An analysis was needed which would indicate the purity and acid
content of maleic anhydride. Small amounts of acid can affect the
copolymerization behavior of the anhydride [1] and may cause
rearrangement and polymerization of the diene component in
Diels-Alder reactions [2]. Standardized solutions of tertiary
amines such as tripropylamine and N-ethylpiperidine have been used
by Siggia and Floramo [ 1] to titrate maleic and phthalic acids in
their anhydrides. This method is rather specific for maleic acid
since the acids which might be included in the determination are
those with dissociation constants 3 of 10- , or greater, in water.
This would not include 5 acids such as succinic (dissociation
constant, 7 * 10- ) 4 or fumaric (9.3 * 10- ). Anhydrides have been
determined in the presence of their acids by reaction with excess
aniline and deter- mination of the excess [3]. The acid content is
then found by difference in anhydride and total acidity by
hydrolysis. Mixtures of anhydride and acid have been determined by
difference using either sodium methylate in methanol to titrate the
free acid plus one equivalent per mole of the anhydride and sodium
hydroxide [4], or trimethyl- benzylammonium hydroxide [5] in the
presence of water to titrate the free acid plus two equivalents per
mole of the anhydride. The determination of free acid by the
difference in the two titrations yields poor results for samples of
low acid content.
General
Imprint: |
Springer-Verlag New York
|
Country of origin: |
United States |
Release date: |
July 2013 |
First published: |
1961 |
Authors: |
D. S. Jackson
|
Dimensions: |
235 x 155 x 10mm (L x W x T) |
Format: |
Paperback
|
Pages: |
185 |
Edition: |
Softcover reprint of the original 1st ed. 1961 |
ISBN-13: |
978-1-4899-2704-0 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
Physical chemistry >
General
|
LSN: |
1-4899-2704-2 |
Barcode: |
9781489927040 |
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