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Bridging Heterogeneous and Homogeneous Catalysis - Concepts, Strategies, and Applications (Hardcover)
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Bridging Heterogeneous and Homogeneous Catalysis - Concepts, Strategies, and Applications (Hardcover)
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There are two main disciplines in catalysis research -- homogeneous
and heterogeneous catalysis. This is due to the fact that the
catalyst is either in the same phase (homogeneous catalysis) as the
reaction being catalyzed or in a different phase (heterogeneous
catalysis). Over the past decade, various approaches have been
implemented to combine the advantages of homogeneous catalysis
(efficiency, selectivity) with those of heterogeneous catalysis
(stability, recovery) by the heterogenization of homogeneous
catalysts or by carrying out homogeneous reactions under
heterogeneous conditions.
This unique handbook fills the gap in the market for an up-to-date
work that links both homogeneous catalysis applied to organic
reactions and catalytic reactions on surfaces of heterogeneous
catalysts. As such, it highlights structural analogies and shows
mechanistic parallels between the two, while additionally
presenting kinetic analysis methods and models that either work for
both homogeneous and heterogeneous catalysis.
Chapters cover asymmetric, emulsion, phase-transfer, supported
homogeneous, and organocatalysis, as well as in nanoreactors and
for specific applications, catalytic reactions in ionic liquids,
fluorous and supercritical solvents and in water. Finally, the text
includes computational methods for investigating
structure-reactivity relations.
With its wealth of information, this invaluable reference provides
academic and industrial chemists with novel concepts for innovative
catalysis research.
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