According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond
Complexes is described as 'the definitive account of
twentieth-century work in the area of sigma complexation'. It
covers not only Kubas' discovery of dihydrogen coordination and the
study of its structure and general properties but also discusses
both the theoretical beliefs and experimental results of bonding
and activation of dihydrogen on metal centers and the coordination
and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview
of 'one of the hottest areas in chemistry'.
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