Physics and Chemistry of Electrons and Ions in Condensed Matter (Paperback, Softcover reprint of the original 1st ed. 1984)

xvii PART I PROPERTIES OF CRYSTALLINE MATERIALS The Effective U in Oxides and in Sulfides: Conceptual Phase Diagrams and their Applications . . . . . . . . . . . . . . .; . . . . . . . . . . . . . . . 1 John B. Goodenough 1. Definitions 1 2. Interatomic interactions 23 References 44 Electron Correlations in Elementary Structures. The Case of Weak Correlations: Metallic and Covalent Bondings . . . . . . . . . . . . . . . . . 45 J. Friedel Introduct i on 45 1. The H2 molecule 46 2. Other elementary diatomic molecules 52 3. Metallic aggregates 53 4. Macroscopic phases of transition metals 57 5. Aggregates and solids of tetravalent (sp) elements 64 6. Aggregates of covalent dimers 67 7. Weak distortions of metallic closepacked or covalent structures 69 Appendixes 74 References 82 Statistical Thermodynamics of Mixed Valence at Low Temperatures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Dieter Wohlleben 1. Introduction 85 2. The free enthalpy without mixing 86 3. The valence fluctuation temperature 89 4. 'The free enthalpy with interconfigurational mlxlng 90 5. Equation of state for the valence fluctuation n e 6. The conduction electron density of states near T=O 98 7. Application to Ce metal 101 8. Acknowledgements 104 References 104 Mixed Valency in Inorganic Chemistry . . . . . . . . . . . . . . . . . . . . 109 P. Day CONTENTS vi Important Discussion of Part I Intermedi ate Val ency (IV) Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 111 N. F. Mott Thermal Expansion and Specific Heat of Mixed Valence Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 R. Pott 1. Introduction 117 2. Experiments and experimental results 117 3. Discussion 120 4. Acknowledgements 122 5."

General

Imprint:	Springer
Country of origin:	Netherlands
Series:	NATO Science Series C, 130
Release date:	November 2011
First published:	1984
Editors:	J.V. Acrivos • N. F Mott • A. D. Joffe
Dimensions:	235 x 155 x 38mm (L x W x T)
Format:	Paperback
Pages:	732
Edition:	Softcover reprint of the original 1st ed. 1984
ISBN-13:	978-9400964426
Categories:	Books > Science & Mathematics > Chemistry > Physical chemistry > General
LSN:	9400964420
Barcode:	9789400964426

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