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Handbook on the Physics and Chemistry of Rare Earths, Volume 36 (Hardcover, 36th edition)
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Handbook on the Physics and Chemistry of Rare Earths, Volume 36 (Hardcover, 36th edition)
Series: Handbook on the Physics & Chemistry of Rare Earths
Expected to ship within 12 - 17 working days
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This volume of the Handbook on the Physics and Chemistry of Rare
Earth begins with a Dedication to late Professor LeRoy Eyring who
had been a committed co-editor of the first 32 volumes of this
series. This is followed by four chapters, the first two pertaining
to solid state physics and materials science, while the last two
chapters describe organic (and inorganic) reactions mediated by
tetravalent cerium-based oxidants and by divalent samarium-based
reductants. Chapter 227 is devoted to the description of the
crystal chemistry and physical properties of rare-earth
bismuthides, a class of compounds showing large similarities with
the rare-earth antimonides previously reviewed in volume 33 of this
series. The fascinating optical and electric properties of
rare-earth hydride films displaying a switchable mirror effect as a
function of hydrogen pressure, i.e. from a shiny metallic state to
a transparent insulating film with increasing pressure, are
described in Chapter 228, along with their fabrication methods.
Many chemical reactions take advantage of the tetravalent/trivalent
Ce(IV)/Ce(III) redox couple and many of its potential applications
are presented in Chapter 229, from analytical procedures, to
electrosynthesis, and organic and industrial (polymerization)
reactions. The last review (Chapter 230) focuses on the synthesis
and use of divalent samarium-based reductants in organic and
inorganic reactions, mainly on those containing iodide and
pentamethylcyclopentadienyl ligands.
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