S Sulfur-Nitrogen Compounds - Part 10a: Compounds with Sulfur of Oxidation Number II (Paperback, 8th ed. 1994. Softcover reprint of the original 8th ed. 1994)

The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida- tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or- ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi- tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one- coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac- 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Series:	S. Schwefel. Sulfur (System-Nr. 9), S / S-N / 10 / a
Release date:	October 2013
First published:	1994
Editors-in-chief:	Alfons Kubny
Authors:	Norbert Baumann • Hans-Jurgen Fachmann • Reimund Jotter • Alfons Kubny
Dimensions:	254 x 178 x 19mm (L x W x T)
Format:	Paperback
Pages:	324
Edition:	8th ed. 1994. Softcover reprint of the original 8th ed. 1994
ISBN-13:	978-3-662-06353-8
Categories:	Books > Science & Mathematics > Chemistry > General
LSN:	3-662-06353-0
Barcode:	9783662063538

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