The idea for putting together a tutorial on zeolites came originally from my co-editor, Eric Derouane, about 5 years ago. I ?rst met Eric in the mid-1980s when he spent 2 years working for Mobil R&D at our then Corporate lab at Princeton, NJ. He was on the senior technical staff with projects in the synthesis and characterization of new materials. At that time, I managed a group at our Paulsboro lab that was responsible for catalyst characterization in support of our catalyst and process development efforts, and also had a substantial group working on new material synthesis. Hence, our interests overlapped considerably and we met regularly. After Eric moved back to Namur (initially), we maintained contact, and in the 1990s, we met a number of times in Europe on projects of joint interest. It was after I retired from ExxonMobil in 2002 that we began to discuss the tutorial concept seriously. Eric had (semi-)retired and lived on the Algarve, the southern coast of Portugal. In January 2003, my wife and I spent 3 weeks outside of Lagos, and I worked parts of most days with Eric on the proposed content of the book. We decided on a comprehensive approach that ultimately amounted to some 20+ chapters covering all of zeolite chemistry and catalysis and gave it the title Zeolite Chemistry and Catalysis: An integrated Approach and Tutorial.

Dynamic Failure of Materials and Structures discusses the topic of dynamic loadings and their effect on material and structural failure. Since dynamic loading problems are very difficult as compared to their static counterpart, very little information is currently available about dynamic behavior of materials and structures. Topics covered include the response of both metallic as well as polymeric composite materials to blast loading and shock loadings, impact loadings and failure of novel materials under more controlled dynamic loads. These include response of soft materials that are important in practical use but have very limited information available on their dynamic response. Dynamic fragmentation, which has re-emerged in recent years has also been included. Both experimental as well as numerical aspects of material and structural response to dynamic loads are discussed. Written by several key experts in the field, Dynamic Failure of Materials and Structures will appeal to graduate students and researchers studying dynamic loadings within mechanical and civil engineering, as well as in physics and materials science.

Preface to Second Edition Several new topics have been added, some small errors have been corrected and some new references have been added in this edition. New topics include aberration corrected instruments, scanning confocal mode of operations, Bloch wave eigenvalue methods and parallel computing techniques. The ?rst edition - cluded a CD with computer programs, which is not included in this edition. - stead the associated programs will be available on an associated web site (currently people.ccmr.cornell.edu/~kirkland,but may move as time goes on). I wish to thank Mick Thomas for preparing the specimen used to record the image in Fig.5.26 and to thank Stephen P. Meisburger for suggesting an interesting biological specimen to use in Fig.7.24. Again, I apologize in advance for leaving out some undoubtedlyoutstanding r- erences. I also apologize for the as yet undiscovered errors that remain in the text. Earl J. Kirkland, December 2009 Preface to First Edition Image simulation has become a common tool in HREM (High Resolution El- tron Microscopy) in recent years. However, the literature on the subject is scattered among many different journals and conference proceedings that have occurred in the last two or three decades. It is dif?cult for beginners to get started in this ?eld.

From October 15 to 19, 1995 a Workshop on Hetero- structureEpitaxyandDeviceswasheldatSmoleniceCastlenear Slovakia'scapital Bratislava. The intention ofthisWorkshop was toestablishandstrengthentiesbetweenscientistsoftheformerly Socialist East and Middle-European states with their colleagues fromtheWesterncountries. WiththisaimtheWorkshopfoundthe financialsupportbyNATOwhichtremendouslyhelpedtofacilitate organizingthemeeting That the Workshop was also a scientific success is evidenced by the present volume comprising a selection of the contributed papers. We are confident that the reader of these Proceedings can convincehimselfofthe highqualityofthe work whose results are presented here. We hope that this and the numerousdiscussionsbetweenthe participants ofthe Workshop will promote cooperations among scientists from the countries representedatthemeeting. It is a pleasure to express our gratitude to NATO and, as representatives ofthe institutions involved in the organization, to Lubomir Malacky (Institute of Electrical Engineering, Slovak Academy of Sciences) and Hergo-Heinrich Wehmann (Institute for Semiconductor Technology, Technical University Braun- schweig) whose dedicated work was most essential for the Workshop. A. Schlachetzki J. Novak November1995 xiii SIMULATIONOFIII-VLAYERGROWTH y. ARIMA DepartmentofPhysics, Gakushuin University 1-5-1 Mejiro, Toshima-ku, Tokyo 171, Japan AND T. IRISAWA ComputerCenter, Gakushuin University 1-5-1 Mejiro, Toshima-ku, Tokyo 171, Japan 1. Introduction Since it was reported [1] that the intensities of RHEED for the growing surface of aGaAs crystal in the process of MBE oscillate with a period correspondingto the completion of a monolayer, this phenomenon has been applied to the thin layer growth of man-made superlattices.

This book offers systematic and up-to-date treatment of the whole area of magnetic domains. It contains many contributions that have not been published before. The comprehensive survey of this important area gives a good introduction to students and is also interesting to researchers.

"Semiconductor-On-Insulator Materials for NanoElectronics Applications" is devoted to the fast evolving field of modern nanoelectronics, and more particularly to the physics and technology of nanoelectronic devices built on semiconductor-on-insulator (SemOI) systems. The book contains the achievements in this field from leading companies and universities in Europe, USA, Brazil and Russia. It is articulated around four main topics: 1. New semiconductor-on-insulator materials; 2. Physics of modern SemOI devices; 3. Advanced characterization of SemOI devices; 4. Sensors and MEMS on SOI. "Semiconductor-On-Insulator Materials for NanoElectonics Applications" is useful not only to specialists in nano- and microelectronics but also to students and to the wider audience of readers who are interested in new directions in modern electronics and optoelectronics.

This book discusses future trends and developments in electron device packaging and the opportunities of nano and bio techniques as future solutions. It describes the effect of nano-sized particles and cell-based approaches for packaging solutions with their diverse requirements. It offers a comprehensive overview of nano particles and nano composites and their application as packaging functions in electron devices. The importance and challenges of three-dimensional design and computer modeling in nano packaging is discussed; also ways for implementation are described. Solutions for unconventional packaging solutions for metallizations and functionalized surfaces as well as new packaging technologies with high potential for industrial applications are discussed. The book brings together a comprehensive overview of nano scale components and systems comprising electronic, mechanical and optical structures and serves as important reference for industrial and academic researchers.

The micro- and nano-modification of infrastructure materials and the associated multi-scale characterization and simulation has the potential to open up whole new uses and classes of materials, with wide-ranging implications for society. The use of multi-scale characterization and simulation brings the ability to target changes at the very small scale that predictably effect the bulk behavior of the material and thus allowing for the optimization of material behavior and performance. The International RILEM Symposium on Multi-Scale Modeling and Characterization of Infrastructure Materials (Stockholm, June 10-12, 2013) brought together key researchers from around the world to present their findings and ongoing research in this field in a focused environment with extended discussion times. From asphalt to concrete, from chemistry to mechanics, from nano- to macro-scale: the collection of topics covered by the Symposium represents the width and depth of the currently ongoing efforts of developing more sustainable infrastructure materials. Researchers, practitioners, undergraduates and graduate students engaged in infrastructure materials or multi-scale characterization and modeling efforts can use this book as a comprehensive reference, to learn about the currently ongoing research efforts in this field or as an inspiration for new research ideas to enhance the long-term performance of infrastructure materials from a fundamental perspective. The Symposium was held under the auspices of the RILEM Technical Committee on Nanotechnology-Based Bituminous Materials 231-NBM and the Transport Research Board (TRB) Technical Committee on Characteristics of Asphalt Materials AFK20.

In this book, advanced steel technologies mainly developed at the National Institute for Materials Science (NIMS), Japan, for structure control, mechanical properties, and the related mechanisms are introduced and discussed. NIMS has long worked on developing advanced steel techniques, namely, producing advanced steels by using only simple alloying elements such as carbon, manganese, and silicon, and also by utilizing steel scrap. The hope is that this approach will lead to a technology of a so-called steel-to-steel recycling process, with the ultimate goal of a recycling process such as an automotive-steel-to-automotive-steel recycling process to take the place of the current cascade-type recycling system. The main idea is to utilize ultra-grain refining structures and hetero structures as well as martensite structures. In particular, the focus of this book is on tensile strength and toughness of advanced steels from both the fundamental and engineering points of view. Fundamentally, a unique approach to analysis is taken, based on fracture surface energy as effective grain size is employed to better understand the mechanism of property improvement. From the engineering point of view, in fracture toughness such factors as crack tip opening displacement (CTOD) of advanced steels are evaluated in comparison with those of conventional steels.

The subject of mechanical behavior has been in the front line of basic studies in engineering curricula for many years. This textbook was written for engineering students with the aim of presenting, in a relatively simple manner, the basic concepts of mechanical behavior in solid materials. A second aim of the book is to guide students in their laboratory experiments by helping them to understand their observations in parallel with the lectures of their various courses; therefore the first chapter of the book is devoted to mechanical testing. Another aim of the book is to provide practicing engineers with basic help to bridge the gap of time that has passed from their graduation up to their actual involvement in engineering work. The book also serves as the basis for more advanced studies and seminars when pursuing courses on a graduate level. The content of this textbook and the topics discussed correspond to courses that are usually taught in universities and colleges all over the world, but with a different and more modern approach. It is however unique by the inclusion of an extensive chapter on mechanical behavior in the micron and submicron/nanometer range. Mechanical deformation phenomena are explained and often related to the presence of dislocations in structures. Many practical illustrations are provided representing various observations encountered in actual structures of particularly technical significance. A comprehensive list of references at the end of each chapter is included to provide a broad basis for further studying the subject.

In 1991, my newly formed researchgroupat Berkeley was working intensely in the area of continuum-level constitutive relationships that could be obtained in a deductive mannerfrom microstructuralinformationthroughthemethods of homogenization theory. Of particular interest was the application of such methods to structural problems in the blossoming field of micromechanical devices. In this context it was becoming evident that we needed to learn to navigate through the continuum/discrete interface. Such were the circumstances when Vladimir Granik came to visit us at Berkeley for the first time. It is probably not surprising that we received with great enthusiasm his offer to join forces and develop a mechanics .of solid structures that would be based on a discrete representation of matter. Vladimir had established the foundations for such an endeavor with his work at Moscow University in the late 1970s. Since that first meeting, and with ever-increasing enthusiasm, it has been a great privilege for me to collaborate with Vladimir. We first applied the formalism of what has become known as "doublet mechanics" to the microstructure-based theory of failure of solids and worked on the paral- lels and differences between the doublet approach and homogenization, to- gether with Kevin Mon and Derek Hansford. Plane elastodynamics followed after Francesco Maddalena had proposed doublet viscoelesticity. The consti- tutive relationships in doublet mechanics were laid on a firm thermodynami- cal foundation through the work of Kevin Mon, while Miqin Zhang analyzed free boundary effects on multi-scale plane elastic waves in discrete domains.

This is the seventh volume of a well-established series in which expert practitioners discuss topical aspects of light scattering in solids. Emphasis is placed on electronic excitations between crystal-field split levels of transition-metal and rare-earth ions in crystals, among them high-Tc superconductors and magnetic excitations that appear in superlattices containing magnetic metals. The contents of this volume again demonstrates the usefulness of Raman spectroscopy for the investigation and characterization of this class of materials. It will be useful to advanced students and to all researchers who apply Raman spectroscopy in their work.

This is the first volume of a two-volume work which summarizes in an edited format and in a fairly comprehensive manner many of the recent technical research accomplishments in the area of Elastomers. "Advances in Elastomers" discusses the various attempts reported on solving these problems from the point of view of the chemistry and the structure of elastomers, highlighting the drawbacks and advantages of each method. It summarize the importance of elastomers and their multiphase systems in human life and industry, and covers all the topics related to recent advances in elastomers, their blends, IPNs, composites and nanocomposites. This first volume focuses on advances on the blends and interpenetrating networks (IPNs) of elastomers.

This book gives an overview on the fatigue of materials under non-proportional loads. It presents the rich spectrum of phenomena and treats various computational models to mathematically describe the non-proportional fatigue of materials.

The purpose of 'Numerical Analysis of Heat and Mass Transfer in Porous Media' is to provide a collection of recent contributions in the field of computational heat and mass transfer in porous media. The main benefit of the book is that it discusses the majority of the topics related to numerical transport phenomenon in engineering (including state-of-the-art and applications) and presents some of the most important theoretical and computational developments in porous media and transport phenomenon domain, providing a self-contained major reference that is appealing to both the scientists, researchers and the engineers. At the same time, these topics encounter of a variety of scientific and engineering disciplines, such as chemical, civil, agricultural, mechanical engineering, etc. The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional colleagues.

This book presents a method for replicating natural butterfly wing scales using a variety of metals for state-of-the-art applications requiring high surface-enhancement properties. During the past decade, three dimensional (3D) sub-micrometer structures have attracted considerable attention for optical applications. These 3D subwavelength metallic structures are, however, difficult to prepare. By contrast, the 3D superstructures of butterfly wing scales, with more than 175 000 morphologies, are efficiently engineered by nature. Natural butterfly wing scales feature 3D sub-micrometer structures that are superior to many human designs in terms of structural complexity, reproducibility, and cost. Such natural wealth offers a versatile chemical route via the replication of these structures into functional metals. A single versatile chemical route can be used to produce butterfly scales in seven different metals. These synthesized structures have the potential for catalytic (Au, Pt, Pd), thermal (Ag, Au, Cu), electrical (Au, Cu, Ag), magnetic (Co, Ni), and optical (Au, Ag, Cu) applications. Plasmon-active Au, Cu, Ag butterfly scales have exhibited excellent properties in surface-enhanced Raman scattering (SERS). The Au scales as SERS substrates have ten times the analyte detection sensitivity and are one-tenth the cost of their human-designed commercial counterparts (KlariteTM). Preliminary mechanisms of these surface-enhancement phenomena are also reviewed.

Nanoscale structures and materials have been explored in many biological applications because of their novel and impressive physical and chemical properties. Such properties allow remarkable opportunities to study and interact with complex biological processes. This book analyses the state of the art of piezoelectric nanomaterials and introduces their applications in the biomedical field. Despite their impressive potentials, piezoelectric materials have not yet received significant attention for bio-applications. This book shows that the exploitation of piezoelectric nanoparticles in nanomedicine is possible and realistic, and their impressive physical properties can be useful for several applications, ranging from sensors and transducers for the detection of biomolecules to "sensible" substrates for tissue engineering or cell stimulation.

Laser-enabled measurements are valuable tools for the investigation of surfaces and interfaces or for the in situ investigation of interfacial processes including electrode processes. The understanding of the thermodynamics of solid/liquid surfaces is important for surface science and electrochemistry. In the first part of this book, the authors describe a range of techniques for investigating interfacial tension and surface stress, which is important for coatings, thin films, and fuel cells. The techniques covered comprise bending beam (bending plate, bending cantilever, wafer curvature) methods with different detection techniques. Special attention is given to methods using optical detection by laser beam deflection or interferometry. The second part is devoted to the techniques based on the detection of refractive index gradients in the solution. The refractive index changes could be related to concentration gradients (Probe Beam Deflection, PBD) or light-induced thermal gradients (Photothermal Deflection Spectroscopy, PDS). The application of the techniques to surface-confined and solution electrochemical systems is described. Subsequently, a comparison with others techniques able to monitor ion fluxes is performed.

C axis Current I ~ . The (11 0) thick homoepitaxial film of 320 nm -------~ ~-=-=--==---==--==--==--- shows a very good surface flatness, which --------** sJ;1 0] suggests the unique (110) atomic plane helps 2- A [1 1 OJ dimensional epitaxial growth of YBCO films, and shows excellent high Tc. The resultant 1. 0 surface morphology of YBCO is quite different Q ,. -- R(270)=1. 60 m 0 from the (110) heteroepitaxial films of similar 0 0. 0 " thickness [11). In the case of heteroepitaxy ~ . ,,_. 1. 0 irrespective of c-axis [ 12] or a-axis oriented ~ ~. . ,. R(270)=3. 71 m 0 films [5), only thin films show flat surfaces, g 0. 0 . . Tc=92. 3K "' which, however, give usually a degraded Tc due -~ 1. 0 v v I - to lattice mismatching. In conclusion, we have ::1. ,. . . . . R(270)=31. 9 mO succeeded to grow high-quality (11 0) YBCO ~ YBCO film . . Tc=90. 7 K 0. 0 *;:: YBCO(IIO) 1 0 *d*--~ YBCO thinfilms on (11 0) YBCO single crystal substrate ~Xtt=u 1. 0 substra substrates with very flat surfaces and high Tc's. :GBP R(270)=40. 1 m 0 0. 0 LLLLL. J. . . . LL~. t-J' L-Tc=9LWO. L-! L-K LLLLL. . . . L. . I. . . . l. . . . L. L. L. J. . . . . L. L. l. . . J 50 100 150 200 250 300 0 ACKNOWLEDGMENTS Temperature (K) One of the authors (T. U. ) would like to thank Fig.

"Solid-State Theory - An Introduction" is a textbook for graduate students of physics and material sciences. Whilst covering the traditional topics of older textbooks, it also takes up new developments in theoretical concepts and materials that are connected with such breakthroughs as the quantum-Hall effects, the high-Tc superconductors, and the low-dimensional systems realized in solids. Thus besides providing the fundamental concepts to describe the physics of the electrons and ions comprising the solid, including their interactions, the book casts a bridge to the experimental facts and gives the reader an excellent insight into current research fields. A compilation of problems makes the book especially valuable to both students and teachers.

This volume of Modern Aspects covers a wide spread of topics presented in an authoritative, informative and instructive manner by some internationally renowned specialists. Professors Politzer and Dr. Murray provide a comprehensive description of the various theoretical treatments of solute-solvent interactions, including ion-solvent interactions. Both continuum and discrete molecular models for the solvent molecules are discussed, including Monte Carlo and molecular dynamics simulations. The advantages and drawbacks of the resulting models and computational approaches are discussed and the impressive progress made in predicting the properties of molecular and ionic solutions is surveyed. The fundamental and applied electrochemistry of the silicon/electrolyte interface is presented in an authoritative review by Dr. Gregory Zhang, with emphasis in the preparation of porous silicon, a material of significant technological interest, via anodic dissolution of monocrystalline Si. The chapter shows eloquently how fundamental electrokinetic principles can be utilized to obtain the desired product morphology. Markov chains theory provides a powerful tool for modeling several important processes in electrochemistry and electrochemical engineering, including electrode kinetics, anodic deposit formation and deposit dissolution processes, electrolyzer and electrochemical reactors performance and even reliability of warning devices and repair of failed cells. The way this can be done using the elegant Markov chains theory is described in lucid manner by Professor Thomas Fahidy in a concise chapter which gives to the reader only the absolutely necessary mathematics and is rich in practical examples.

This book is intended for those people who have a knowledge or understanding of rubber materials and processes but who wish to update their knowledge. It should be read in conjunction with Developments in Rubber Technology-l as that volume discussed developments in natural rubber and selected special purpose synthetic rubbers as well as additives. The authors have been selected for their expertise in each particular field and we, as editors, would like to express our appreciation to the individual authors and also to their companies. Such a book would be impossible to produce without such active cooperation as we have received. Volumes 1 and 2 of Developments in Rubber Technology cover rubbers which are processed and vulcanised in the traditional manner. It is appreciated that the omission of non-vulcanised rubber materials (the so called thermoplastic elastomers) will be unwelcome to many readers but it is intended, because of the size of the subject, to cover these materials in a subsequent volume. A.W. K.S.L."

During September 24-26, 2001, the Faculty of Aerospace Engineering of the Delft University of Technology in the Netherlands organised the Glare - the New Material for Aircraft Conference, an international conference on the relationship between design, material choice and application of aircraft materials with respect to new developments in industry. Eminent representatives from the aircraft manufacturing world, including manufacturers, airlines, airports, universities, governments and aviation authorities, were present at this conference to meet and exchange ideas - see the group photo on the next two pages. The fact that the conference was held just two weeks after 'September 11, 2001' put things in a rather unique perspective. The aim of the conference was to illustrate the many unique applications of the Glare family of fibre metal laminates and to provide for the exchange and distribution of information regarding this material in order to stimulate their acceptance and promote further application. The introduction of fibre metal laminates into the commercial aviation market took about 20 years' time. Introducing new technologies should not be taken lightly, however; the aircraft industry is by nature rather conservative and innovations must therefore be proven - a paradox actually - in all possible ways before they can be introduced in real aircraft structures. Not only do technical aspects play a role in this respect; historical, cultural, economical and political issues are equally important.