Perturbations on quantum dynamical systems are of great relevance
both in chemical physics and physical chemistry. The present study
has answered a few such questions and raised many more. The
ionization of halide anions explored through model can be
calculated on solvated halide anions to extract accurate ion-water
potentials. Studies on modelling thermal effects on
photo-dissociation dynamics and dynamics of tunnelling indicate
that part of the effects is accounted for by our choice and may be
compared with experimental results. The proton as well as electron
transfer processes can be explored in the connection of tunnelling
phenomena. The quantum hysteresis is interesting as it arises out
of the competition between two time-scales, the time scale of
driving and relaxation. The time-lag between the two processes is
important in determining the fate of energy redistribution in the
systems after it is pumped in. Another important question
concerning the Landau-Zener transition rates has been raised when
we study the nuclear dynamics on coupled potential energy surfaces
and the non-adiabatic processes. Overall a new methodology, TDFGH,
has been proposed to study all such systems.
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