The purpose of this book is to bridge the gap between the traditional Geomechanics and Numerical Geotechnical Modelling with applications in science and practice. Geomechanics is rarely taught within the rigorous context of Continuum Mechanics and Thermodynamics, while when it comes to Numerical Modelling, commercially available finite elements or finite differences software utilize constitutive relationships within the rigorous framework. As a result, young scientists and engineers have to learn the challenging subject of constitutive modelling from a program manual and often end up with using unrealistic models which violate the Laws of Thermodynamics. The book is introductory, by no means does it claim any completeness and state of the art in such a dynamically developing field as numerical and constitutive modelling of soils. The author gives basic understanding of conventional continuum mechanics approaches to constitutive modelling, which can serve as a foundation for exploring more advanced theories. A considerable effort has been invested here into the clarity and brevity of the presentation. A special feature of this book is in exploring thermomechanical consistency of all presented constitutive models in a simple and systematic manner.

Seven years have elapsed since Dr. Renee Ford, editor-in-chief of Materials Technology, first suggested to me to publish a book on Functionally Graded Materials (FGMs). She said that the FGM concept, then largely unknown outside of Japan and a relatively few laboratories elsewhere, would be of great interest to everyone working in the materials field because of its potentially universal applicability. There was no book about FGMs in English at that time, although the number of research papers, review articles, and FGM conference proceedings had been increasing yearly. We discussed what the book should cover, and decided it should present a comprehensive description from basic theory to the most recent applications of FGMs. This would make it useful both as an introduction to FGMs for those simply curious about what this new materials field was all about, and also as a textbook for researchers, engineers, and graduate students in various material fields. The FGM Forum in Japan generously offered to support this publication program. is very difficult for an individual author to write a book that Because it covers such a wide range of various aspects of many different materials, I invited more than 30 eminent materials scientists throughout the world, who were associated with FGM research, to contribute selected topics. I also asked several leading researchers in this field to edit selected chapters: Dr. Barry H. Rabin, then at the U. S.

At present, there is an increasing interest in the prediction of properties of classical and new materials such as substitutional alloys, their surfaces, and metallic or semiconductor multilayers. A detailed understanding based on a thus of the utmost importance for fu microscopic, parameter-free approach is ture developments in solid state physics and materials science. The interrela tion between electronic and structural properties at surfaces plays a key role for a microscopic understanding of phenomena as diverse as catalysis, corrosion, chemisorption and crystal growth. Remarkable progress has been made in the past 10-15 years in the understand ing of behavior of ideal crystals and their surfaces by relating their properties to the underlying electronic structure as determined from the first principles. Similar studies of complex systems like imperfect surfaces, interfaces, and mul tilayered structures seem to be accessible by now. Conventional band-structure methods, however, are of limited use because they require an excessive number of atoms per elementary cell, and are not able to account fully for e.g. substitu tional disorder and the true semiinfinite geometry of surfaces. Such problems can be solved more appropriately by Green function techniques and multiple scattering formalism.

Solid Freeform Fabrication is a set of manufacturing processes that are capable of producing complex freeform solid objects directly from a computer model of an object without part-specific tooling or knowledge. In essence, these methods are miniature manufacturing plants which come complete with material handling, information processing and materials processing. As such, these methods require technical knowledge from many disciplines; therefore, researchers, engineers, and students in Mechanical, Chemical, Electrical, and Manufacturing Engineering and Materials and Computer Science will all find some interest in this subject. Particular subareas of concern include manufacturing methods, polymer chemistry, computational geometry, control, heat transfer, metallurgy, ceramics, optics, and fluid mechanics. History of technology specialists may also find Chapter 1 of interest. Although this book covers the spectrum of different processes, the emphasis is clearly on the area in which the authors have the most experience, thermal laser processing. In particular, the authors have all been developers and inventors of techniques for the Selective Laser Sintering process and laser gas phase techniques (Selective Area Laser Deposition). This is a research book on the subject of Solid Freeform Fabrication.

Non-destructive testing (NDT) systems can generate incomplete, incorrect or conflicting information about a flaw or a defect. Therefore, the use of more than one NDT system is usually required for accurate defect detection and/or quantification. In addition to a reduction in inspection time, important cost savings could be achieved if a data fusion process is developed to combine signals from multisensor systems for manual and remotely operated inspections. This gathering of data from multiple sources and an efficient processing of information help in decision making, reduce signal uncertainty and increase the overall performance of a non-destructive examination. This book gathers, for the first time, essays from leading NDT experts involved in data fusion. It explores the concept of data fusion by providing a comprehensive review and analysis of the applications of NDT data fusion. This publication concentrates on NDT data fusion for industrial applications and highlights progress and applications in the field of data fusion in areas ranging from materials testing in the aerospace industry to medical applications. Each chapter contains a specific case study with a theoretical part but also presents experimental results from a practical point of view. The book should be considered more as a pragmatic introduction to the applications of NDT data fusion rather than a rigorous basis for theoretical studies.

Sol--Gel--Optics encompasses numerous schemes for fabricating optical materials from gels -- materials such as bulk optics, optical waveguides, doped oxides for laser and nonlinear optics, gradient refractive index (GRIN) optics, chemical sensors, environmental sensors, and `smart' windows. Sol--Gel--Optics: Processing and Applications provides in-depth coverage of the synthesis and fabrication of these materials and discusses the optics related to microporous, amorphous, crystalline and composite materials. The reader will also find in this book detailed descriptions of new developments in silica optics, bulk optics, waveguides and thin films. Various applications to sensor and device technology are highlighted. For researchers and students looking for novel optical materials, processing methods or device ideas, Sol--Gel--Optics: Processing and Applications surveys a wide array of promising new avenues for further investigation and for innovative applications. (This book is the first in a new subseries entitled `Electronic Materials: Science and Technology).

2. High Temperature UHV-STM System 264 3. Hydrogen Desorption Process on Si (111) Surface 264 4. (7x7) - (1 xl) Phase Transition on Si (111) Surface 271 Step Shifting under dc Electric Fields 275 5. 6. Conclusions 280 Acknowledgements and References 281 12. DYNAMIC OBSERVATION OF VORTICES IN SUPERCONDUCTORS USING ELECTRON WAVES 283 by Akira Tonomura 1. Introduction 283 2. Experimental Method 284 2. 1 Interference Microscopy 284 2. 2 Lorentz Microscopy 287 Observation of Superconducting Vortices 288 3. 3. 1 Superconducting Vortices Observed by Interference Microscopy 288 3. 1. 1 Profile Mode 288 3. 1. 2 Transmission Mode 291 3. 2 Superconducting Vortices Observed by Lorentz Microscopy 293 3. 3 Observation of Vortex Interaction with Pinning Centers 294 3. 3. 1 Surface Steps 295 3. 3. 2 Irradiated Point Defects 296 4. Conclusion 298 References 299 13. TEM STUDIES OF SOME STRUCTURALLY FLEXIBLE SOLIDS AND THEIR ASSOCIATED PHASE TRANSFORMATIONS 301 by Ray L. Withers and John G. Thompson 1. Introduction 301 2. Tetrahedrally Comer-Connected Framework Structures 302 3. Tetragonal a-PbO 311 4. Compositionally Flexible Anion-Deficient Fluorites and the "Defect Fluorite" to C-type Sesquioxide Transition 320 5. Summary and Conclusions 327 Acknowledgements and References 327 Author Index 331 Subject Index 333 List of Contributors A. ASEEV Institute of Semiconductor Physics, Russian Academy of Sciences Novosibirsk, 630090, pr. ac. , Lavrentjeva 13, RUSSIA E. BAUER Department of Physics and Astronomy, Arizona State University Tempe, AZ 85287-1504, U. S. A. G. H.

As we approach the end of the present century, the elementary particles of light (photons) are seen to be competing increasingly with the elementary particles of charge (electrons/holes) in the task of transmitting and processing the insatiable amounts of infonnation needed by society. The massive enhancements in electronic signal processing that have taken place since the discovery of the transistor, elegantly demonstrate how we have learned to make use of the strong interactions that exist between assemblages of electrons and holes, disposed in suitably designed geometries, and replicated on an increasingly fine scale. On the other hand, photons interact extremely weakly amongst themselves and all-photonic active circuit elements, where photons control photons, are presently very difficult to realise, particularly in small volumes. Fortunately rapid developments in the design and understanding of semiconductor injection lasers coupled with newly recognized quantum phenomena, that arise when device dimensions become comparable with electronic wavelengths, have clearly demonstrated how efficient and fast the interaction between electrons and photons can be. This latter situation has therefore provided a strong incentive to devise and study monolithic integrated circuits which involve both electrons and photons in their operation. As chapter I notes, it is barely fifteen years ago since the first demonstration of simple optoelectronic integrated circuits were realised using m-V compound semiconductors; these combined either a laser/driver or photodetector/preamplifier combination.

219 8. 2 Sensors 221 8. 3 Physical Sensors 222 8. 3. 1 Electrical Sensing Means 223 8. 3. 2 Magnetic Field Methods 231 8. 3. 3 Optical Methods 232 8. 4 Chemical Sensors 241 8. 4. 1 Electrical Gas and Chemical Sensors 243 8. 4. 2 Guided-Optics Intrinsic Chemical Sensors 246 8. 4. 3 Extrinsic Chemical Sensors 250 8. 4. 4 Polymer Waveguide Chemical Sensors 251 8. 4. 5 Surface Plasmon Chemical Sensors 252 8. 4. 6 Indicator-Mediated Extrinsic Sensing 253 8. 4. 7 Optical Biosensors 256 8. 4. 8 Ultrasonic Gas and Chemical Sensors 257 8. 4. 9 Intelligent Sensors 258 8. 5 Connections/Links and Wiring 258 8. 5. 1 Optical Links 260 8. 5. 2 Requirement on the Processing Unit/Intelligence 262 8. 6 Actuators 263 8. 7 Signal Processing/Computing 264 8. 7. 1 Implicit Computation 266 8. 7. 2 Explicit Computation 267 8. 8 References 274 Subject Index 279 Micro-Actuators (Electrical, Magnetic, Thermal, Optical, Mechanical, and Chemical) It has become quite apparent that sensors and actuators are the main bottleneck of the modem information processing and control systems. Microprocessors and computers used to be the main limiting element in most information processing systems. But thanks to the enonnous progress in the microelectronics industry, most information analysis tasks can be processed in real time. The data has to be acquired by the processor in some form and processed and used to produce some useful function in the real world.

The introduction of GaAs/ AIGaAs double heterostructure lasers has opened the door to a new age in the application of compound semiconductor materials to microwave and optical technologies. A variety and combination of semiconductor materials have been investigated and applied to present commercial uses with these devices operating at wide frequencies and wavelengths. Semiconductor modulators are typical examples of this technical evolutions and hsve been developed for commercial use. Although these have a long history to date, we are not aware of any book that details this evolution. Consequently, we have written a book to provide a comprehensive account of semiconductor modulators with emphasis on historical details and experimantal reports. The objective is to provide an up-to-date understanding of semiconductor modulators. Particular attention has been paid to multiple quantum well (MQW) modulators operating at long wavelengths, taking into account the low losses and dispersion in silica fibers occuring at around 1.3 and 1.55 mm. At the present time, MQW structures have been investigated but these have not been sufficiently developed to provide characteristic features which would be instructive enough for readers. One problem is the almost daily publication of papers on semiconductor modulators. Not only do these papers provide additional data, but they often modify the interpretations of particular concepts. Almost all chapters refer to the large number of published papers that can be consulted for future study.

Heat treatment of metallic alloys constitutes an important step within the production process. The heat treatment process itself is considered as a cycle of heating the workpieces to a predetermined temperature, keeping them at this temperature for the time period required, and cooling them to room temperature in an appropriate way. The process of heating and keeping workpieces at the required temperature is now adays weil mastered and mostly automatized. The process of cooling or quenching which determines actually the resulting properties, is handicapped with many physical and technical uncertainties. Good results can already be obtained predominantly by using empirically based practice. But increased demands on the properties of the pro ducts as weIl as demands on safety and environment conditions of the quenching media require efforts to investigate the details of the quenching process and to transfer the results of the research to practical application. Advances in the knowledge about quenching processes have been achieved by modem applied thermodynamics especially by the heat and mass transfer researches; further the application of computer technology was helpful to new approaches in quenching pro cesses. Special emphases has been given to: - The theory of heat transfer and heat exchange intensification during quenching - Wetting kinematics - Residual stresses after quenching - Determination of the quenching intensity - Prediction of microstructural transformation and hardness distribution after quenching, the latter with some limitations."

This the fourth volume of six from the Annual Conference of the Society for Experimental Mechanics, 2010, brings together 58 chapters on Application of Imaging Techniques to Mechanics of Materials and Structure. It presents findings from experimental and computational investigations involving a range of imaging techniques including Recovery of 3D Stress Intensity Factors From Surface Full-field Measurements, Identification of Cohesive-zone Laws From Crack-tip Deformation Fields, Application of High Speed Digital Image Correlation for Vibration Mode Shape Analysis, Characterization of Aluminum Alloys Using a 3D Full Field Measurement, and Low Strain Rate Measurements on Explosives Using DIC.

Die 2. Auflage dieses Buches ist durch Mitarbeiter des Institutes fur Textiltechnik der RWTH Aachen fachlich durchgesehen, auf den neuesten Stand gebracht, um etwa 1.000 Begriffe erweitert und durch die italienische Sprache erganzt.

1 U.H.F. Bunz: Synthesis and Structure of PAEs.- 2 E. Klemm, T. Pautzsch, L. Blankenburg: Organometallic PAEs.- 3 C.R. Ray, J.S. Moore: Supramolecular Organization of Foldable Phenylene Ethynylene Oligomers.- 4 J. Zheng, T.M. Swager: Poly(arylene ethynylene)s in Chemosensing and Biosensing.- 5 T. Yamamoto, I. Yamaguchi, T. Yasuda: PAEs with Heteroaromatic Rings.- 6 G. Voskerician, C. Weder: Electronic Properties of PAEs.-

Through his voluminous and in?uential writings, editorial activities, organi- tional leadership, intellectual acumen, and strong sense of history, Clifford - brose Truesdell III (1919-2000) was the main architect for the renaissance of - tional continuum mechanics since the middle of the twentieth century. The present collection of 42 essays and research papers pays tribute to this man of mathematics, science, and natural philosophy as well as to his legacy. The ?rst ?ve essays by B. D. Coleman, E. Giusti, W. Noll, J. Serrin, and D. Speiser were texts of addresses given by their authors at the Meeting in memory of Clifford Truesdell, which was held in Pisa in November 2000. In these essays the reader will ?nd personal reminiscences of Clifford Truesdell the man and of some of his activities as scientist, author, editor, historian of exact sciences, and principal founding member of the Society for Natural Philosophy. The bulk of the collection comprises 37 research papers which bear witness to the Truesdellian legacy. These papers cover a wide range of topics; what ties them together is the rational spirit. Clifford Truesdell, in his address upon receipt of a Birkhoff Prize in 1978, put the essence of modern continuum mechanics succinctly as "conceptual analysis, analysis not in the sense of the technical term but in the root meaning: logical criticism, dissection, and creative scrutiny.

Progress in the development of surgical implant materials has been hindered by the lack of basic information on the nature of the tissues, organs and systems being repaired or replaced. Materials' properties of living systems, whose study has been conducted largely under the rubric of tissue mechanics, has tended to be more descriptive than quantitative. In the early days of the modern surgical implant era, this deficiency was not critical. However, as implants continue to improve and both longer service life and higher reliability are sought, the inability to predict the behavior of implanted manufactured materials has revealed the relative lack of knowledge of the materials properties of the supporting or host system, either in health or disease. Such a situation is unacceptable in more conventional engineering practice: the success of new designs for aeronautical and marine applications depends exquisitely upon a detailed, disciplined and quantitative knowledge of service environments, including the properties of materials which will be encountered and interacted with. Thus the knowledge of the myriad physical properties of ocean ice makes possible the design and development of icebreakers without the need for trial and error. In contrast, the development period for a new surgical implant, incorporating new materials, may well exceed a decade and even then only short term performance predictions can be made.

The development of photosensitive materials in general and photoreactive polymers in particular is responsible for major advances in the information, imaging, and electronic industries. Computer parts manufacturing, information storage, and book and magazine publishing all depend on photoreactive polymer systems. The photo-and radiation-induced processes in polymers are also active areas of research. New information on the preparation and properties of com mercially available photosensitive systems is constantly being acquired. The recent demand for environmentally safe solvent-free and water-soluble materials also motivated changes in the composition of photopolymers and photoresists. The interest in holographic recording media for head-up displays, light scanners, and data recording stimulated development of reconfigurable and visible light sensitive materials. Photoconductive polymerizable coatings are being tested in electrostatic proofing and color printing. The list of available initiators, poly meric binders, and other coating ingredients is continually evolving to respond to the requirements of low component loss (low diffusivity) and the high rate of photochemical reactions.

This is a work in four parts, dealing with the mechanics and thermodynamics of materials with memory, including properties of the dynamical equations which describe their evolution in time under varying loads. The first part is an introduction to Continuum Mechanics with sections dealing with classical Fluid Mechanics and Elasticity, linear and non-linear. The second part is devoted to Continuum Thermodynamics, which is used to derive constitutive equations of materials with memory, including viscoelastic solids, fluids, heat conductors and some examples of non-simple materials. In part three, free energies for materials with linear memory constitutive relations are comprehensively explored. The new concept of a minimal state is also introduced. Formulae derived over the last decade for the minimum and related free energies are discussed in depth. Also, a new single integral free energy which is a functional of the minimal state is analyzed in detail. Finally, free energies for examples of non-simple materials are considered. In the final part, existence, uniqueness and stability results are presented for the integrodifferential equations describing the dynamical evolution of viscoelastic materials. A new approach to these topics, based on the use of minimal states rather than histories, is discussed in detail. There are also chapters on the controllability of thermoelastic systems with memory, the Saint-Venant problem for viscoelastic materials and on the theory of inverse problems.

stacked QD structure and is useful for examining the possibility of all optical measurement of stacked QD layers. Optical absorption spectra of self-assembled QDs has been little reported, and further investigation in necessary to study hole-burning memory. 2.5 Summary This chapter describes recent advances in quantum dot fabrication tech nologies, focusing on our self-formed quantum dot technologies including TSR quantum dots and SK-mode self-assembled quantum dots. As is described in this chapter, there are many possible device applications such as quantum dot tunneling memory devices, quantum dot fioating-dot gate FETs, quantum dot lasers, and quantum dot hole-burning memory devices. The quantum dot laser applications seem to be the most practicable among these applications. However, many problems remain to be solved before even this application becomes practical. The most important issue is to of self-assembled quantum dots more pre control the size and position cisely, with an accuracy on an atomic scale. The confinement must be enough to keep the separation energy between quantized energy levels high enough to get high-temperature characteristics. The lasing oscillation frequency should be fixed at 1.3 f.lITl or 1.5 f.lITl for optical communication. Phonon bottleneck problems should be solved by the optimization of device structures. Fortunately, there is much activity in the area of quantum dot lasers and, therefore, many breakthroughs will be made, along with the exploration of other new application areas.

The purpose of Oxide-Based Fiber-Reinforced Ceramic-Matrix Composites is to provide comprehensive information on the most recent successful findings. The book consists of six chapters which characterize the current state of the art concerning oxide-based fiber-reinforced composites. Chapter one provides an introduction, examples of application areas and background information. Chapter two deals with the primary material properties for the areas of application and lists the possible constituent parts of the composites, depending on particular demands. Chapter three explains both the past and present fabrication methods which can affect the performance of the composites. Chapter four defines the interphase-related phenomena and describes the mechanical characteristics of the oxide-based fiber-reinforced composite, produced with different interphases. Chapter five deals with the fabrication route, functionality and mechanical characterization of the porous-matrix composites. The last chapter summarizes the present achievements and identifies requirements for reaching the goal, thereby providing a promising course for future research.

The papers published in these proceedings represent the latest developments in the nondestructive characterization of materials and were presented at the Eleventh International Symposium on Nondestructive Characterization of Materials held in June 2002, in Berlin, Germany.

The photorefractive effect is now firmly established as one of the highest-sensitivity nonlinear optical effects, making it an attractive choice for use in many optical holographic processing applications. As with all technologies based on advanced materials, the rate of progress in the development of photorefractive applications has been principally limited by the rate at which breakthroughs in materials science have supplied better photorefractive materials. The last ten years have seen an upsurge of interest in photorefractive applications because of several advances in the synthesis and growth of new and sensitive materials. This book is a collection of many of the most important recent developments in photorefractive effects and materials. The introductory chapter, which provides the necessary tools for understanding a wide variety of photorefractive phenomena, is followed by seven contributed chapters that offer views of the state-of-the-art in several different material systems. The second chapter represents the most detailed study to date on the growth and photorefractive performance of BaTi03, one of the most important photorefractive ferroelectrlcs. The third chapter describes the process of permanently fixing holographic gratings in ferroelectrics, important for volumetric data storage with ultra-high data densities. The fourth chapter describes the discovery and theory of photorefractive spatial solitons. Photorefractive polymers are an exciting new class of photo refractive materials, described in the fifth chapter. Polymers have many advantages, primarily related to fabrication, that could promise a breakthrough to the marketplace because of ease and low-cost of manufacturing.

When this publisher offered me the opportunity to \\Tite a book, some six years ago, I did not hesitate to say yes. I had just spent the last four years of graduate school struggling to understand the physics of strained quantum well lasers, and it seemed to me the whole experience was much more difficult that it should have been. For although many of the results I needed were easy to locate, the underlying physical premises and intervening steps were not. If only I had a book providing the derivations, I could have absorbed them and gone on my way. Such a book lies before you. It provides a unified and self-contained descrip tion of the essential physics of strained quantum well lasers, starting from first principles whenever feasible. The presentation I have chosen requires only the standard introductory background in quantum mechanics, solid state physics, and electromagnetics expected of entering graduate students in physics or elec trical engineering. A single undergraduate course in each of these subjects should be more than sufficient to follow the text. :'Iore advanced material on quantum mechanics is developed and collected in the first chapter. \Vhen pos sible, I have presented the results in a general setting and have later applied them to specific cases of interest. I find this the most satisfying way to ap proach the subject, and it has the additional benefit of solving many problems once and for all.