This book is devoted to various aspects of self-assembly of gold nanoparticles at liquid-liquid interfaces and investigation of their properties. It covers primarily two large fields: (i) self-assembly of nanoparticles and optical properties of these assemblies; and (ii) the role of nanoparticles in redox electrocatalysis at liquid-liquid interfaces. The first part aroused from a long-lasting idea to manipulate adsorption of nanoparticles at liquid-liquid with an external electric field to form 'smart' mirrors and/or filters. Therefore, Chapters 3 to 5 are dedicated to explore fundamental aspects of charged nanoparticles self-assembly and to investigate optical properties (extinction and reflectance) in a through manner. Novel tetrathiafulvalene (TTF)-assisted method leads to self-assembly of nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs) with remarkable optical properties. The second part (Chapters 6 to 8) clarifies the role of nanoparticles in interfacial electron transfer reactions. They demonstrate how nanoparticles are charged and discharged upon equilibration of Fermi levels with redox couples in solution and how it can be used to perform HER and ORR. Finally, Chapter 9 gives a perspective outlook, including applications of suggested methods in fast, one-step preparation of colloidosomes, SERS substrates as well as pioneer studies on so-called Marangony-type shutters drive by the electric field.

This book illustrates the practical workings of environmental transmission electron microscopy (ETEM) from history and instrument design through to solving practical problems. Aspects of instrument design, performance, and operating procedures are covered, together with common problems and pitfalls of the technique. Not only will a properly operated instrument and a carefully set up experiment provide new insight into your specimen, but the ability to observe the specimen in its natural habitat will be essential to meeting specific design criteria for the development of the next generation of materials. Over the past five decades, transmission electron microscopy (TEM) under environmental conditions relevant to a particular sample has been of increasing interest. Symposia dealing with the topic are now among the best attended at international microscopy conferences. Since typical operating modes for the ETEM require the sample be subjected to a harsh environment consisting of corrosive gases and high temperatures, the challenges of adapting and operating the instrument for observation under dynamic operating conditions are numerous. However, careful consideration of the interaction of the electrons with the gases and sample, as well as the gases with the microscope components, can lead to highly rewarding results. In Controlled Atmosphere Transmission Electron Microscopy, leading experts help you to perform successful experiments using the ETEM, and to interpret and understand the results.

This book provides a unique review of various aspects of metallic contamination in Si and Ge-based semiconductors. It discusses all of the important metals including their origin during crystal and/or device manufacturing, their fundamental properties, their characterization techniques and their impact on electrical devices' performance. Several control and possible gettering approaches are addressed. The book offers a valuable reference guide for all researchers and engineers studying advanced and state-of-the-art micro- and nano-electronic semiconductor devices and circuits. Adopting an interdisciplinary approach, it combines perspectives from e.g. material science, defect engineering, device processing, defect and device characterization, and device physics and engineering.

This book is the 2nd special volume dedicated to the memory of Gerard Maugin. Over 30 leading scientists present their contribution to reflect the vast field of scientific activity of Gerard Maugin. The topics of contributions employing often non-standard methods (generalized model) in this volume show the wide range of subjects that were covered by this exceptional scientific leader. The topics range from micromechanical basics to engineering applications, focusing on new models and applications of well-known models to new problems. They include micro-macro aspects, computational efforts, possibilities to identify the constitutive equations, and old problems with incorrect or non-satisfying solutions based on the classical continua assumptions.

This book covers the basic principles and application of nanoindentation technology to determine residual stresses in films and coatings. It briefly introduces various detection technologies for measuring residual stresses, while mainly focusing on nanoindentation. Subsequently, nanoindentation is used to determine residual stresses in different types of films and coatings, and to describe them in detail. This book is intended for specialists, engineers and graduate students in mechanical design, manufacturing, maintenance and remanufacturing, and as a guide to the practice of production with social and economic benefits.

This book presents physical units and widely used physical formulas, which are given together with conversion factors in various units. It includes frequently used atomic spectra and data for atoms, ions and molecules, as well as potential curves for diatomic molecules, and provides numerical parameters for transport phenomena in gases and plasmas. Further, the rate constants of a number of processes in atmospheric ionized air have been added to this second edition of the book. The numerical data has been selected from the information on atoms, atomic systems, atomic processes and models for atomic physics in this area, and the numerical parameters of atoms, ions and atom systems are included in periodical tables of elements.

This book focuses on charged-particle optics and microscopy, as well as their applications in the materials sciences. Presenting a range of cutting-edge theoretical and methodological advances in electron microscopy and microanalysis, and examining their crucial roles in modern materials research, it offers a unique resource for all researchers who work in ultramicroscopy and/or materials research. The book addresses the growing opportunities in this field and introduces readers to the state of the art in charged-particle microscopy techniques. It showcases recent advances in scanning electron microscopy, transmission electron microscopy and helium ion microscopy, including advanced spectroscopy, spherical-corrected microscopy, focused-ion imaging and in-situ microscopy. Covering these and other essential topics, the book is intended to facilitate the development of microscopy techniques, inspire young researchers, and make a valuable contribution to the field.

Premature cracking in asphalt pavements and overlays continues to shorten pavement lifecycles and creates significant economic and environmental burden. In response, RILEM Technical Committee TC 241-MCD on Mechanisms of Cracking and Debonding in Asphalt and Composite Pavements has conducted a State-of-the-Art Review (STAR), as detailed in this comprehensive book. Cutting-edge research performed by RILEM members and their international partners is presented, along with summaries of open research questions and recommendations for future research. This book is organized according to the theme areas of TC 241-MCD - i.e., fracture in the asphalt bulk material, interface debonding behaviour, and advanced measurement systems. This STAR is expected to serve as a long term reference for researchers and practitioners, as it contributes to a deeper fundamental understanding of the mechanisms behind cracking and debonding in asphalt concrete and composite pavement systems.

In this book, the author describes the development of the experimental diffraction setup and structural analysis of non-crystalline particles from material science and biology. Recent advances in X-ray free electron laser (XFEL)-coherent X-ray diffraction imaging (CXDI) experiments allow for the structural analysis of non-crystalline particles to a resolution of 7 nm, and to a resolution of 20 nm for biological materials. Now XFEL-CXDI marks the dawn of a new era in structural analys of non-crystalline particles with dimensions larger than 100 nm, which was quite impossible in the 20th century. To conduct CXDI experiments in both synchrotron and XFEL facilities, the author has developed apparatuses, named KOTOBUKI-1 and TAKASAGO-6 for cryogenic diffraction experiments on frozen-hydrated non-crystalline particles at around 66 K. At the synchrotron facility, cryogenic diffraction experiments dramatically reduce radiation damage of specimen particles and allow tomography CXDI experiments. In addition, in XFEL experiments, non-crystalline particles scattered on thin support membranes and flash-cooled can be used to efficiently increase the rate of XFEL pulses. The rate, which depends on the number density of scattered particles and the size of X-ray beams, is currently 20-90%, probably the world record in XFEL-CXDI experiments. The experiment setups and results are introduced in this book. The author has also developed software suitable for efficiently processing of diffraction patterns and retrieving electron density maps of specimen particles based on the diffraction theory used in CXDI.

This new edition provides a state-of-the-art survey of ellipsometric methods used to study organic films and surfaces, from laboratory to synchrotron applications, with a special focus on in-situ use in processing environments and at solid-liquid interfaces. Thanks to the development of functional organic, meta- and hybrid materials for new optical, electronic, sensing and biotechnological devices, the ellipsometric analysis of optical and material properties has made tremendous strides over the past few years. The second edition has been updated to reflect the latest advances in ellipsometric methods. The new content focuses on the study of anisotropic materials, conjugated polymers, polarons, self-assembled monolayers, industrial membranes, adsorption of proteins, enzymes and RGD-peptides, as well as the correlation of ellipsometric spectra to structure and molecular interactions.

This thesis provides an innovative strategy for rail crack monitoring using the acoustic emission (AE) technique. The field study presented is a significant improvement on laboratory studies in the literature in terms of complex rail profile and crack conditions as well as high operational noise. AE waves induced by crack propagation, crack closure, wheel-rail impact and operational noise were obtained through a series of laboratory and field tests, and analyzed by wavelet transform (WT) and synchrosqueezed wavelet transform (SWT). A wavelet power-based index and the enhanced SWT scalogram were sequentially proposed to classify AE waves induced by different mechanisms according to their energy distributions in the time-frequency domain. A novel crack sizing method taking advantage of crack closure-induced AE waves was developed based on fatigue tests in the laboratory. The propagation characteristics of AE waves in the rail were investigated, and Tsallis synchrosqueezed wavelet entropy (TSWE) with time was finally brought forward to detect and locate rail cracks in the field. The proposed strategy for detection, location and sizing of rail cracks helps to ensure the safe and smooth operation of the railway system. This thesis is of interest to graduate students, researchers and practitioners in the area of structural health monitoring.

This book presents a collection of chapters on various aspects of futuristic composite materials, from manufacturing challenges to materials characterization. The book covers the scientific basis of processing and synthesizing futuristic composites, including the prerequisite theoretical background and latest fabrication techniques. The book also discusses industrial applications of composites, such as in aerospace, automotive, and sports equipment. This book will serve as a valuable guide for researchers and professionals working in the area of futuristic lightweight materials.

This book describes the development of three dimensional electroactive fibres using a novel coaxial wet-spinning approach from organic conductors in combination with non-conducting hydrogel polymers. This book also presents the characterization and evaluation of multiaxial biofibres in terms of mechanical, physical, electrochemical and biological properties, and explores their use in a diverse range of applications including implantable electrodes, drug delivery systems and energy-storage systems. In the first chapter, the author highlights the significance of engineering three dimensional fibres, introduces the involved hydrogels and organic conductors with emphasis on their biomedical application, and collects some of the previously established methods for fabrication of biofibres. In the second chapter, particular attention is given to the overall experimental fabrication methods and characterization analyses conducted in the work. Chapters three to five present the main findings of this work, in which readers will discover how novel hybrid hydrogel fibres with an inner core of chitosan and alginate were prepared and characterized, how graphene was incorporated into coaxial wet-spun biofibres, and how one-dimensional triaxial fibres were developed using a novel coaxial wet-spinning fibre production method and applied as potential battery devices. In the final chapter of this work, the author summarizes the main achievements of the work and outlines some recommendations for future research.

The Laser world consists basically of two areas, which are necessary and in many cases also sufficient for effective innovation: The right laser for the right application. For the individual application that means the determination of optimized process parameters in terms of laser power, peak power/ intensity, focus geometry and dimension, pulse length, pulse repetition rate and wavelength to name only the six most important ones. Once these parameters are identified, the corresponding Laser has to be selected on the basis of commercial availability. Obviously there is no such thing than "One Laser for all". The situation is rather comparable with electrical power, were depending on the demand of the application in terms of voltage, current and time corresponding power supplies need to be tailored, however, with the difference that in the case of the Laser the variety of parameters is even higher, thus the technology is more complex but on the other hand much more flexible in terms optimizing the source to the application. As a consequence it is suggested to generate two volumes on Lasers and Applications named "Tailored Light".

This book reports on the development and application of a new uniaxial pressure apparatus that is currently generating considerable interest in the field of materials physics. The author provides practical guidelines for performing such experiments, backed up by finite element simulations. Subsequently, the book reports on two uses of the device. In the first, high pressures are used to tune to a Van Hove singularity in Sr2RuO4, while the effects on the unconventional superconductivity and the normal state properties are investigated. In the second experiment, precise and continuous strain control is used to probe symmetry breaking and novel phase formation in the vicinity of a quantum critical point in Sr3Ru2O7.

This book brings out the innovations in textile wet or chemical processing to alleviate the environmental impacts arising from this sector. The major challenge in the textiles and fashion sector is that it requires a massive sustainable innovation to mitigate the huge environmental impacts arising from chemical or wet processing. This book also discusses innovations in eco-friendly methods for textile wet processes and applications of enzymes in textiles.

This book highlights the innovations in textile fibres, that is the starting point of the supply chain. There are numerous innovations made in terms of making the existing fibres sustainable and also to discover new sustainable fibres. This book deals with those innovative sustainable textile fibres in detail. It also presents an overview of various current textile fibres, their issues associated with sustainability and how new, sustainable fibres overcome those issues. Finally it discusses the challenges and implications of these sustainable fibres on technical and economic fronts.

This book is intended as an introductory lecture in material physics, in which the modern computational group theory and the electronic structure calculation are in collaboration. The first part explains how to use computer algebra for applications in solid-state simulation, based on the GAP computer algebra package. Computer algebra enables us to easily obtain various group theoretical properties, such as the representations, character tables, and subgroups. Furthermore it offers a new perspective on material design, which could be executed in a mathematically rigorous and systematic way. The second part then analyzes the relation between the structural symmetry and the electronic structure in C60 (as an example of a system without periodicity). The principal object of the study was to illustrate the hierarchical change in the quantum-physical properties of the molecule, which correlates to the reduction in the symmetry (as it descends down in the ladder of subgroups). The book also presents the computation of the vibrational modes of the C60 by means of the computer algebra. In order to serve the common interests of researchers, the details of the computations (the required initial data and the small programs developed for the purpose) are explained in as much detail as possible.

This book is an up-to-date survey of the major optical characterization techniques for thin solid films. Emphasis is placed on practicability of the various approaches. Relevant fundamentals are briefly reviewed before demonstrating the application of these techniques to practically relevant research and development topics. The book is written by international top experts, all of whom are involved in industrial research and development projects.

This book focuses on the widely used experimental techniques available for the structural, morphological, and spectroscopic characterization of materials. Recent developments in a wide range of experimental techniques and their application to the quantification of materials properties are an essential side of this book. Moreover, it provides concise but thorough coverage of the practical and theoretical aspects of the analytical techniques used to characterize a wide variety of functional nanomaterials. The book provides an overview of widely used characterization techniques for a broad audience: from beginners and graduate students, to advanced specialists in both academia and industry.

This volume constitutes the state-of-the-art in active interrogation, widely recognized as indispensable methods for addressing current and future nuclear security needs. Written by a leading group of science and technology experts, this comprehensive reference presents technologies and systems in the context of the fundamental physics challenges and practical requirements. It compares the features, limitations, technologies, and impact of passive and active measurement techniques; describes radiation sources for active interrogation including electron and ion accelerators, intense lasers, and radioisotope-based sources; and it describes radiation detectors used for active interrogation. Entire chapters are devoted to data acquisition and processing systems, modeling and simulation, data interpretation and algorithms, and a survey of working active measurement systems. Active Interrogation in Nuclear Security is structured to appeal to a range of audiences, including graduate students, active researchers in the field, and policy analysts. The first book devoted entirely to active interrogation Presents a focused review of the relevant physics Surveys available technology Analyzes scientific and technology trends Provides historical and policy context Igor Jovanovic is a Professor of Nuclear Engineering and Radiological Sciences at the University of Michigan and has previously also taught at Penn State University and Purdue University. He received his Ph.D. from University of California, Berkeley and worked as physicist at Lawrence Livermore National Laboratory. Dr. Jovanovic has made numerous contributions to the science and technology of radiation detection, as well as the radiation sources for use in active interrogation in nuclear security. He has taught numerous undergraduate and graduate courses in areas that include radiation detection, nuclear physics, and nuclear security. At University of Michigan Dr. Jovanovic is the director of Neutron Science Laboratory and is also associated with the Center for Ultrafast Optical Science. Anna Erickson is an Assistant Professor in the Nuclear and Radiological Engineering Program of the G.W. Woodruff School of Mechanical Engineering at Georgia Institute of Technology. Previously, she was a postdoctoral researcher in the Advanced Detectors Group at Lawrence Livermore National Laboratory. Dr. Erickson received her PhD from Massachusetts Institute of Technology with a focus on radiation detection for active interrogation applications. Her research interests focus on nuclear non-proliferation including antineutrino analysis and non-traditional detector design and characterization. She teaches courses in advanced experimental detection for reactor and nuclear nonproliferation applications, radiation dosimetry and fast reactor analysis.

This book explores the application of external physical fields to the solidification processing of metallic alloys. Leading academics from around the world present comprehensive and critical reviews on state-of-the-art research and discuss possible future directions. Major physical fields, including electromagnetic, electric, acoustic, and thermal, are considered. In addition, the most advanced synchrotron X-ray based real-time and in-situ studies and numerical modeling methodologies are reviewed and discussed, with a special emphasis on their applications to the solidification processes. Throughout, all chapters are illustrated with both historical and very recent research cases, including typical examples of in-situ studies, modeling, and simulation. This book contains essential knowledge and information suitable for a wide audience, from undergraduate and postgraduate students to academics, practicing researchers, and engineers in materials, metallurgy, and manufacturing.

This book is an homage to the pioneering works of E. Aero and G. Maugin in the area of analytical description of generalized continua. It presents a collection of contributions on micropolar, micromorphic and strain gradient media, media with internal variables, metamaterials, beam lattices, liquid crystals, and others. The main focus is on wave propagation, stability problems, homogenization, and relations between discrete and continuous models.

This book addresses the current status, challenges and future directions of data-driven materials discovery and design. It presents the analysis and learning from data as a key theme in many science and cyber related applications. The challenging open questions as well as future directions in the application of data science to materials problems are sketched. Computational and experimental facilities today generate vast amounts of data at an unprecedented rate. The book gives guidance to discover new knowledge that enables materials innovation to address grand challenges in energy, environment and security, the clearer link needed between the data from these facilities and the theory and underlying science. The role of inference and optimization methods in distilling the data and constraining predictions using insights and results from theory is key to achieving the desired goals of real time analysis and feedback. Thus, the importance of this book lies in emphasizing that the full value of knowledge driven discovery using data can only be realized by integrating statistical and information sciences with materials science, which is increasingly dependent on high throughput and large scale computational and experimental data gathering efforts. This is especially the case as we enter a new era of big data in materials science with the planning of future experimental facilities such as the Linac Coherent Light Source at Stanford (LCLS-II), the European X-ray Free Electron Laser (EXFEL) and MaRIE (Matter Radiation in Extremes), the signature concept facility from Los Alamos National Laboratory. These facilities are expected to generate hundreds of terabytes to several petabytes of in situ spatially and temporally resolved data per sample. The questions that then arise include how we can learn from the data to accelerate the processing and analysis of reconstructed microstructure, rapidly map spatially resolved properties from high throughput data, devise diagnostics for pattern detection, and guide experiments towards desired targeted properties. The authors are an interdisciplinary group of leading experts who bring the excitement of the nascent and rapidly emerging field of materials informatics to the reader.

This book highlights the environmental and economic benefits of recycling in textiles and fashion; vis-a-vis virgin textiles. Recycling plays an inevitable part when it comes to sustainable innovations in textiles and fashion sector. As basic information pertaining to the benefits, challenges of recycling in textiles are discussed to the sufficient extent in the literature, this book deals with the innovative at the same time, sustainable products made from the recycled textiles.