their commercial application. On the other hand, the very large number of poorly understood microstructural, chemical and mechanical variables involved in the preparation of bulk materials are currently prohibiting large scale commercialization of wires and tapes.

In this volume a survey of the most relevant nonlinear crack models is provided, with the purpose of analyzing the nonlinear mechanical effects occurring at the tip of macrocracks in quasi-brittle materials - such as concrete, rocks, ceramics, polymers, high-strength metallic alloys - and in brittle-matrix fibre-reinforced composites. Such local effects, as, for example, plastic deformation, yielding, strain-hardening, strain-softening, mechanical damage, matrix microcracking, aggregate debonding, fibre bridging, fibre slippage, crazing, and so on, are properly described through different simplified models, representing the peculiarities of the phenomena involved. The models are introduced and described separately and then compared in the last part of the book. This volume will be of interest to students, professionals and researchers in the field of nonlinear fracture mechanics.

CONJUGATED POLYMERS: THE IMTERPLAY BETWEEN SYNTHESIS, 1 STRUCTURE, AND PROPERTIES C. B. GORMAN and R. H. GRUBBS 1. Introduction 2 2. Structural Features of Conjuqated. Polyaers 3 3. Polymer Synthesis: Basic Methods 4 3. 1 Step-Growth Polymerization 5 3. 2 Chain-Growth Polymerization 6 3. 3 Rinq-Openinq Polymerization 8 4. Direct Synthetic Methods 8 4. 1 Electrochemical Synthesis 9 4. 2 Synthesis by Step-Growth Polymerization 11 4. 2. 1 Polyaniline (PAN) 11 4. 2. 2 Poly(Phenylene Sulfide) 12 4. 2. 3 Poly thiophene and its Derivatives 13 4. 2. 4 Other 5-membered Heterocyclic 16 Derivatives 4. 2. 5 Polyparaphenylene (PPP) 17 4. 2. 6 Polysilanes 18 4. 2. 7 Polymers of Phthalocyanines 19 4. 2. 8 Other Conjugated Metal Coordination 20 Polymers 4. 2. 9 Ladder Polymers 21 4. 3 The Unusual Topochemical Polymerization to 23 form Polydiacetylenes 4. 4 Chain-Growth Polymerizations 24 4. 4. 1 Polyacetylene via Ziegler-Natta 24 Polymerization 4. 4. 2 Ring-Opening Metathesis Polymerization 26 Routes to Polyacetylenes 5. Polymers fro. precursors 27 5. 1 Polyparaphenylene (PPP) 27 5. 2 Poly(Phenylene Vinylene) (PPV) and Other 28 Vinylene Polymers 5. 3 Precursors to Polyacetylene 29 6. Extentions of these Methods in the Synthesis of 31 *saall-Bandqap* Pplymers 7. Conjuqated. Polymer Matrices 33 8. Conclusions and Caveats 35 Acknowled. qements 36 References 36 vi TABLE OF CONTENTS PROPERTIES OF HIGHLY CONDUCTIHG POLYACETYLEHE 49 Th. SCHIMMEL, D. GLASER, M. SCHWOERER AND H. NAARMANN 1. Introduction 50 2. SBIlpie Synthesis, lIorphology and Properties 52 2.

It has been ten years since I presented the paper entitled "A new model and theory on yield and failure of materials under the complex stress state" at the Sixth Conference on Mechanical Behaviour of Materials held at Kyoto, Japan in 1991. The proceedings edited by Jono and Inoue were published by Pergamon Press in 1991. At that conference Professor Murakami and I were invited to act as the chairperson and co-chairperson of a session, and I presented the paper at another session. Few days before the conference, I had given a seminar regarding the tw- shear strength theory and the unified strength theory at Nagoya Technological University. These were the first two presentations of the unified strength theory, although I had completed the research of the unified strength theory in 1990. The paper "Twin-shear strength theory and its generalization" was published in the English edition of Sciences in China, the top journal in China, in 1985. The th original generalized twin-shear strength theory was presented at the 16 International Theoretical and Applied Mechanics Congress held at Copenhagen in Denmark and MPA (MaterialPrufungsAnstalt) at Stuttgart University, Germany in 1984. After this Congress I visited the MPA and School of Civil Engineering of Stuttgart University, and gave a seminar regarding the generalized twin-shear strength theory at MPA of Stuttgart University. Professor Otto Mohr (1835-1918) has had worked at the Stuttgart University. He was a very good professor, his lectures aroused great interest in his students."

Advanced composite materials have been a major research focus for the past forty years. As a reinforcement for conventional materials including glass, ceramics and polymers, carbon has proved to be the most successful. Carbon gives these materials flexibility so that they may be produced in bulk form with a wide variety of properties. Whereas carbon/carbon composites are the most effective materials in extreme temperature conditions. Application ranges from brakes to missile nose cones. Carbon Reinforcements and Carbon/Carbon Composites gives the present state on this subject in comprehensive form, as well as projections for other "High Tech" materials and their application.

Luminescence of Solids gathers together much of the latest work on luminescent inorganic materials and new physical phenomena. The volume includes chapters covering -- the achievements that have led to the establishment of the fundamental laws of luminescence -- light sources, light-dispersing elements, detectors, and other experimental techniques -- models and mechanisms -- materials preparation, and -- future trends. This international collection of cutting-edge luminescence research is complemented by over 170 illustrations that bring to life the text's many vital concepts.

Materials and Processes for Surface and Interface Engineering, which has been written by experts in the fields of deposition technology and surface modification techniques, offers up to date tutorial papers on the latest advances in surface and interface engineering. The emphasis is on fundamental aspects, principles and applications of plasma and ion beam processing technology. A handbook for the engineer and scientist as well as an introduction for students in several branches of materials science and surface engineering.

This volume contains papers presented at the NATO Advanced Research Workshop (ARW) on Photons and Local Probes. The workshop had two predecessors. The first was the NATO ARW on Near Field Optics, held in October 1992 at Arc et Senans and was organized by Daniel Courjon and Dieter Pohl. The other predecessor was a workshop on Photons and Scanning Probe Microscopies held at the University of Konstanz in July 1992. The workshop on Photons and Local Probes was held at the Loechnerhaus on the Reichenau Island at the Lake of Constance, from September 11 to 17, 1994. The Reichenau Island was an important place in Europe in the middle age. Even the tomb of one of the carolingian emperors, Charles the Fat, is located there. At this workshop more than 60 scientists from Europe and the United States met to communicate their latest results in the field of local probes in combination with optical techniques. In eight sessions 31 talks as well as 9 posters were presented. Among those 31 publications were submitted for publication in the NATO proceedings. They were accepted after a strict, but constructive refereeing process.

This volume is based on the proceedings of the NATO-sponsored Advanced Studies Institute (ASn on The New Superconducting Electronics (held 9-20 August 1992 in Waterville Valley, New Hampshire USA). The contents herein are intended to provide an update to an earlier volume on the same subject (based on a NATO ASI held in 1988). Four years seems a relatively short time interval, and our title itself, featuring The New Superconducting Electronics, may appear somewhat pretentious. Nevertheless, we feel strongly that the ASI fostered a timely reexamination of the technical progress and application potential of this rapid-paced field. There are, indeed, many new avenues for technological innovation which were not envisioned or considered possible four years ago. The greatest advances by far have occurred with regard to oxide superconductors, the so-called high transition-temperature superconductors, known in short as HTS. These advances are mainly in the ability to fabricate both (1) high-quality, relatively large-area films for microwave filters and (2) multilayer device structures, principally superconducting-normal-superconducting (SNS) Josephson junctions, for superconducting-quantum-interference-device (SQUID) magnetometers. Additionally, we have seen the invention and development of the flux-flow transistor, a planar three-terminal device. During the earlier ASI only the very first HTS films with adequate critical-current density had just been fabricated, and these were of limited area and had high resistance for microwave current."

In this volume there is set forth the text of the Pro ceedings of the Third International Conference on Sintering and Related Phenomena, which conference was held at the University of Notre Dame on June 5-7, 1972. This conference was the seventh in the series of University Conferences on Ceramic Science organized yearly by a happy "confederation" of four institutions; North Carolina State University, Raleigh, North Carolina; the University of California, Berkeley, California; Alfred University, Alfred, New York; and the University of Notre Dame, Notre Dame, Indiana. The 1972 Conference at Notre Dame was devoted to prob lems of sintering and allied phenomena. Previous gatherings at Notre Dame took place in 1954 and 1965. The proceedings of the first Notre Dame Conference were not published by reason of the conviction that a free forum similar in spirit to the Gordon Conferences should prevail. However, discus sions of the second Conference were preserved for posterity in a rather substantial volume (894 pp) published by Gordon and Breach in 1967. As the spirit of free exchange of ideas was not diminished by threat of publication of the revela tions of the second Notre Dame Conference, we deemed it just that the 1972 Proceedings be made public. Thus the present volume is a report upon progress realized in our science during the past six years.