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Expanded Clays and Other Microporous Solids (Paperback, Softcover reprint of the original 1st ed. 1992)
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Expanded Clays and Other Microporous Solids (Paperback, Softcover reprint of the original 1st ed. 1992)
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the chapters contained in this volume. Chapters dealing with
pillared clays char- acterization and testing have been included to
illustrate the importance of mod- em characterization techniques
and of test reactions in understanding the prop- erties of these
materials. A special acknowledgment is made of the generous
financial contribution from industrial sponsors, to the many
colleagues who acted as referees and to the authors for the time
and effort they gave to presenting their research at the symposium
and in preparing the camera ready manuscripts. We would also like
to thank Professors A. Clearfield, T. J. Pinnavaia, Z. Gabelica, H.
Kessler, S. Yamanaka, and to Doctors G. W. Skeel and D. E. W.
Vaughan for helping to chair the symposium. Mario L. Occelli Yorba
Linda, CA Harry E. Robson Baton Rouge, LA Expanded Clays and Other
Microporous Solids 1 APPROACHES TO THE SYNTHESIS OF SUPER GALLERY
PILLARED CLAYS Thomas J. Pinnavaia, Department of Chemistry and
Center for Fundamental Materials Research, Michigan State
University, East Lansing, Michigan 48824 Recent advances in the
design of microporous pillared solids with "supergallery"
structures are discussed. Supergallery derivatives are defined as
intercalates in which the interlayer thickness is substantially
larger than the thickness of the host layer. Three general classes
of hosts are considered, namely, 2:1 smectite clays,layered double
hydroxides (LDHs) , and layered silicic acids.
General
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