This monograph deals with ion induced electron emission from crystalline solids bombarded by fast ions. During the past decade, electron spectroscopy combined with the ion channeling technique has revealed various "messages" about ion solid and electron solid interactions carried by the emitted elec trons. While the ion induced electrons produced by binary encounter pro cesses are of primary interest in this book, closely related topics such as the emission of ion induced Auger electrons from crystal targets are also reviewed, with emphasis on their interdisciplinary aspects, for example, their relation to photoelectron diffraction. In addition to these topics, the book describes the underlying physics and experimental techniques so that it should provide useful information for students and scientists working in ion beam based re search and development in various areas of atomic and solid state physics, materials science, surface science, etc. I am much indebted to the gererations of students who have passed through my laboratory, since they have stimulated me with elementary but essential questions in various phases of the studies. I am also grateful to T. Azuma, Y. Kido, K. Kimura, H. Naramoto, and S. Seki for critical reading of the manuscript. Tsukuba, August 2001 Hiroshi Kudo Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1o Terminology and Table of Symbols . . . . . . . . . . . . . . . . . . . . . . . 5 2. 2. 1 Notes on Terminology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2. 2 Frequently Used Symbols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 3. Binary Encounter Electron Emission . . . . . . . . . . . . . . . . . . . . . . 7 3. 1 Ion Electron Elastic Collisions . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 3. 2 Recoil Cross Section of Orbital Electrons . . . . . . . . . . . . . . . . . .

This book reviews recent advances in polymer swelling resulting from the use of novel microporous composite films. It offers a new approach to understanding sorption processes in polymer-liquid systems based on the molecular structures of the sorbed molecules and the repeat unit of the sorbent polymer. It is shown how the adsorption parameters obtained in these studies relate meaningfully with the Flory-Huggins interaction parameters. This implies that these adsorption parameters have relevance not only for swelling and drying of polymers, but also for other phenomena in which molecular sorption plays an important role, such as in chromatography and in membrane permeation.

Continued and systematic analysis of the mechanics of flexible fibre assemblies dates from about 1945, although the growth of research into textiles after 1920 had included studies of fabric structure and the measurement of mechanical properties. The subject is thus a young one, although this NATO Advanced Study Institute is a sign of developing maturity. However there is an earlier tradition. Relevant, even if somewhat loosely connected, quotations can be found in the works of the engineers of the ancient civilisations, recurring during the llenaissance with Leonardo da Vinci and Galileo. But the glorious libk is with Euler and the Bernoulli family, with their theories of the mechanics of flexible slender rods. While mathematicians have admired the beauty of this work, the invention of elliptic integrals, and the grace of the different classes of planar elastica, it is in the technology of textile materials, composed of flexible fibres and yarns, that the subject has found its more direct application. All this, and much more such as Max Born's doctoral thesis, was brought to our attention in a delightful discourse by Milos Konopasek, who is not only fascinated by the mathematics of Euler and the modern movement of the solutions of bending curves from two dimensions into three by the use of the computer, but also feels a personal link through having lived and studied within sight of the scene of Euler's triumphs in St. Petersburg.

Some years ago in Paisley (Scotland) the International Conference on Composite Materials, headed by Professor I. Marshall, took place. During the conference, I presented a paper on the manufacturing and properties of the Soviet Union's composite materials. Soviet industry had made great achievements in the manufacturing of composite materials for aerospace and rocket applications. For example, the fraction of composites (predominantly carbon fibre reinforced plastics) in the large passenger aircrafts Tu-204 and 11-86 is 12-15% of the structure weight. The percentage by weight share of composites in military aircraft is greater and the fraction of composites (organic fibre reinforced plastics) used in military helicopters exceeds a half of the total structure weight. The nose parts of most rockets are produced in carbon-carbon materials. In the Soviet spacecraft 'Buran' many fuselage tubes are made of boron-aluminium composites. Carbon-aluminium is used for space mirrors and gas turbine blades. These are just a few examples of applications. Many participants at the Paisley conference suggested that the substantial Soviet experience in the field of composite materials should be distilled and presented in the form of a comprehensive reference publication. So the idea of the preparation and publication of a six volume work Soviet Advanced Composites Technology, edited by Academician J. Fridlyander and Professor I. Marshall, was born.

In many cases rheological measurements are carried out in the simplest of geometries, but the interpretation involved in obtaining the rheological parameters of the test fluids from these measurements is surprisingly complex. The purpose of this book is to emphasise the points on which most workers in the field agree, and to let the authors deal with the contentious points according to their own beliefs and experience. This work represents a summary of the current thought on rheological meas urement by experts in the various techniques. When making measurements and obtaining from them parameters that describe the flow behaviour of the test fluids, it is essential that the experimentalist understands the underlying theory and shortcomings of the measurement technique, that he is aware of the likely microstructure of the fluid, and that from this he can appreciate how the fluid and the measuring system will interact with each other. It is this interaction that gives both the required rheological parameters of the fluids and the artefacts that confuse the issue. This book covers the main rheological measurement techniques from capillary, slit and stretching flows to rotational and oscillatory rheometry in various geometries including sliding plate measurements. These topics are backed up by chapters on more practical aspects, such as commercial instruments, and on computer control and data acquisition. The chapters deal with the basic methods, how the measurements are taken, and what assumptions and interpretations are made to obtain valid data on the test fluids."

After epoxy resins and polyimides, cyanate esters arguably form the most well-developed group of high-temperature, thermosetting polymers. They possess a number of desirable performance characteristics which make them of increasing technological importance, where their somewhat higher costs are acceptable. The principal end uses for cyanate esters are as matrix resins for printed wiring board laminates and structural composites. For the electronics markets, the low dielectric loss characteristics, dimen sional stability at molten solder temperatures and excellent adhesion to conductor metals at temperatures up to 250 DegreesC, are desirable. In their use in aerospace composites, unmodified cyanate esters offer twice the frac ture toughness of multifunctional epoxies, while achieving a service tem perature intermediate between epoxy and bis-maleimide capabilities. Applications in radome construction and aircraft with reduced radar signatures utilize the unusually low capacitance properties of cyanate esters and associated low dissipation factors. While a number of commercial cyanate ester monomers and prepoly mers are now available, to date there has been no comprehensive review of the chemistry and recent technological applications of this versatile family of resins. The aims of the present text are to present these in a com pact, readable form. The work is primarily aimed at materials scientists and polymer technologists involved in research and development in the chemical, electronics, aerospace and adhesives industries. It is hoped that advanced undergraduates and postgraduates in polymer chemistry and technology, and materials science/technology will find it a useful introduc tion and source of reference in the course of their studies.

The IUTAM Symposium on Mechanical and Electromagnetic Waves in Structured Media took place at the University of Sydney from January 18- 22, 1999. It brought together leading researchers from eleven countries for a week-long meeting, with the aim of providing cross-links between the com- nities studying related problems involving elastic and electromagnetic waves in structured materials. After the meeting, participants were invited to submit articles based on their presentations, which were refereed and assembled to constitute these Proceedings. The topics covered here represent areas at the forefront of research intoelastic and electromagnetic waves. They include effect of nonlinearity, diffusion and multiple scattering on waves, as well as asymptotic and numerical techniques. Composite materials are discussed in depth, with example systems ranging fromdusty plasmas to a magneto-elastic microstructured system. Also included are studies of homogenisation, that field which seeks to determine equivalent homogeneous systems which can give equivalent wave properties to structured materials, and inverse problems, in which waves are used as a probe to infer structural details concerning scattering systems. There are also strong groups of papers on the localization of waves by random systems, and photonic and phononic band gap materials. These are being developed by analogue with semiconductors for electrons, and hold out the promise of enabling designers to control the propagation of waves through materials in novel ways. We would like to thank the other members of the Scientific Committee (A.

The broad field of conformational motion disorder in crystals is described with particular attention to the separation from the well known mesophases of liquid crystals and plastic crystals. Structure, thermodynamics and motion of a larger number of small and large molecules are discussed. Of special interest are the borderlines between smectic and high viscosity liquid crystals and condis crystals and between plastic crystals and condis crystals as complicated by pseudorotation, jumping between symmetry-related states and hindered rotation. This paper illustrates the wide distribution of conformational disorder in nature. Condis crystals and glasses ("Con"formational "Dis"order) can be found in small and large molecule systems made of organic, inorganic and biological compounds. The condis state was newly discovered only four years ago. In this article over 100 examples are discussed as example of the condis state. In many cases the condis state was suggested for the first time. Motion in the Condensed State, Condis Crystals and their Relation to Plastic Crystals, Condis Crystals of Flexible Macromolecules, Condis Crystals and their Relation to Liquid Crystals, Condis Crystals of Stiff Macromolecules.

At the time when increasing numbers of chemists are being attracted by the fascination of supposedly easy computing and associated colourful imaging, this book appears as a counterpoint. The first part focuses on fundamental concepts of quantum chemistry, covering MCSCF theory, perturbation treatments, basis set developments, density matrices, wave function instabilities to correlation effects, and momentum space theory. The second part is devoted to more practical studies, ranging from the characterisation of exotic interstellar molecules, the accurate determination of spectroscopic constants, excited states structures and EPR parameters through photochemical and charge-transfer processes, cluster chemistry and fullerenes, muonium chemistry, to the possible prediction of the response of materials to electric fields in view of nonlinear optical applications. Audience: Graduate students and researchers whose work involves quantum chemistry, molecular physics, and materials modelling.

The modeling of minerals and silicated materials is a. difficult challenge faced by Solid StatePhysics, Quantum Chemistry and Molecular Dynamics communities. The difficulty of such a modeling is due to the wide diversity of elements, including heavy atoms, and types of bonding involved in such systems. Moreover, one has to consider infinite systems: either perfect cr- tals or glasses and melts. In the solid state a given chemical composition gives rise to numerous polymorphs, geometricallycloselyrelated. These polymorphs have very similar energies and related thermodynamical pr- erties which explain the complexity of their phase diagrams. The modeling of silicates and minerals covers a wide field of applications ranging from basic research to technology, from Solid State Physics to Earth and Planetary science. The use of modeling techniques yields information of different nature. In the case of chemical studies, we can mention inv- tigations on catalytic processes occurring on surfaces and in zeolite cages. These calculations find possible applications in chemical engineering, in particular in the oil industry

This volume includes 58 contributions to the 11th International Conference on Surface and Colloid Science, a highly successful conference sponsored by the International Association of Colloid and Interface Scientists and held in Iguassu Falls, Brazil, in September 2003. Topics covered are the following: Biocolloids and Biological Applications, Charged Particles and Interfaces, Colloid Stability, Colloidal Dispersions, Environmental Colloidal Science, Interfaces and Adsorption, Nanostructures and Nanotechnology, Self-Assembly and Structured Fluids, Surfactants and Polymers, Technology and Applications, Colloids and Surfaces in Oil Production. Surface and colloid science has acquired great momentum during the past twenty years and this volume is a good display of new results and new directions in this important area.

This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields have resulted in a considerable increase in our understanding of the behavior of polymers at interfaces. Inevitably these advances have generated a wealth of literature and although there have been numerous reviews, a critical treatment with adequate descriptions of both theory and experiment, including detailed analysis of the two, has been missing. This text hopes to fill this gap, providing a timely and comprehensive account of the field as it stands today. This long needed work will be invaluable to experts as well as newcomers in the broad field of polymers, interfaces and colloids, both in industry and academia. Whilst industrial laboratories involved in this field will find it indispensable, it will be equally important to anyone with an interest in interfacial polymer or colloidal research.

In recent years, a growing number of engineering applications of light weight and energy efficient plastics can be found in high quality parts vital to the func tioning of entire equipments and structures. Improved mechanical properties, especially balance of stiffness and toughness, are among the most frequently desired features of the new materials. In addition, reduced flammability is con sidered the single most important requirement for further expansion of plastics into large volume and demanding markets such as construction and mass trans port. Production of power cables also requires flame retardant cable jacketing plastics to replace or at least to reduce consumption of environmentally unsound PVC. The two principal ways to achieve the goals mentioned above include the development of completely new thermoplastic polymers and various modifica tions of the existing ones. Development and commercialization of a new ther moplastic require mobilization of large human and financial resources, the lat ter being within the range from $100 million to $10 billion, in comparison to $100 thousand to $10 million needed to develop and commercialize polymeric mate rial with prescribed end use properties using physical or chemical modification of an existing plastic. In addition, the various markets utilizing thermoplastics demand large flexibility in material properties with only moderate volumes, at the best.

This book deals with the application of grazing angle x-ray and neutron scattering to the study of surface-induced critical phenomena. With the advent of even more advanced synchrotron radiation sources and new sophisticated instrumentation this novel technique is expected to experience a boom. The comprehensive and detailed presentation of theoretical and experimental aspects of the scattering of evanascent x-ray and neutron waves inside a solid makes this book particularly useful for tutorial courses. Particular emphasis is put on the use of this technique to extract microscopic information (correlation functions) from the real structure of a surface, from buried and magnetic interfaces and from surface roughness.

The IUTAM Symposium on Rheology of Bodies with Defects was held in Beijing in September, 1997. It was aimed at the development of Rheology in Solid Mechanics. Rheology is classified in Applied Mechanics Review under fluid mechanics, however, in its broadest content as was envisaged in its earlier days, it covers the whole spectrum of material behavior from elasticity, plasticity, and fluid mechanics to gas dynamics. It was thought of as a branch of continuum mechanics, but emphasized the physical aspects of different materials, and frequently proceeded from basic physical principles. As the temperature rises, the distinction between solid and fluid, and the distinction between their micro-mechanical movements, become blurred. The physical description of such materials and their movements must be based on the thermodynamic principles of state variable theory; the classical division between solid and fluid mechanics disappears. Under the classification adopted by Applied Mechanics Reviews, the subjects dealt with in this symposium come closer to viscoelasticity and viscoplasticity, especially close to the subdivision of creep dealing with creep rupture. The symposium focused at building a bridge between macroscopic and microscopic research on damage and fracture behavior of defective bodies made of metal, polymer, composite and other viscoelastic materials. Two different approaches are presented at the symposium. The first is a continuum damage theory for time-dependent evolution of defects at the macro/meso/microscopic levels.

A recent major development in high technology, and one which bears considerable industrial potential, is the advent of low-dimensional semiconductor quantum structures. The research and development activity in this field is moving fast and it is thus important to afford scientists and engineers the opportunity to get updated by the best experts in the field. The present book draws together the latest developments in the fabrication technology of quantum structures, as well as a competent and extensive review of their fundamental properties and some remarkable applications. The book is based on a set of lectures that introduce different aspects of the basic knowledge available, it has a tutorial content and could be used as a textbook. Each aspect is reviewed, from elementary concepts up to the latest developments. Audience: Undergraduates and graduates in electrical engineering and physics schools. Also for active scientists and engineers, updating their knowledge and understanding of the frontiers of the technology.

This volume of the series gives an overview on Rigid Polymer Networks written by two reputed experts in the field. A broad range of densely-branched, highly-crosslinked aromatic networks and gels of increasing rigidity are discussed, with special emphasis on aromatic rigid liquid-crystal polymer networks. The synthetic procedures to create the networks are briefly described and extensively referenced. Features of one-step and two-step rigid networks in their pre-gel and post-gel states are discussed. Some first steps are then taken in the theoretical treatment of LCP networks with long aromatic segments of decreasing stiffness. The current state of theory dealing with the broader class of highly-crosslinked rigid aromatic networks and gels is finally mentioned.

A comprehensive presentation of the complete spectrum of methods for CVD-diamond deposition and an overview of the most important applications.

Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite H were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

This second edition of a well-received volume has been thoroughly updated and expanded to cover the most recent developments. Coverage now includes additional polymers such as polyindole and polyazines, composites of polymers with carbon nanotubes, metals, and metal oxides, as well as bending-beam techniques for characterization. Again, the author provides a systematic survey of the knowledge accumulated in this field in the last thirty years. This includes thermodynamic aspects, the theory of the mechanism of charge transport processes, the chemical and physical properties of these compounds, the techniques of characterization, the chemical and electrochemical methods of synthesis as well as the application of these systems. The book contains a compilation of the polymers prepared so far and covers the relevant literature with almost 2000 references. From reviews of the previous edition 'a comprehensive reference guide for those interested in this field' (Journal of Solid State Electrochemistry)

This book had its nucleus in some lectures given by one ofus (J. O'M. B. ) in a course on electrochemistry to students of energy conversion at the Vniversity of Pennsylvania. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all ofwhom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry wh ich could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importanee. Thus, conversion to electrochemically powered trans portation systems appears to be an important step by means of which the difficulties of air pollution and the effeets of an increasing concentration in the atmosphere of carbon dioxide may be met. Corrosion is recognized as having an electroehemical basis. The synthesis of nylon now contains an important electroehemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of Ameriean organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the Vnited States."

The state of development of composite materials is quite unique in the scientific world with simultaneous advances being made both in their usage and basic understanding. The complexity and high technology required in manufacturing structural parts with these materials as well as the need for fundamental description of their processing and property characteristics necessitates a close col laboration between industrial and academic researchers. This col laboration has become significant not only in solving specific tech nical problems, but in providing a much needed supply of scientists with training and background focused on anticipated demand for further advances in composite usage. The fact that the transportation industry with its current international character has a vital interest in composite materials for weight savings applications has provided a strong incentive for extending these developments beyond national boundaries. An excel lent example of an established international venture is the building of the new generation commercial aircraft by the Boeing Company with composite parts manufactured by Aerita1ia in Italy. Accordingly, we organized a Joint U. S. -Italy Symposium on Composite Materials in Italy which was successfully held on June 15-19, 1981, under the primary sponsorship of NSF in the U. S. A. and CNR in Italy. The strong support we also received from industrial co-sponsors, both from Italy and the U. S. A., as well as our respective academic insti tutions gave us confidence that we were addressing a timely and important area in Science and Engineering with a unique concept."