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Instability Constants of Complex Compounds (Paperback, 1960 ed.)
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Instability Constants of Complex Compounds (Paperback, 1960 ed.)
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In recent years many research workers have turned their attention
to the quantitative characterization of complex compounds and
reactions of complex-formation in solution. Instability constants
characterize quantitatively the equili bria in solutions of complex
compounds and are extensively used by chemists of widely-varying
specialities, in analytical chemistry, electrochemistry, the
technology of non-ferrous and rare metals, etc., for calculations
of various kinds. Despite the wealth of numerical data, no
reasonably full coliection of instability constants of complex
compounds has been made until now. The various individual
collections of data are far from complete and in most cases omit
references to the source materials. Moreover, the present state of
the chemistry of complex compounds most urgently demands the
complete systematization of data on instability constants and an
extension of work in this field which would take advantage of the
latest physico-chemical methods. The present work contains
instability constants for 1,381 complex compounds. We have
considered it convenient to preface the summary of the instability
constants with an introductory section of a general theoretical
character. This section deals with methods for the calculation of
instability constants from experimental data, the influence of
external conditions, such as temperature and ionic strength, on the
stability of com plexes, and the principal factors determining the
stability of complex compounds in aqueous solution. (vii) PREFACE
In compiling the summary we have used the original litera ture and
abstracts for the most part up to 1954, and some work published in
1955-1956."
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