Biological chemistry is a major frontier of inorganic chemistry.
Three special volumes devoted to Metal Sites in Proteins and Models
address the questions: how unusual ("entatic") are metal sites in
metalloproteins and metalloenzymes compared to those in small
coordination complexes? And if they are special, how do polypeptide
chains and co-factors control this? The chapters deal with iron,
with metal centres acting as Lewis acids, metals in phosphate
enzymes, with vanadium, and with the wide variety of transition
metal ions which act as redox centres. They illustrate in
particular how the combined armoury of genetics and structure
determination at the molecular level are providing unprecedented
new tools for molecular engineering.
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