Epoxidations and Hydroperoxidations of , -Unsaturated Ketones - An Approach through Asymmetric Organocatalysis (Paperback, 2012 ed.)

Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic , -unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of , -enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Series:	Springer Theses
Release date:	July 2014
First published:	2012
Authors:	Corinna Reisinger
Dimensions:	235 x 155 x 15mm (L x W x T)
Format:	Paperback
Pages:	260
Edition:	2012 ed.
ISBN-13:	978-3-642-43533-1
Categories:	Books > Science & Mathematics > Chemistry > Organic chemistry > General Books > Science & Mathematics > Chemistry > Physical chemistry > Catalysis Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry > General
LSN:	3-642-43533-5
Barcode:	9783642435331

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