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Th Thorium - Compounds with S, Se, Te and B (Paperback, 8th ed. 1985)
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Th Thorium - Compounds with S, Se, Te and B (Paperback, 8th ed. 1985)
Series: Th. Thorium (System-Nr. 44), T-h / A-E / C / 5
Expected to ship within 10 - 15 working days
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The present volume, Thorium C5, deals with the compounds of thorium
and sulfur, selenium, tellurium, and boron, as well as with oxoacid
compounds of the three chalcogen elements. Thorium borates have
already been treated in Thorium C2. In contrast to the
corresponding compounds of uranium the thorium sulfides, etc. , do
not show any nuclear or other technological application; they are
only of academic interest, despite some very interest ing
electronic properties, especially of the 1 : 1 compounds. The
thorium-sulfur and the thorium boron systems in particular were
studied in detail, so that we have a clear picture of them, whereas
there are still a lot of open questions in the systems Th-Se and
Th-Te - not very different from other metal chalcogenide systems.
Thorium sulfates are of some technological importance because they
are formed in solution during recovery of thorium from monazite by
sulfuric acid leaching. The very detailed and critical treatment of
the chemical and physical properties of the compounds discussed
also enables us to find gaps still remaining in our knowledge and
thus to initiate new research in this field. I want to thank the
two authors, Dr. Horst Wedemeyer (Karlsruhe) and Dr. David Brown
(Harwell), for their excellent contributions, the
"Literaturabteilung" of the Karlsruhe Nuclear Research Center for
its help in providing reports and other documents difficult to
procure, as well as the staff of the Gmelin-Institute, especially
to Dr. K. -C.
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