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Sb Organoantimony Compounds - Part 5: Compounds of Pentavalent Antimony with Three, Two and One Sb-C Bonds (Paperback, 8th ed. 1990. Softcover reprint of the original 8th ed. 1990)
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Sb Organoantimony Compounds - Part 5: Compounds of Pentavalent Antimony with Three, Two and One Sb-C Bonds (Paperback, 8th ed. 1990. Softcover reprint of the original 8th ed. 1990)
Series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, S-b / 1-4 / 5
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This fifth volume on organoantimony compounds continues the
description of pentavalent antimony compounds and concludes the
entire series. The treatment of pentavalent compounds with three
Sb-C bonds began in Part 4 with the RSbX type and is now completed
with types RSb(X)Y, RR'SbX , RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX
(Section 2.5.1) and the corresponding bi- and trinuclear compounds
(Sec- 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote
different organic groups bonded through carbon to the antimony
atom. X and Y represent inorganic or organic groups that are bonded
to antimony by an atom other than carbon. R, X, and/or Y can also
be chelating ligands. The remaining part of the volume completeLy
covers all pentavalent antimony compounds containing two Sb-C bonds
(RSbX , RSb(X )Y, RR'SbX , RR'Sb(X )Y, bi- and tetranucLear 2 3 2 2
3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C
bond (RSbX , RSb(X )Y, 4 3 RSb(X)Y , bi- and trinucLear compounds,
Chapter 2.7, p. 237). These compounds form ad- 2 2 ducts with Lewis
bases (symbol D) and form many ionic compLexes by the addition of
saLts such as amine hydrochLorides (symbol MZ). The adducts and
ionic compLexes are described immediately after the parent
substances. The volume concludes with an Empirical Formula Index
(p. 318) and a Ligand Formula Index (p. 357).
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