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Modern Aspects of Electrochemistry No. 7 (Paperback, Softcover reprint of the original 1st ed. 1972)
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Modern Aspects of Electrochemistry No. 7 (Paperback, Softcover reprint of the original 1st ed. 1972)
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Despite reductions in the level of research activity in most fields
which, for reasons of economic decline, have taken place in the
U.S. during the last year or two, world progress in the fundamental
aspects has continued actively. An important aspect of such recent
work has been the use of nonaqueous solvents in studies on the
constitution of the double-layer and electrochemical reactions.
Interpretation of the behavior of electrode interfaces in such
solvents demands more knowledge of the solvation properties of ions
in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in
Nonaqueous and Mixed Solvents" gives an up to date review of the
present state of knowledge in this field, together with tabulations
of data that are likely to be of quantitative value in further
investigations of both homogeneous and heterogeneous
electrochemistry in such media. Electrochemical studies of cathodic
processes in nonaqueous solvents have, in recent years, revealed
the role of solvated electrons. These are of interest in new
approaches to reductive electro-organic synthesis. Similarly, the
generation of hydrated electrons in photo cathodic processes is of
great interest. In Chapter 2, by Conway, the conditions under which
solvated electrons can arise in electrode processes are critically
examined and the electro-organic reactions that hwe been
investigated are reviewed. The supposed electro generation of
hydrated electrons in the water solvent and as inter mediates in
cathodic hydrogen evolution is shown to be unlikely.
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