Once again, just before Easter, a goodly number of people gathered to hear a series of papers on a variety of aspects of adhesion presented by authors from a number of countries. Overall they all seemed to be as well pleased as ever with what they received. One might have thought that by now-the twenty-eighth year-the whole range of possible topics had been scanned; but no, there are two papers which are concerned with an entirely new one. This arises from the fairly recent recognition that if society is to utilise adhesives and gain anything like their potential advantage, then there is a whole area of dissemination of information and a special sort of education which must be accomplished. To meet this need various initiatives have been undertaken, and two of these are reported within this volume-in addition to papers of the more conventional technological type. As always, I must record my thanks to all those who make possible both these conferences and the books through which the papers are available to a wider audience. The audience, the authors and their secretaries, various people within the University, the publishers and their staff; all are essential parts of the whole. To them, each and everyone, may I express my sincere appreciation and gratitude.

Approach your problems from the right end It isn't that they can't see the solution. It is and begin with the answers. Then one day, that they can't see the problem. perhaps you will find the final question. G. K. Chesterton. The Scandal of Father 'The Hermit Clad in Crane Feathers' in R. Brown The point of a Pin'. van Gulik's The Chinese Maze Murders. Growing specialization and diversification have brought a host of monographs and textbooks on increasingly specialized topics. However, the "tree" of knowledge of mathematics and related fields does not grow only by putting forth new branches. It also happens, quite often in fact, that branches which were thought to be completely disparate are suddenly seen to be related. Further, the kind and level of sophistication of mathematics applied in various sciences has changed drastically in recent years: measure theory is used (non trivially) in regional and theoretical economics; algebraic geometry interacts with physics; the Minkowsky lemma, coding theory and the structure of water meet one another in packing and covering theory; quantum fields, crystal defects and mathematical programming profit from homotopy theory; Lie algebras are relevant to filtering; and prediction and electrical engineering can use Stein spaces. And in addition to this there are such new emerging subdisciplines as "experimental mathematics," "CFD," "completely integrable systems," "chaos, synergetics and large-scale order," which are almost impossible to fit into the existing classification schemes. They draw upon widely different sections of mathematics."

Crystalline or, more properly, semi-crystalline polymers continue to present major challenges and opportunities to scientists and technologists alike. On the one hand, scientific understanding of their structure and properties still lags behind that of other economically important, but less complicated materials. On the other hand, there remains very considerable potential for improving properties in systems designed for specific pur poses. Ways are only just being found of transferring inherent molecular properties (such as high modulus) to the macromolecular solid. Beyond these are many possibilities of manipulating the organization of chemical and physical textures towards desired ends. The chapters in this volume are reports, by wen-known and active researchers, on some of the important recent developments ofthese themes. Grubb begins with the fundamental and central problem of determining polymeric microstructure. Polymers sutTer by comparison with other materials in that it has not generany been possible to exploit the high resolution of the electron microscope to determine their microstructure in adequate detail. However, recently, ways have been found of studying representative lamellar textures in melt-crystallized polymers. When fully exploited these must add greatly to our detailed knowledge and provide a firmer fundamental base for future developments. Radiation damage bears the primary responsibility for restricting electron microscopy. In his chapter, Kener recounts how appreciation of this fact led him into a fascinating study of ever deeper aspects of radiation damage in polyethylene over two decades, often controversiany but invariably clarifying the basic understanding of an area now of increasing commercial importance."

Computer Aided Engineering may be defined as an approach to solving tech nological problems in which most or all of the steps involved are automated through the use of computers, data bases and mathematical models. The success of this ap proach, considering hot forming, is tied very directly to an understanding of material behaviour when subjected to deformation at high temperatures. There is general agreement among engineers that not enough is known about that topic -and this gave the initial impetus for the project described in the present study. The authors secured a research grant from NATO (Special Research Grant #390/83) with a mandate to study the "State-of-the-Art of Controlled Rolling." What follows is the result of that study. There are five chapters in this Monograph. The first one, entitled "State-of-the Art of Controlled Rolling" discusses industrial and laboratory practices and research designed to aid in the development of microalloyed steels of superior quality. Follow ing this is the chapter "Methods of Determining Stress-Strain Curves at Elevated Temperatures." The central concern here is the material's resistance to deformation or in other words, its flow strength, the knowledge of which is absolutely essential for the efficient and economical utilization of the computers controlling the rolling process."

After a short introduction and a brief review of the relation between carbon nanotubes, graphite and other forms of carbon, the synthesis techniques and growth mechanisms for carbon nanotubes are described. This is followed by reviews on nanotube electronic structure, electrical, optical, and mechanical properties, nanotube imaging and spectroscopy, and nanotube applications.

This monograph presents an integrated perspective of the wide range of phenomena and processes applicable to the study of transport of species in porous materials. In order to formulate the entire range of porous media and their uses, this book gives the basics of continuum mechanics, thermodynamics, seepage and consolidation and diffusion, including multiscale homogenization methods. The particular structure of the book has been chosen because it is essential to be aware of the true properties of porous materials particularly in terms of nano, micro and macro mechanisms. This book is of pedagogical and practical importance to the fields covered by civil, environmental, nuclear and petroleum engineering and also in chemical physics and geophysics as it relates to radioactive waste disposal, geotechnical engineering, mining and petroleum engineering and chemical engineering.

The past five years have witnessed some dramatic developments in the general area of ferroelectric thin films materials and devices. Ferroelectrics are not new materials by any stretch ofimagination. Indeed, they have been known since the early partofthis century and popular ferroelectric materials such as Barium Titanate have been in use since the second world war. In the late sixties and seventies, a considerable amountofresearch and development effort was made to create a solid state nonvolatile memory using ferroelectrics in a vary simple matrix-addressed scheme. These attempts failed primarily due to problems associated with either the materials ordue to device architectures. The early eighties saw the advent of new materials processing approaches, such as sol-gel processing, that enabled researchers to fabricate sub-micron thin films of ferroelectric materials on a silicon substrate. These pioneering developments signaled the onsetofa revival in the areaofferroelectric thin films, especially ferroelectric nonvolatile memories. Research and development effort in ferroelectric materials and devices has now hit a feverish pitch, Many university laboratories, national laboratories and advanced R&D laboratories oflarge IC manufacturers are deeply involved in the pursuit of ferroelectric device technologies. Many companies worldwide are investing considerable manpower and resources into ferroelectric technologies. Some have already announced products ranging from embedded memories in micro controllers, low density stand-alone memories, microwave circuit elements, andrf identification tags. There is now considerable optimism that ferroelectric devices andproducts will occupy a significant market-share in the new millennium.

The term rapid prototyping (RP) refers to a generic group of emerging technologies that enable very quick fabrication of engineering components primarily targeted for prototyping applications. With RP, very complex three dimensional parts or prototypes can be fabricated without the need of costly tooling and machining. This inevitably leads to much shorter design cycle time and lower cost of building a prototype. Its manifold benefits include significant productivity gains, cost saving, and shortened development time to introduce concept models. As such, RP technologies have attracted tremendous R&D interests from both academia and industry in the past decade. Many different processes and materials have been commercialized and used in industry primarily for the fabrication of physical prototypes. More recent interests in RP technologies are towards functional applications of the fabricated parts, such as in rapid tooling applications and replacements of damaged components. Many processes and materials have been commercialized but are yet to be able to fulfill the aforementioned functional requirements because of limited mechanical strengths of the fabricated parts.

Worldwide, extrusion lines successfully process more plastics into prod ucts than other processes by consuming at least 36 wt% of all plastics. They continue to find practical solutions for new products and/ or prob lems to meet new product performances. This book, with its practical industry reviews, is a unique handbook (the first of its kind) that covers over a thousand of the potential combina tions of basic variables or problems with solutions that can occur from up-stream to down-stream equipment. Guidelines are provided for maxi mizing processing efficiency and operating at the lowest possible cost. It has been prepared with an awareness that its usefulness will depend greatly upon its simplicity and provision of essential information. It should be useful to: 0) those already extruding and desiring to obtain additional information for their line and/ or prOVide a means of reviewing other lines that can provide their line with operating improvements; (2) those processing or extruding plastics for the first time; (3) those consider ing going into another extrusion process; (4) those desiring additional information about employing the design of various products more effi ciently, with respect to both performance and cost; (5) those contemplat ing entering the business of extrusion; (6) those in new venture groups, materials development, and/ or market development; (7) those in disci plines such as nonplastics manufacturers, engineers, designers, quality control, financial, and management; and (8) those requiring a textbook on extrusion in trade schools and high schools or colleges.

The objectives of this book are twofold: 1. To provide a thorough examination of the materials science of cellulosic fibers with emphasis on the characterization of structure-property relations, and 2. To advance knowledge of how to best analyze cellulosic fibrous networks and composites, and, ultimately, engineer "novel" cellulose-based systems of superior performance and functionality. The design of new materials through the study of living systems, or bio-imitation, is burgeoning to become an established field, generally referred to as biomimetics. The latter, as with materials science, in general, prominently features multi-disciplinarity where new developments in mathematics, physics, chemistry and engineering continue to inspire novel areas of research and development. The book is structured in five chapters which provide a sequential treatment of the running theme: deformation mechanics and the physical, morphological and mechanical characterization of native cellulose fibers networks and composites. The heart of the book is Chapter 3, Damage Accumulation in Fibers, which treats the experimental methodology for fatigue testing of single fibers and the engendered results. In-depth examinations of the morphology, structure and chemical composition of native cellulose fibers, and the mechanics of deformation in these natural composite fibers are proffered in Chapters 1 and 2, respectively. The fourth chapter, Fractal Simulation of Crack Propagation, presents a fractal-based approach to modeling damage accumulation in materials. Fractals lend themselves well to modeling such randomly-oriented phenomena as crack propagation and fracture. The last chapter, Fibrous Structures: Networks and Composites, comprises analytical approaches for handling networks and composites.

I am honored to chair this International Workshop on Functionally st Graded Materials in the 21 Century: A Workshop on Trends and Forecasts, and would like to first express my sincere gratitude to everyone participating. The Mechanical Engineering Laboratory and the Japan International Science and Technology Exchange Center (JISTEC) have co-organized this workshop with the sponsorship of the Science and Technology Agency of Japan and the cooperation of the Association of Mechanical Technology. This workshop is an international conference to focus on functionally graded materials and the aim is to provide an overview of the present global technical trends and the future development of functionally graded materials over the next 10 years. I am very happy to see many researchers meeting together here - including seven researchers invited from abroad. During the three-day oral sessions, 36 research reports will be presented, and I'm sure I'm not the only one who is very anxious to hear and participate in the upcoming interesting discussions. At present, the Mechanical Engineering Laboratory is conducting fundamental and ground-breaking research in such major areas as materials science and technology, bioengineering, information & system science, advanced machine technology, energy technology, manufacturing technology and robotics. In particular, we consider research on materials science and technology to have the highest priority for the 21st century. and since 1996 have participated in the US-Japan joint research project, Precompetitive Processing and Characterization of Functionally Graded Materials.

During the last 25 years (after the growth of the first pseudomorphic GeSi strained layers on Si by Erich Kasper in Germany) we have seen a steady accu- mulation of new materials and devices with enhanced performance made pos- sible by strain. 1989-1999 have been very good years for the strained-Iayer- devices. Several breakthroughs were made in the growth and doping technology of strained layers. New devices were fabricated as a results of these break- throughs. Before the advent of strain layer epitaxy short wavelength (violet to green) and mid-IR (2 to 5 f. Lm) regions of the spectrum were not accessi- ble to the photonic devices. Short wavelength Light Emitting Diodes (LEDs) and Laser Diodes (LDs) have now been developed using III-Nitride and II-VI strained layers. Auger recombination increases rapidly as the bandgap narrows and temperature increases. Therefore it was difficult to develop mid-IR (2 to 5 f. Lm range) lasers. The effect of strain in modifying the band-structure and suppressing the Auger recombination has been most spectacular. It is due to the strain mediated band-structure engineering that mid-IR lasers with good per- formance have been fabricated in several laboratories around the world. Many devices based on strained layers have reached the market place. This book de- scribes recent work on the growth, characterization and properties o(compound semiconductors strained layers and devices fabricated using them.

Designing new structural materials, extending lifetimes and guarding against fracture in service are among the preoccupations of engineers, and to deal with these they need to have command of the mechanics of material behaviour. This ought to reflect in the training of students. In this respect, the first volume of this work deals with elastic, elastoplastic, elastoviscoplastic and viscoelastic behaviours; this second volume continues with fracture mechanics and damage, and with contact mechanics, friction and wear. As in Volume I, the treatment links the active mechanisms on the microscopic scale and the laws of macroscopic behaviour. Chapter I is an introduction to the various damage phenomena. Chapter II gives the essential of fracture mechanics. Chapter III is devoted to brittle fracture, chapter IV to ductile fracture and chapter V to the brittle-ductile transition. Chapter VI is a survey of fatigue damage. Chapter VII is devoted to hydrogen embrittlement and to environment assisted cracking, chapter VIII to creep damage. Chapter IX gives results of contact mechanics and a description of friction and wear mechanisms. Finally, chapter X treats damage in non metallic materials: ceramics, glass, concrete, polymers, wood and composites. The volume includes many explanatory diagrams and illustrations. A third volume will include exercises allowing deeper understanding of the subjects treated in the first two volumes.

The contributions to this volume provide new experiences in hydrocarbon exploration, especially to basin analysis methods and risk assessment by computer modelling. Covering mainly the North Sea and adjacent areas also examples from Paris basin, off-Southern Italy, Pannonian basin, Bulgaria, Turkey, Russian platform and Baltic Sea are presented. New approaches in risk-weighting are performed by Monte Carlo simulations, by application of expert-system technology but also by taking into account the importance of man-made mechanical effects, resulting from stress-sensitivity measurements from log and core data.

This is a collection of interesting articles addressing the interplay between physics and technology in the modern industrial world. The authors, partly coming from universities, partly from research laboratories in big companies, address not only the specialists but also a wide audience including those who shoulder responsibilities in politics and top management.

1. B. Keszler, J.P. Kennedy, Akron, OH, USA Synthesis of High Molecular Weight Poly (Beta-Pinene) 2. Y. Chujo, T. Saegusa, Kyoto, Japan OrganicPolymer Hybrids with Silica Gel by Means of the Sol-Gel Method 3. A. Halperin, Mainz, FRG, M. Tirrell, T.P. Lodge, Minnea- polis, MN, USA Tethered Chains in Polymer Microstructures 4. T.Q. Nguyen, H.-H. Kausch, Lausanne, CH Mechanochemical Degradation in Transient Elongational Flow 5. P. Corradini, G. Guerra, Naples, Italy Polymorphism in Polymers 6. K.A. Armitstead, G. Goldbeck-Wood, A. Keller, Bristol, UK Review of Polymer Crystallization Theories 7. M. Fischer, Fribourg, CH Properties and Failure of Polymers with Tailored Distances between Crosslinks 8. M. Stamm, Mainz, FRG Polymer Interfaces on a Molecular Scale: Comparison of Techniques and Some Examples

During recent years an increasing amount of research has been conducted to develop methods and procedures for improving inter pretation in nondestructive testing. This research covers appro priate testing procedures as well as the algorithms for interpre tation. In several cases a state has been reached which allows for implementation. The objective of the workshop was to bring together researchers and industrial users of both countries and colleagues from other countries for a thorough and critical discussion of how far we have come and where we have to go to solve the basic practical problems of interpretation in nondestructive testing and of data acquisition necessary for this purpose. Dr. Dau from EPRI stated during the last International Confer ence for Nondestructive Testing in Nuclear Industry that from the point of view of time and money spent research is the smallest part of innovation but, I would like to add in full agreement with him, the most essential. Without successful research innovation is not possible at all; but neither research and invention nor any other step in an innovation procedure can be left out. Our philosophy is to keep researchers involved until the end of the innovation. That means until a new or improved NOT-method is approved under industrial environment and implemented in industry. There can be no doubt that the further we proceed on this long road the more industry will have to be involved and assume the initiative, responsibility and the leading role."

This second edition of a well-received volume has been thoroughly updated and expanded to cover the most recent developments. Coverage now includes additional polymers such as polyindole and polyazines, composites of polymers with carbon nanotubes, metals, and metal oxides, as well as bending-beam techniques for characterization. Again, the author provides a systematic survey of the knowledge accumulated in this field in the last thirty years. This includes thermodynamic aspects, the theory of the mechanism of charge transport processes, the chemical and physical properties of these compounds, the techniques of characterization, the chemical and electrochemical methods of synthesis as well as the application of these systems. The book contains a compilation of the polymers prepared so far and covers the relevant literature with almost 2000 references. From reviews of the previous edition 'a comprehensive reference guide for those interested in this field' (Journal of Solid State Electrochemistry)

Emerging Fields in Sol-gel Science and Technology contains selected papers from the symposium on "Sol-Gel and Vitreous Materials and Applications" held during the International Materials Research Congress in Cancun, Mexico in August 2002. One hundred and twenty researchers representing 10 countries attended this symposium. Some of the subjects covered in this symposium include 1.) synthesis of new materials endowed with outstanding and non-conventional optical, magnetic, electrical, thermal, catalytic, and mechanical properties; 2.) study of the sorption properties of model porous materials in order to test the validity of previous and recent theories; 3.) theoretical studies related to density functional theory, fractal and scaling law approaches, 4.) synthesis of biomaterials for use in medicine and pollution control; 5.) application of sol-gel colloids in the fine-chemistry industry in products such as fragrances and pharmaceuticals; 6.) development of special vitreous materials; 7.) implementation of inorganic thin films, and 8.) synthesis of materials for energy saving.

Electro-optic devices based on doped wide-band materials are present in industrial uses, in military applications and in everyday life. Whether one engages in laser surgery with a neodymium-Y AG laser or one communicates overseas using optical fibers, the development of these materials is both scientifically and commercially of great interest. Much of the most innovative work has been done in the last 15 years in this area. A minor revolution in optical fiber communications has occurred with the development of erbium-doped fiber amplifiers. Solid-state laser development shifted into high-gear with the theoretical and experimental study of doubly-doped garnet lasers. Recent developments on semiconductor laser arrays are making diode pumped solid-state lasers commercially feasible. The purpose of this book is to detail these developments and to point out that many of the same underlying physical processes control advances in several diverse applications. For example, the basic science of energy transfer will be discussed by Zharikov et al. and Rotman for energy transfer and dopant-defect interactions, respectively; it will also be crucial in understanding cerium-doped scintilla tors, neodymium-chromium lasers, and up-conversion fiber lasers. As another example, phonon-induced non-radiative relaxation will appear in every chapter in this book.

Synthesis and Properties of Advanced Materials provides an overview of some of the most exciting developments in advanced materials. The book contains review papers based on tutorial lectures given at The First Pan American Advanced Study Institute held in Merida, Mexico, 1995. Each paper serves as a comprehensive introduction and review to the topic covered. Topics included: diamond and related materials, nanocrystalline metals and ceramics, Co-based alloys for biomedical applications, high-temperature superconductivity materials, composite materials, cement-based materials, ion-implanted ceramics and structural ceramics. Each chapter emphasizes the relationships among processing parameters, micro-structure and properties. Synthesis and Properties of Advanced Materials provides an excellent review of the state of the art in advanced materials for the working engineer or researcher. Students will also find this text an accessible introduction to the field.

This book has one single purpose: to present the development of the partial hybrid finite element method for the stress analysis of laminated composite structures. The reason for this presentation is because the authors believe that partial hybrid finite element method is more efficient that the displacement based finite element method for the stress analysis oflaminated composites. In fact, the examples in chapter 5 of this book show that the partial hybrid finite element method is about 5 times more efficient than the displacement based finite element method. Since there is a great need for accurate and efficient calculation of interlaminar stresses for the design using composites, the partial hybrid finite method does provide one possible solution. Hybrid finite method has been in existence since 1964 and a significant amount of work has been done on the topic. However, the authors are not aware of any systematic piece of literature that gives a detailed presentation of the method. Chapters of the displacement finite element method and the evolution 1 and 2 present a sununary of the hybrid finite element method. Hopefully, these two chapters can provide the readers with an appreciation for the difference between the displacement finite element method and the hybrid finite element. It also should prepare the readers for the introduction of partial hybrid finite element method presented in chapter 3.

This volume highlights the latest developments and trends in advanced materials and their properties, the modeling and simulation of non-classical materials and structures, and new technologies for joining materials. It presents the developments of advanced materials and respective tools to characterize and predict the material properties and behavior.