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Molecular Orientation and Emission Characteristics of Ir Complexes and Exciplex in Organic Thin Films (Hardcover, 1st ed. 2019)
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Molecular Orientation and Emission Characteristics of Ir Complexes and Exciplex in Organic Thin Films (Hardcover, 1st ed. 2019)
Series: Springer Theses
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This thesis considers molecular orientation in thin films and
introduces an optical model describing this orientation as applied
to organic light-emitting diodes (OLEDs). It also describes the
electronic structure of intermolecular charge transfer excitons
correlated to molecular orientation in solids. It has long been
known that molecular orientation influences the electrical and
optical properties of molecular films. One notable example is in
liquid crystals where rigid rod or disk shaped molecules are
commonly used. Understanding the origin of the molecular
orientation and its control by surface treatment and electric field
resulted in the development of liquid crystal displays. The same
thing has happened in organic electronics, and considerable effort
has been devoted to understanding and controlling molecular
orientation in solid films to improve charge carrier mobility and
light absorption, ultimately to improve the performance of organic
solar cells and thin film transistors. In contrast, less attention
has been paid to molecular orientation and its influence on the
characteristics of OLEDs, probably because of the use of amorphous
films rather than micro-crystalline films, and it is only in recent
years that some molecular films are known to have preferred
orientation. This thesis addresses this topic, focusing on OLEDs,
describing the origin and control of the orientation of
phosphorescent Ir complexes possessing spherical shape rather than
rod or disk shape, the simulation of the optical characteristics of
OLEDs influenced by preferred molecular orientation, and finally
the orientation of intermolecular charge transfer excitons and its
correlation to electronic structures in thin films.
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