The activation of dioxygen by metal ions has both synthetic
potential and biological relevance. Dioxygen is the cleanest
oxidant for use in emission-free technologies to minimize pollution
of the environment. The book gives a survey of those catalyst
systems based on metal complexes which have been discovered and
studied in the last decade. They activate molecular oxygen and
effect the oxidation of various organic compounds under mild
conditions. Much of the recent progress is due to a search for
biomimetic catalysts that would duplicate the action of
metalloenzymes. Mechanistic aspects are emphasized throughout the
book. An introductonary chapter reviews the chemistry of transition
metal dioxygen complexes, which are usually the active
intermediates in the catalytic reactions discussed. Separate
chapters are devoted to oxidation of saturated, unsaturated and
aromatic hydrocarbons, phenols, catechols, oxo-compounds,
phosphorus, sulfur and nitrogen compounds.
General
Imprint: |
Springer
|
Country of origin: |
Netherlands |
Series: |
Catalysis by Metal Complexes, 13 |
Release date: |
June 2003 |
First published: |
1992 |
Authors: |
Laszlo I. Simandi
|
Dimensions: |
229 x 152 x 23mm (L x W x T) |
Format: |
Hardcover
|
Pages: |
397 |
Edition: |
1992 ed. |
ISBN-13: |
978-0-7923-1896-5 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
Physical chemistry >
Catalysis
|
LSN: |
0-7923-1896-X |
Barcode: |
9780792318965 |
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