Iron catalysts in organic synthesis are strongly in demand because
iron is non-toxic, inexpensive and the most abundant transition
metal in the earth, although their use is still limited compared
with that of rare, precious metals such as palladium, ruthenium and
rhodium. This thesis describes the first practical example of iron
catalysis in the carbon hydrogen bond activation reaction to
synthesized fused aromatic ring compounds. By using a unique
combination of iron catalyst and dichloride oxidant, various kind
of naphthalene and phenanthrene derivatives were synthesized via
annulation reaction with alkynes including direct C H bond
activation process. This achievement opens the new possibility of
low-valent iron catalysis and expands synthetic methods for a
sustainable society."
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