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The Physics and Chemistry of Inorganic Clathrates (Paperback, Softcover reprint of the original 1st ed. 2014)
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The Physics and Chemistry of Inorganic Clathrates (Paperback, Softcover reprint of the original 1st ed. 2014)
Series: Springer Series in Materials Science, 199
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The chemistry and physics of group 14 elements such as silicon and
germanium have been extensively studied, largely due to their
fundamental importance in the development of semiconductor
electronics. In addition, crystalline open-framework and
nano-porous materials are attracting increasing attention for their
potential technological applications. Inorganic open-framework
materials comprised of group 14 elements crystallizing in crystal
structures known as clathrates are of particular interest. These
materials correspond to expanded forms, and in some cases
metastable allotropes, of silicon, germanium and tin. The novel
crystal structures these materials possess are intimately related
to the unique physical properties they exhibit. Just as interesting
as the structure and properties group 14 clathrates display is the
diverse range of synthetic techniques developed to synthesize and
grow single crystals of these materials. This volume will encompass
many of these aspects and describe their potential for important
technological applications.
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